Self-assembly and two-dimensional spontaneous resolution of cyano-functionalized [7]helicenes on Cu111

Birds of a feather flock together: STM and DFT studies provide the first example of spontaneous chiral resolution of a helicene on a surface. Racemic 6,13-dicyano[7]helicene forms fully segregated domains of pure enantiomers (2D conglomerate) on Cu(111). The propensity of the system to optimize intermolecular CN⋅⋅⋅HC(Ar) hydrogen bonding and CN⋅⋅⋅CN dipolar interactions translates into chiral recognition with preferential assembly of homochiral molecules

Graviton propagator from background-independent quantum gravity

We study the graviton propagator in euclidean loop quantum gravity, using the spinfoam formalism. We use boundary-amplitude and group-field-theory techniques, and compute one component of the propagator to first order, under a number of approximations, obtaining the correct spacetime dependence. In the large distance limit, the only term of the vertex amplitude that contributes is the exponential of the Regge action: the other terms, that have raised doubts on the physical viability of the model, are suppressed by the phase of the vacuum state, which is determined by the extrinsic geometry of the boundary.Comment: 6 pages. Substantially revised second version. Improved boundary state ansat

On the geometry of loop quantum gravity on a graph

We discuss the meaning of geometrical constructions associated to loop quantum gravity states on a graph. In particular, we discuss the "twisted geometries" and derive a simple relation between these and Regge geometries.Comment: 6 pages, 1 figure. v2: some typos corrected, references update

Inflationary Perturbations in Palatini Generalised Gravity

We examine the generation of primordial perturbations during an inflationary epoch in generalised theories of gravity when the equations of motion are derived using the Palatini variational principle. Both f(R) and Scalar-Tensor theories are considered and we compare our results with those obtained under the conventional metric formalism. Non-linear generalisations of the action lead to different theories under the two variational choices and we obtain distinct results for scalar and tensor spectral indices and their ratio. We find the following general result; inflation driven solely by f(R) modifications alone do not result in suitable curvature perturbations whilst Scalar-Tensor theories generate nearly scalar invariant curvature perturbations but no tensor modes.Comment: 9 page

Can lizard embryos survive climate warming? Thermal constraints on the physiology of developing Eastern fence lizards

Sublethal stressors will likely mediate an organism’s response to climate change. Mobile animals can change their behavior to maintain temperatures within preferred ranges. However, animals in immobile life stages are particularly vulnerable to warming. For example, lizard embryos experience recurrent thermal stress as they develop in shallow nests with daily temperature fluctuations. Nesting temperatures above 41.5°C can be lethal to Eastern fence lizard (Sceloporus undulatus) embryos. Although that is beyond the range experienced at current nest sites, rapid warming will push nest conditions toward critical limits. Therefore, it is important to examine the effects of sublethal high nest temperatures on developing lizards. We reared S. undulatus embryos under three thermal regimes—one to simulate contemporary nest conditions with a maximum daily temperature (Tmax) of 32.1°C, and two regimes to simulate warming scenarios in which the Tmax was raised to 35.6°C and 39.1°C. We tracked changes in physiology and survival through embryonic development, and we measured growth and metabolic rates of surviving hatchlings. Results showed reduced embryo survival and decreased hatchling growth for lizards reared under sublethal warming, suggesting that thermal constraints on the physiology of developing Eastern fence lizards may limit the persistence of the species under climate warming

The complete LQG propagator: II. Asymptotic behavior of the vertex

In a previous article we have show that there are difficulties in obtaining the correct graviton propagator from the loop-quantum-gravity dynamics defined by the Barrett-Crane vertex amplitude. Here we show that a vertex amplitude that depends nontrivially on the intertwiners can yield the correct propagator. We give an explicit example of asymptotic behavior of a vertex amplitude that gives the correct full graviton propagator in the large distance limit.Comment: 16 page

Giant g factor tuning of long-lived electron spins in Ge

Control of electron spin coherence via external fields is fundamental in spintronics. Its implementation demands a host material that accommodates the highly desirable but contrasting requirements of spin robustness to relaxation mechanisms and sizeable coupling between spin and orbital motion of charge carriers. Here we focus on Ge, which, by matching those criteria, is rapidly emerging as a prominent candidate for shuttling spin quantum bits in the mature framework of Si electronics. So far, however, the intrinsic spin-dependent phenomena of free electrons in conventional Ge/Si heterojunctions have proved to be elusive because of epitaxy constraints and an unfavourable band alignment. We overcome such fundamental limitations by investigating a two dimensional electron gas (2DEG) confined in quantum wells of pure Ge grown on SiGe-buffered Si substrates. These epitaxial systems demonstrate exceptionally long spin relaxation and coherence times, eventually unveiling the potential of Ge in bridging the gap between spintronic concepts and semiconductor device physics. In particular, by tuning spin-orbit interaction via quantum confinement we demonstrate that the electron Land\'e g factor and its anisotropy can be engineered in our scalable and CMOS-compatible architectures over a range previously inaccessible for Si spintronics

Stable classical structures in dissipative quantum chaotic systems

We study the stability of classical structures in chaotic systems when a dissipative quantum evolution takes place. We consider a paradigmatic model, the quantum baker map in contact with a heat bath at finite temperature. We analyze the behavior of the purity, fidelity and Husimi distributions corresponding to initial states localized on short periodic orbits (scar functions) and map eigenstates. Scar functions, that have a fundamental role in the semiclassical description of chaotic systems, emerge as very robust against environmental perturbations. This is confirmed by the study of other states localized on classical structures. Also, purity and fidelity show a complementary behavior as decoherence measures.Comment: 4 pages, 3 figure