11,377 research outputs found
The correlation potential in density functional theory at the GW-level: spherical atoms
As part of a project to obtain better optical response functions for nano
materials and other systems with strong excitonic effects we here calculate the
exchange-correlation (XC) potential of density-functional theory (DFT) at a
level of approximation which corresponds to the dynamically- screened-exchange
or GW approximation. In this process we have designed a new numerical method
based on cubic splines which appears to be superior to other techniques
previously applied to the "inverse engineering problem" of DFT, i.e., the
problem of finding an XC potential from a known particle density. The
potentials we obtain do not suffer from unphysical ripple and have, to within a
reasonable accuracy, the correct asymptotic tails outside localized systems.
The XC potential is an important ingredient in finding the particle-conserving
excitation energies in atoms and molecules and our potentials perform better in
this regard as compared to the LDA potential, potentials from GGA:s, and a DFT
potential based on MP2 theory.Comment: 13 pages, 9 figure
Electronic properties of disordered corner-sharing tetrahedral lattices
We have examined the behaviour of noninteracting electrons moving on a
corner-sharing tetrahedral lattice into which we introduce a uniform (box)
distribution, of width W, of random on-site energies. We have used both the
relative localization length and the spectral rigidity to analyze the nature of
the eigenstates, and have determined both the mobility edge trajectories as a
function of W, and the critical disorder, Wc, beyond which all states are
localized. We find (i) that the mobility edge trajectories (energies Ec vs.
disorder W) are qualitatively different from those found for a simple cubic
lattice, and (ii) that the spectral rigidity is scale invariant at Wc and thus
provides a reliable method of estimating this quantity -- we find Wc/t=14.5. We
discuss our results in the context of the metal-to-insulator transition
undergone by LiAlyTi{2-y}O4 in a quantum site percolation model that also
includes the above-mentioned Anderson disorder, and show that the effects
produced by Anderson disorder are far less important than those produced by
quantum site percolation, at least in the determination of the doping
concentration at which the metal-to-insulator transition is predicted to occur
Measurement of gamma p --> K+ Lambda and gamma p --> K+ Sigma0 at photon energies up to 2.6 GeV
The reactions gamma p --> K+ Lambda and gamma p --> K+ Sigma0 were measured
in the energy range from threshold up to a photon energy of 2.6 GeV. The data
were taken with the SAPHIR detector at the electron stretcher facility, ELSA.
Results on cross sections and hyperon polarizations are presented as a function
of kaon production angle and photon energy. The total cross section for Lambda
production rises steeply with energy close to threshold, whereas the Sigma0
cross section rises slowly to a maximum at about E_gamma = 1.45 GeV. Cross
sections together with their angular decompositions into Legendre polynomials
suggest contributions from resonance production for both reactions. In general,
the induced polarization of Lambda has negative values in the kaon forward
direction and positive values in the backward direction. The magnitude varies
with energy. The polarization of Sigma0 follows a similar angular and energy
dependence as that of Lambda, but with opposite sign.Comment: 21 pages, 25 figures, submitted to Eur. Phys. J.
Composition Conditions for Classes of Analytic Functions
We prove that for classes of analytic functions tree composition condition
and composition condition coincide.Comment: 13 page
Investigating Atomic Details of the CaF(111) Surface with a qPlus Sensor
The (111) surface of CaF has been intensively studied with
large-amplitude frequency-modulation atomic force microscopy and atomic
contrast formation is now well understood. It has been shown that the apparent
contrast patterns obtained with a polar tip strongly depend on the tip
terminating ion and three sub-lattices of anions and cations can be imaged.
