5,405 research outputs found
Experiments on the origin of molecular chirality by parity non-conservation during beta-decay
Experiments are described to test a theory for the origin of optical activity wherein the longitudinally polarized electrons resulting from parity violation during radioactive beta decay, and their resulting circularly polarized Bremsstrahlung, might interact asymmetrically with organic matter to yield optically active products. Experiments involve subjecting a number of racemic and optically active amino acid samples to irradiation in a 61700 Ci90SR-90Y beta radiation source for a period of 1.34 years, then examining them for any asymmetric effects by means of optical rotatory dispersion and analytical gas chromatography. In the cases of D,L-leucine, norleucine, norvaline and proline as solids, of D,L-leucine in solution and of D,L-tyrosine in alkaline solution no optical rotation was observed during CRD measurements in the 250-630 nm spectral region. While slight differences were noted in the percent radiolysis of solid D- (12.7%) and L-leucine (16.2%) as determined by GC, no enrichment of either enantiomer was found
Total Chiral Symmetry Breaking during Crystallization: Who needs a "Mother Crystal"?
Processes that can produce states of broken chiral symmetry are of particular
interest to physics, chemistry and biology. Chiral symmetry breaking during
crystallization of sodium chlorate occurs via the production of secondary
crystals of the same handedness from a single "mother crystal" that seeds the
solution. Here we report that a large and "symmetric" population of D- and
L-crystals moves into complete chiral purity disappearing one of the
enantiomers. This result shows: (i) a new symmetry breaking process
incompatible with the hypothesis of a single "mother crystal"; (ii) that
complete symmetry breaking and chiral purity can be achieved from an initial
system with both enantiomers. These findings demand a new explanation to the
process of total symmetry breaking in crystallization without the intervention
of a "mother crystal" and open the debate on this fascinating phenomenon. We
present arguments to show that our experimental data can been explained with a
new model of "complete chiral purity induced by nonlinear autocatalysis and
recycling".Comment: 5 pages, 4 figures, Added reference
The Fast Wandering of Slow Birds
I study a single "slow" bird moving with a flock of birds of a different, and
faster (or slower) species. I find that every "species" of flocker has a
characteristic speed , where is the mean speed of the
flock, such that, if the speed of the "slow" bird equals , it
will randomly wander transverse to the mean direction of flock motion far
faster than the other birds will: its mean-squared transverse displacement will
grow in with time like , in contrast to for the
other birds. In , the slow bird's mean squared transverse displacement
grows like , in contrast to for the other birds. If , the mean-squared displacement of the "slow" bird crosses over from
to scaling in , and from to scaling in
, at a time that scales according to .Comment: 10 pages; 5 pages of which did not appear in earlier versions, but
were added in response to referee's suggestion
A Reanalysis of the Hydrodynamic Theory of Fluid, Polar-Ordered Flocks
I reanalyze the hydrodynamic theory of fluid, polar ordered flocks. I find
new linear terms in the hydrodynamic equations which slightly modify the
anisotropy, but not the scaling, of the damping of sound modes. I also find
that the nonlinearities allowed {\it in equilibrium} do not stabilize long
ranged order in spatial dimensions ; in accord with the Mermin-Wagner
theorem. Nonequilibrium nonlinearities {\it do} stabilize long ranged order in
, as argued by earlier work. Some of these were missed by earlier work; it
is unclear whether or not they change the scaling exponents in .Comment: 6 pages, no figures. arXiv admin note: text overlap with
arXiv:0909.195
Finite-Field Ground State of the S=1 Antiferromagnetic-Ferromagnetic Bond-Alternating Chain
We investigate the finite-field ground state of the S=1
antiferromagnetic-ferromagnetic bond-alternating chain described by the
Hamiltonian
{\calH}=\sum\nolimits_{\ell}\bigl\{\vecS_{2\ell-1}\cdot\vecS_{2\ell}
+J\vecS_{2\ell}\cdot\vecS_{2\ell+1}\bigr\} +D\sum\nolimits_{\ell}
\bigl(S_{\ell}^z)^2 -H\textstyle\sum\nolimits_\ell S_\ell^z, where
\hbox{} and \hbox{}. We find that two kinds of
magnetization plateaux at a half of the saturation magnetization, the
1/2-plateaux, appear in the ground-state magnetization curve; one of them is of
the Haldane type and the other is of the large--type. We determine the
1/2-plateau phase diagram on the versus plane, applying the
twisted-boundary-condition level spectroscopy methods developed by Kitazawa and
Nomura. We also calculate the ground-state magnetization curves and the
magnetization phase diagrams by means of the density-matrix
renormalization-group method
The Origin of Primordial Dwarf Stars and Baryonic Dark Matter
I present a scenario for the production of low mass, degenerate dwarfs of
mass via the mechanism of Lenzuni, Chernoff & Salpeter (1992).
Such objects meet the mass limit requirements for halo dark matter from
microlensing surveys while circumventing the chemical evolution constraints on
normal white dwarf stars. I describe methods to observationally constrain this
scenario and suggest that such objects may originate in small clusters formed
from the thermal instability of shocked, heated gas in dark matter haloes, such
as suggested by Fall & Rees (1985) for globular clusters.Comment: TeX, 4 pages plus 2 postscript figures. To appear in Astrophysical
Journal Letter
Diffusion Enhances Chirality Selection
Diffusion effect on chirality selection in a two-dimensional
reaction-diffusion model is studied by the Monte Carlo simulation. The model
consists of achiral reactants A which turn into either of the chiral products,
R or S, in a solvent of chemically inactive vacancies V. The reaction contains
the nonlinear autocatalysis as well as recycling process, and the chiral
symmetry breaking is monitored by an enantiomeric excess .
