489 research outputs found
Understanding the open circuit voltage in organic solar cells on the basis of a donor-acceptor abrupt (p-n++) heterojunction
By using electrical characterization and classical solid state semiconductor device theory, we demonstrate that the open circuit voltage (V oc ) in organic solar cells based on non-intentional doped semiconductors is fundamentally limited by the built-in potential (V bi ) originated at a donor-acceptor abrupt (p-n ++ ) heterojunction in case of selective contacts. Our analysis is validated using P3HT:PCBM devices fabricated in our research group. We also demonstrate that such a result can be generalized using data already reported in literature for fullerene-based solar cells. Finally, we show that the dependence of V oc on the device contacts can be understood in terms of the potential barriers formed by the Fermi level alignment of semiconductors at the heterojunction and at the Schottky junctions
Increasing organic solar cell efficiency with polymer interlayers
We demonstrate how organic solar cell efficiency can be increased by introducing a pure polymer interlayer between the PEDOT:PSS layer and the polymer: fullerene blend. We observe an increase in device efficiency with three different material systems over a number of devices. Using both electrical characterization and numerical modeling we show that the increase in efficiency is caused by optical absorption in the pure polymer layer and hence efficient charge separation at the polymer bulkheterojunction interface
Self-Dual Bending Theory for Vesicles
We present a self-dual bending theory that may enable a better understanding
of highly nonlinear global behavior observed in biological vesicles. Adopting
this topological approach for spherical vesicles of revolution allows us to
describe them as frustrated sine-Gordon kinks. Finally, to illustrate an
application of our results, we consider a spherical vesicle globally distorted
by two polar latex beads.Comment: 10 pages, 3 figures, LaTeX2e+IOPar
Status of the CRESST Dark Matter Search
The CRESST experiment aims for a detection of dark matter in the form of
WIMPs. These particles are expected to scatter elastically off the nuclei of a
target material, thereby depositing energy on the recoiling nucleus. CRESST
uses scintillating CaWO4 crystals as such a target. The energy deposited by an
interacting particle is primarily converted to phonons which are detected by
transition edge sensors. In addition, a small fraction of the interaction
energy is emitted from the crystals in the form of scintillation light which is
measured in coincidence with the phonon signal by a separate cryogenic light
detector for each target crystal. The ratio of light to phonon energy permits
the discrimination between the nuclear recoils expected from WIMPs and events
from radioactive backgrounds which primarily lead to electron recoils. CRESST
has shown the success of this method in a commissioning run in 2007 and, since
then, further investigated possibilities for an even better suppression of
backgrounds. Here, we report on a new class of background events observed in
the course of this work. The consequences of this observation are discussed and
we present the current status of the experiment.Comment: Proceedings of the 13th International Workshop on Low Temperature
Detectors, 4 pages, 3 figure
Composite CaWO4 Detectors for the CRESST-II Experiment
CRESST-II, standing for Cryogenic Rare Events Search with Superconducting
Thermometers phase II, is an experiment searching for Dark Matter. In the LNGS
facility in Gran Sasso, Italy, a cryogenic detector setup is operated in order
to detect WIMPs by elastic scattering off nuclei, generating phononic lattice
excitations and scintillation light. The thermometers used in the experiment
consist of a tungsten thin-film structure evaporated onto the CaWO4 absorber
crystal. The process of evaporation causes a decrease in the scintillation
light output. This, together with the need of a big-scale detector production
for the upcoming EURECA experiment lead to investigations for producing
thermometers on smaller crystals which are glued onto the absorber crystal. In
our Run 31 we tested composite detectors for the first time in the Gran Sasso
setup. They seem to produce higher light yields as hoped and could provide an
additional time based discrimination mechanism for low light yield clamp
events.Comment: Proceedings of the Thirteenth International Workshop on Low
Temperature Detectors 4 pages, 9 figure
Displacement of polarons by vibrational modes in doped conjugated polymers
Organic pi-conjugated polymers are deemed to be soft materials with strong electron-phonon coupling, which results in the formation of polarons, i.e., charge carriers dressed by self-localized distortion of the nuclei. Universal signatures for polarons are optical resonances below the band gap and intense vibrational modes (IVMs), both found in the infrared (IR) spectral region. Here, we study p-doped conjugated homo-and copolymers by combining first-principles modelling and optical spectroscopy from the far-IR to the visible. Polaronic IVMs are found to feature absorption intensities comparable to purely electronic transitions and, most remarkably, show only loose resemblance to the Raman or IR-active modes of the neutral polymer. The IVM frequency is dramatically scaled down (up to 50%) compared to the backbone carbon-stretching modes in the pristine polymers. The very large intensity of IVMs is associated with displacement of the excess positive charge along the backbone driven by specific vibrational modes. We propose a quantitative picture for the identification of these polaron shifting modes that solely based on structural information, directly correlates with their IR intensity. This finding finally discloses the elusive microscopic mechanism behind the huge IR intensity of IVMs in doped polymeric semiconductors
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