725 research outputs found

    Robust assessment of future changes in extreme precipitation over the Rhine basin using a GCM

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    Estimates of future changes in extremes of multiday precipitation sums are critical for estimates of future discharge extremes of large river basins. Here we use a large ensemble of global climate model SRES A1b scenario simulations to estimate changes in extremes of 1–20 day precipitation sums over the Rhine basin, projected for the period 2071–2100 with reference to 1961–1990. We find that in winter, an increase of order 10%, for the 99th percentile precipitation sum, is approximately fixed across the selected range of multiday sums, whereas in summer, the changes become increasingly negative as the summation time lengthens. Explanations for these results are presented that have implications for simple scaling methods for creating time series of a future climate. We show that the dependence of quantile changes on summation time is sensitive to the ensemble size and indicate that currently available discharge estimates from previous studies are based on insufficiently long time series

    A Workshop About Land-Use Decision-Making in the Context of Community/Societal Values

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    Community based land-use decision-making is often left to an oligarchy who are familiar with the planning process. Stakeholders are frequently under-represented, possibly because of their unwillingness to participate due to the unfamiliarity with the process. The workshop described here develops participants\u27 understanding of a land-use planning process and the complexity of socio-economic values using individual reflection and shared perspective through writing, model-making, presentations, and discussions. Using consensus-building strategies, along with a documentary film, participants engage in several hands-on group activities. Shared values in combination with new community perspectives are realized through a series of workshop activities

    Response to Comment on “Laser Desorption/Ionization Coupled to FTICR Mass Spectrometry for Studies of Natural Organic Matter”

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    Response to Comment on “Laser Desorption/Ionization Coupled to FTICR Mass Spectrometry for Studies of Natural Organic Matter

    Laser desorption/ionization coupled to FT-ICR mass spectrometry for studies of natural organic matter

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    Laser desorption/ionization (LDI) was investigated as an ionization method for Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS) studies of natural organic matter (NOM). Using International Humic Substances Society standards, Suwannee River fulvic acid (SRFA) and Suwannee River natural organic matter (SRNOM), LDI was found to ionize a very similar set of compounds (>90% of molecular formulas identity) to the matrix assisted laser desorption/ionization (MALDI), while producing higher quality spectra. A comparison of electrospray ionization (ESI) and LDI spectra showed that different types of compounds are ionized by these methods with only 9.9% of molecular formulas common to both. The compounds ionized by LDI/MALDI belong to low oxygen classes (maximum number of species for O7–O9), while ESI compounds belong to higher oxygen classes (maximum number of species for O14–O16). Compounds ionized by LDI can be classified as aliphatic, aromatic, and condensed aromatics in approximately equal measure, while aliphatic compounds dominated the ESI spectra of SRFA. In order to maximize the coverage of molecular species, LDI, as a particularly convenient and readily deployable ionization method, should be used routinely in combination with other ionization methods, such as ESI, for FTICR MS studies of NOM

    D9.2 Report, containing internal deliverable outcomes ID9.2-ID9.11

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    The aim of this deliverable is to report on TENCompetence training activities from the project month 13 to 30The work on this publication has been sponsored by the TENCompetence Integrated Project that is funded by the European Commission's 6th Framework Programme, priority IST/Technology Enhanced Learning. Contract 027087 [http://www.tencompetence.org

    Response of low-strength phenol-acclimated activated sludge to shock loading of high phenol concentrations

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    (ii) investigate the degradation pathways and (iii) model the growth and biodegradation kinetics, all under the condition of increasingly higher phenol concentrations (step-up shock loading). With the use of activated sludge acclimated to phenol concentration of 140 mg∙ℓ−1 (low-strength phenol-acclimated activated sludge), complete degradation of phenol with a COD removal efficiency of more than 95% was achieved up to 1 050 mg∙ℓ−1 of initial phenol concentration. At low initial phenol concentrations, the experimental results were indicative of the meta-cleavage pathway for phenol degradation. When the initial phenol concentration was above 630 mg∙ℓ−1, the degradation results were indicative of both meta- and ortho-cleavage pathways. The values of the Haldane kinetic parameters indicated a low degree of inhibition exerted by the presence of increasing phenol concentration. This was substantiated by the observation that the rate constant of phenol removal decreased by only 33% even though the initial phenol concentration was increased by 15 times from 70 to 1 050 mg∙ℓ−1.Thus, the activated sludge acclimated to only 140 mg∙ℓ−1 of phenol could successfully treat up to 1 050 mg∙ℓ−1 of phenol without experiencing complete inhibition during the degradation process.Keywords: Phenol removal, low-strength phenol-acclimated activated sludge, degradation pathway, Haldane kinetic paramete
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