Without dilution a strong nonlinear autocatalysis ensures chiral symmetry
breaking. By dilution, the chiral order decreases, and the racemic state
is recovered below the critical concentration . Diffusion effectively
enhances the concentration of chiral species, and decreases as the
diffusion coefficient increases. The relation between and for a
system with a finite fits rather well to an interpolation formula between
the diffusionless(D=0) and homogeneous () limits.Comment: 7 pages, 6 figure
PON1 status does not influence cholinesterase activity in Egyptian agricultural workers exposed to chlorpyrifos.
Animal studies have shown that paraoxonase 1 (PON1) genotype can influence susceptibility to the organophosphorus pesticide chlorpyrifos (CPF). However, Monte Carlo analysis suggests that PON1 genotype may not affect CPF-related toxicity at low exposure conditions in humans. The current study sought to determine the influence of PON1 genotype on the activity of blood cholinesterase as well as the effect of CPF exposure on serum PON1 in workers occupationally exposed to CPF. Saliva, blood and urine were collected from agricultural workers (n=120) from Egypt's Menoufia Governorate to determine PON1 genotype, blood cholinesterase activity, serum PON1 activity towards chlorpyrifos-oxon (CPOase) and paraoxon (POase), and urinary levels of the CPF metabolite 3,5,6-trichloro-2-pyridinol (TCPy). The PON1 55 (P≤0.05) but not the PON1 192 genotype had a significant effect on CPOase activity. However, both the PON1 55 (P≤0.05) and PON1 192 (P≤0.001) genotypes had a significant effect on POase activity. Workers had significantly inhibited AChE and BuChE after CPF application; however, neither CPOase activity nor POase activity was associated with ChE depression when adjusted for CPF exposure (as determined by urinary TCPy levels) and stratified by PON1 genotype. CPOase and POase activity were also generally unaffected by CPF exposure although there were alterations in activity within specific genotype groups. Together, these results suggest that workers retained the capacity to detoxify chlorpyrifos-oxon under the exposure conditions experienced by this study population regardless of PON1 genotype and activity and that effects of CPF exposure on PON1 activity are minimal
The Nature of the Dense Core Population in the Pipe Nebula: Thermal Cores Under Pressure
In this paper we present the results of a systematic investigation of an
entire population of starless dust cores within a single molecular cloud.
Analysis of extinction data shows the cores to be dense objects characterized
by a narrow range of density. Analysis of C18O and NH3 molecular-line
observations reveals very narrow lines. The non-thermal velocity dispersions
measured in both these tracers are found to be subsonic for the large majority
of the cores and show no correlation with core mass (or size). Thermal pressure
is thus the dominate source of internal gas pressure and support for most of
the core population. The total internal gas pressures of the cores are found to
be roughly independent of core mass over the entire range of the core mass
function (CMF) indicating that the cores are in pressure equilibrium with an
external source of pressure. This external pressure is most likely provided by
the weight of the surrounding Pipe cloud within which the cores are embedded.
Most of the cores appear to be pressure confined, gravitationally unbound
entities whose nature, structure and future evolution are determined by only a
few physical factors which include self-gravity, the fundamental processes of
thermal physics and the simple requirement of pressure equilibrium with the
surrounding environment. The observed core properties likely constitute the
initial conditions for star formation in dense gas. The entire core population
is found to be characterized by a single critical Bonnor-Ebert mass. This mass
coincides with the characteristic mass of the Pipe CMF indicating that most
cores formed in the cloud are near critical stability. This suggests that the
mass function of cores (and the IMF) has its origin in the physical process of
thermal fragmentation in a pressurized medium.Comment: To appear in the Astrophysical Journa
Global Nonradial Instabilities of Dynamically Collapsing Gas Spheres
Self-similar solutions provide good descriptions for the gravitational
collapse of spherical clouds or stars when the gas obeys a polytropic equation
of state, (with ). We study the behaviors of
nonradial perturbations in the similarity solutions of Larson, Penston and
Yahil, which describe the evolution of the collapsing cloud prior to core
formation. Our global stability analysis reveals the existence of unstable
bar-modes () when . In particular, for the collapse of
isothermal spheres, which applies to the early stages of star formation, the
density perturbation relative to the background, , increases as ,
where denotes the epoch of core formation, and is the cloud
central density. Thus, the isothermal cloud tends to evolve into an ellipsoidal
shape (prolate bar or oblate disk, depending on initial conditions) as the
collapse proceeds. In the context of Type II supernovae, core collapse is
described by the equation of state, and our analysis
indicates that there is no growing mode (with density perturbation) in the
collapsing core before the proto-neutron star forms, although nonradial
perturbations can grow during the subsequent accretion of the outer core and
envelope onto the neutron star. We also carry out a global stability analysis
for the self-similar expansion-wave solution found by Shu, which describes the
post-collapse accretion (``inside-out'' collapse) of isothermal gas onto a
protostar. We show that this solution is unstable to perturbations of all
's, although the growth rates are unknown.Comment: 28 pages including 7 ps figures; Minor changes in the discussion; To
be published in ApJ (V.540, Sept.10, 2000 issue
- …