Re-melting behaviour and wear resistance of vanadium carbide precipitating Cr27.5Co14Fe22Mo22Ni11.65V2.85 high entropy alloy

High entropy alloys (HEAs) are among of the most promising new metal material groups. The achievable properties can exceed those of common alloys in different ways. Due to the mixture of five or more alloying elements, the variety of high entropy alloys is fairly huge. The presented work will focus on some first insights on the weldability and the wear behavior of vanadium carbide precipitation Cr27.5Co14Fe22Mo22Ni11.65V2.85 HEA. The weldability should always be addressed in an early stage of any alloy design to avoid welding-related problems afterwards. The cast Cr27.5Co14Fe22Mo22Ni11.65V2.85 HEA has been remelted using a TIG welding process and the resulting microstructure has been examined. The changes in the microstructure due to the remelting process showed little influence of the welding process and no welding-related problems like hot cracks have been observed. It will be shown that vanadium carbides or vanadium-rich phases precipitate after casting and remelting in a two phased HEA matrix. The hardness of the as cast alloy is 324HV0.2 and after remelting the hardness rises to 339HV0.2. The wear behavior can be considered as comparable to a Stellite 6 cobalt base alloy as determined in an ASTM G75 test. Overall, the basic HEA design is promising due to the precipitation of vanadium carbides and should be further investigated

Wire and arc additive manufacturing of a CoCrFeMoNiV complex concentrated alloy using metal-cored wire: process, properties, and Wear Resistance

The field of complex concentrated alloys offers a very large number of variations in alloy composition. The achievable range of properties varies greatly within these variants. The experimental determination of the properties is in many cases laborious. In this work, the possibility of using metal-cored wires to produce sufficient large samples for the determination of the properties using arc-based additive manufacturing or in detail wire and arc additive manufacturing (WAAM) is to be demonstrated by giving an example. In the example, a cored wire is used for the production of a CoCrFeNiMo alloy. In addition to the process parameters used for the additive manufacturing, the mechanical properties of the alloy produced in this way are presented and related to the properties of a cast sample with a similar chemical composition. The Characterization of the resulting microstructure and wear resistance will complete this work. It will be shown that it is possible to create additively manufactured structures for a microstructure and a property determination by using metal-cored filler wires in arc-based additive manufacturing. In this case, the additively manufactured structure shows an FCC two-phased microstructure, a yield strength of 534 MPa, and a decent wear resistance

Stochastic Resonance Whole-Body Vibration Improves Postural Control in Health-Care Professionals: A Worksite Randomised Controlled Trial.

AIM To investigate the acute effects of stochastic resonance whole body vibration (SR-WBV), including muscle relaxation and cardiovascular activation. METHODS Sixty-four healthy students participated. The participants were randomly assigned to sham SR-WBV training at a low intensity (1.5 Hz) or a verum SR-WBV training at a higher intensity (5 Hz). Systolic blood pressure (SBP), diastolic blood pressure (DBP), heart rate (HR) and self-reported muscle relaxation were assessed before and immediately after SR-WBV. RESULTS Two factorial analyses of variance (ANOVA) showed a significant interaction between pre- vs post-SR-WBV measurements and SR-WBV conditions for muscle relaxation in the neck and back [F(1,55) = 3.35, P = 0.048, η2 = 0.07]. Muscle relaxation in the neck and back increased in verum SR-WBV, but not in sham SR-WBV. No significant changes between pre- and post-training levels of SBD, DBD and HR were observed either in sham or verum SR-WBV conditions. With verum SR-WBV, improved muscle relaxation was the most significant in participants who reported the experience of back, neck or shoulder pain more than once a month (P < 0.05). CONCLUSION A single session of SR-WBV increased muscle relaxation in young healthy individuals, while cardiovascular load was low. An increase in musculoskeletal relaxation in the neck and back is a potential mediator of pain reduction in preventive worksite SR-WBV trials. Key Words: Musculoskeletal system, Prevention, Blood pressure, Heart rate, Low back pain Core tip: This randomized controlled trial shows musculoskeletal relaxation to increase after application of a single training of stochastic resonance whole body vibration (SR-WBV). SR-WBV increased muscle relaxation especially in those who suffered from musculoskeletal pain in the last year. Participants reported improved muscular relaxation while the cardiovascular activation as indicated by blood pressure and heart rate was very low. In addition to ergonomic interventions SR-WBV contributes to prevent muscle related pain at work

1,2,3-Triphenyl-1,2-dihydro­quinoxaline

The title compound, C26H20N2, first reported in 1891, was obtained as a by-product in the preparation of benzildianil from benzil and excess aniline. The dihedral angles between the fused benzene ring and the pendant phenyl rings are 17.93 (11), 53.18 (10) and 89.08 (12)°

Forest Health Status in Europe

Forest health status in Europe is assessed by the International Cooperative Programme on Assessment and Monitoring of Air Pollution Effects on Forests (ICP Forests). Established by the Convention on Long-Range Transboundary Air Pollution (CLRTAP) under the United Nations Economic Commission for Europe (UNECE), the ICP Forests has been monitoring forest condition in close cooperation with the European Commission (EC) for 20 years. The present paper describes the latest results of the deposition measurements on permanent monitoring plots and of the extensive defoliation sample survey. The findings reveal marked spatial patterns in bulk and throughfall depositions of nitrate (N-NO3-), ammonium (N-NH4+), and sulfate (S-SO42-), as well as an obvious decrease in bulk and throughfall deposition of sulfate. Latest analyses of defoliation data confirm previous results, indicating a high correlation with weather extremes