Here, we study the details of atomic contrast formation on CaF(111) with
small-amplitude force microscopy utilizing the qPlus sensor that has been shown
to provide utmost resolution at high scanning stability. Step edges resulting
from cleaving crystals in-situ in the ultra-high vacuum appear as very sharp
structures and on flat terraces, the atomic corrugation is seen in high clarity
even for large area scans. The atomic structure is also not lost when scanning
across triple layer step edges. High resolution scans of small surface areas
yield contrast features of anion- and cation sub-lattices with unprecedented
resolution. These contrast patterns are related to previously reported
theoretical results.Comment: 18 pages, 9 Figures, presented at 7th Int Conf Noncontact AFM
Seattle, USA Sep 12-15 2004, accepted for publication in Nanotechnology,
http://www.iop.or
Measurement of the reaction \gamma p \TO K^ + \Lambda(1520) at photon energies up to 2.65 GeV
The reaction \gamma p \TO K^+\Lambda(1520) was measured in the energy range
from threshold to 2.65 GeV with the SAPHIR detector at the electron stretcher
facility ELSA in Bonn. The production cross section was
analyzed in the decay modes , , , and
as a function of the photon energy and the squared
four-momentum transfer . While the cross sections for the inclusive
reactions rise steadily with energy, the cross section of the process \gamma p
\TO K^+\Lambda(1520) peaks at a photon energy of about 2.0 GeV, falls off
exponentially with , and shows a slope flattening with increasing photon
energy. The angular distributions in the -channel helicity system indicate
neither a nor a exchange dominance. The interpretation of the
as a molecule is not supported.Comment: 11 pages, 16 figures, 4 table
Optimized Effective Potential Model for the Double Perovskites Sr2-xYxVMoO6 and Sr2-xYxVTcO6
In attempt to explore half-metallic properties of the double perovskites
Sr2-xYxVMoO6 and Sr2-xYxVTcO6, we construct an effective low-energy model,
which describes the behavior of the t2g-states of these compounds. All
parameters of such model are derived rigorously on the basis of
first-principles electronic structure calculations. In order to solve this
model we employ the optimized effective potential method and treat the
correlation interactions in the random phase approximation. Although
correlation interactions considerably reduce the intraatomic exchange splitting
in comparison with the Hartree-Fock method, this splitting still substantially
exceeds the typical values obtained in the local-spin-density approximation
(LSDA), which alters many predictions based on the LSDA. Our main results are
summarized as follows: (i) all ferromagnetic states are expected to be
half-metallic. However, their energies are generally higher than those of the
ferrimagnetic ordering between V- and Mo/Tc-sites (except Sr2VMoO6); (ii) all
ferrimagnetic states are metallic (except fully insulating Y2VTcO6) and no
half-metallic antiferromagnetism has been found; (iii) moreover, many of the
ferrimagnetic structures appear to be unstable with respect to the spin-spiral
alignment. Thus, the true magnetic ground state of the most of these systems is
expected to be more complex. In addition, we discuss several methodological
issues related to the nonuniqueness of the effective potential for the magnetic
half-metallic and insulating states.Comment: 15 pages, 9 figure
Pseudoconvex domains spread over complex homogeneous manifolds
Using the concept of inner integral curves defined by Hirschowitz we
generalize a recent result by Kim, Levenberg and Yamaguchi concerning the
obstruction of a pseudoconvex domain spread over a complex homogeneous manifold
to be Stein. This is then applied to study the holomorphic reduction of
pseudoconvex complex homogeneous manifolds X=G/H. Under the assumption that G
is solvable or reductive we prove that X is the total space of a G-equivariant
holomorphic fiber bundle over a Stein manifold such that all holomorphic
functions on the fiber are constant.Comment: 21 page
Fibrations of genus two on complex surfaces
We consider fibrations of genus 2 over complex surfaces. The purpose of this
paper is primarily to provide a geometric description of the possible
structures of the fibration on a neighborhood of a singular fiber. In
particular it is shown that the "geometric data" of the singular fiber
determines the fibration on its neighborhood up to a transversely holomorphic
-diffeomorphism. The method employed is quite flexible and it
applies to good extent to fibrations of arbitrary genus.Comment: This is the final version, June 201
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