Time Pressure, Time Autonomy, and Sickness Absenteeism in Hospital Employees: A Longitudinal Study on Organizational Absenteeism Records

Background Although work absenteeism is in the focus of occupational health, longitudinal studies on organizational absenteeism records in hospital work are lacking. This longitudinal study tests time pressure and lack of time autonomy to be related to higher sickness absenteeism. Methods Data was collected for 180 employees (45% nurses) of a Swiss hospital at baseline and at follow-up after 1 year. Absent times (hours per month) were received from the human resources department of the hospital. One-year follow-up of organizational absenteeism records were regressed on self-reported job satisfaction, time pressure, and time autonomy (i.e., control) at baseline. Results A multivariate regression showed significant prediction of absenteeism by time pressure at baseline and time autonomy, indicating that a stress process is involved in some sickness absenteeism behavior. Job satisfaction and the interaction of time pressure and time autonomy did not predict sickness absenteeism. Conclusion Results confirmed time pressure and time autonomy as limiting factors in healthcare and a key target in work redesign. Keywords healthcare ; occupational health ; time autonomy ; work absenteeism ; work stres

Airway management in a Helicopter Emergency Medical Service (HEMS): a retrospective observational study of 365 out-of-hospital intubations.

BACKGROUND Airway management is a key skill in any helicopter emergency medical service (HEMS). Intubation is successful less often than in the hospital, and alternative forms of airway management are more often needed. METHODS Retrospective observational cohort study in an anaesthesiologist-staffed HEMS in Switzerland. Patient charts were analysed for all calls to the scene (n = 9,035) taking place between June 2016 and May 2017 (12 months). The primary outcome parameter was intubation success rate. Secondary parameters included the number of alternative techniques that eventually secured the airway, and comparison of patients with and without difficulties in airway management. RESULTS A total of 365 patients receiving invasive ventilatory support were identified. Difficulties in airway management occurred in 26 patients (7.1%). Severe traumatic brain injury was the most common indication for out-of-hospital Intubation (n = 130, 36%). Airway management was performed by 129 different Rega physicians and 47 different Rega paramedics. Paramedics were involved in out-of-hospital airway manoeuvres significantly more often than physicians: median 7 (IQR 4 to 9) versus 2 (IQR 1 to 4), p < 0.001. CONCLUSION Despite high overall success rates for endotracheal intubation in the physician-staffed service, individual physicians get only limited real-life experience with advanced airway management in the field. This highlights the importance of solid basic competence in a discipline such as anaesthesiology

Modification of Co-Cr alloys to optimize additively welded microstructures and subsequent surface finishing

Cobalt chromium alloys are often used in turbine and plant construction. This is based on their high thermal and mechanical stress resistance as well as their high wear resistance to corrosive and abrasive loads. However, cobalt is a cost-intensive material that is difficult to machine. Moreover, increasingly complex structures and the optimisation of resource efficiency also require additive manufacturing steps for the production or repair of components in many sectors. Concerning inhomogeneity and anisotropy of the microstructure and properties as well as manufacturing-related stresses, a lot of knowledge is still necessary for the economic use of additive welding processes in SMEs. As a result of the high stresses on the components and requirements for a high surface quality, a complementary use of additive and machining manufacturing processes is necessary. Thereby, Co–Cr alloys are extremely challenging for machining with geometrically defined cutting edges because of their low thermal conductivity combined with high strength and toughness. An approach to solve this problem is to refine and homogenise the microstructure. This is achieved by modifying the alloy with elements zirconium and hafnium, which are added up to a maximum of 1 wt.-%. A reduction of the process forces and stresses on the tool and work piece surface is also achievable via hybrid milling processes. There are already studies on the combined use of additive and machining manufacturing processes based on laser technology. However, knowledge based on powder and wire-based arc processes is important, as these processes are more widespread. Furthermore, the effects on the surface zone of additively manufactured components by hybrid finish milling have not yet been a subject of research. The results show that the structural morphology could be significantly influenced with the addition of zirconium and hafnium

Forest Focus Monitoring Database System - Validation Methodology 2008

Forest Focus (Regulation (EC) No 2152/2003) is a Community scheme for harmonized, broadbased, comprehensive and long-term monitoring of European forest ecosystems. Under this scheme the monitoring of air pollution effects on forests is carried out by participating countries on the basis of the systematic network of observation points (Level I) and of the network of observation plots for intensive and continuous monitoring (Level II). According to Article 15(1) of the Forest Focus Regulation Member States shall annually, through the designated authorities and agencies, forward to the Commission geo-referenced data gathered under the scheme, together with a report on them by means of computer telecommunications and/or electronic technology. For managing the data JRC has implemented a Forest Focus Monitoring Database System. This report presents the methodology used to validate Level II data. The procedures applied at the various stages of checking data Compliance, Conformity and Uniformity are described. The report also provides detailed information on the interpretation of data formats and the threshold values used in the Conformity range tests.JRC.H.7-Land management and natural hazard