Recent Developments in Steelmaking Industry and Potential Alkali Activated Based Steel Waste: A Comprehensive Review

The steel industry is responsible for one-third of all global industrial CO2 emissions, putting pressure on the industry to shift forward towards more environmentally friendly production methods. The metallurgical industry is under enormous pressure to reduce CO2 emissions as a result of growing environmental concerns about global warming. The reduction in CO2 emissions is normally fulfilled by recycling steel waste into alkali-activated cement. Numerous types of steel waste have been produced via three main production routes, including blast furnace, electric arc furnace, and basic oxygen furnace. To date, all of the steel waste has been incorporated into alkali activation system to enhance the properties. This review focuses on the current developments over the last ten years in the steelmaking industry. This work also summarizes the utilization of steel waste for improving cement properties through an alkali activation system. Finally, this work presents some future research opportunities with regard to the potential of steel waste to be utilized as an alkali-activated material.</jats:p

Solidification/stabilization technology for radioactive wastes using cement: an appraisal

Across the world, any activity associated with the nuclear fuel cycle such as nuclear facility operation and decommissioning that produces radioactive materials generates ultramodern civilian radioactive waste, which is quite hazardous to human health and the ecosystem. Therefore, the development of effectual and commanding management is the need of the hour to make certain the sustainability of the nuclear industries. During the management process of waste, its immobilization is one of the key activities conducted with a view to producing a durable waste form which can perform with sustainability for longer time frames. The cementation of radioactive waste is a widespread move towards its encapsulation, solidification, and finally disposal. Conventionally, Portland cement (PC) is expansively employed as an encapsulant material for storage, transportation and, more significantly, as a radiation safeguard to vigorous several radioactive waste streams. Cement solidification/stabilization (S/S) is the most widely employed treatment technique for radioactive wastes due to its superb structural strength and shielding effects. On the other hand, the eye-catching pros of cement such as the higher mechanical strength of the resulting solidified waste form, trouble-free operation and cost-effectiveness have attracted researchers to employ it most commonly for the immobilization of radionuclides. In the interest to boost the solidified waste performances, such as their mechanical properties, durability, and reduction in the leaching of radionuclides, vast attempts have been made in the past to enhance the cementation technology. Additionally, special types of cement were developed based on Portland cement to solidify these perilous radioactive wastes. The present paper reviews not only the solidification/stabilization technology of radioactive wastes using cement but also addresses the challenges that stand in the path of the design of durable cementitious waste forms for these problematical functioning wastes. In addition, the manuscript presents a review of modern cement technologies for the S/S of radioactive waste, taking into consideration the engineering attributes and chemistry of pure cement, cement incorporated with SCM, calcium sulpho–aluminate-based cement, magnesium-based cement, along with their applications in the S/S of hazardous radioactive wastes

Behavior of Alkali-Activated Fly Ash through Underwater Placement

Underwater concrete is a cohesive self-consolidated concrete used for concreting underwater structures such as bridge piers. Conventional concrete used anti-washout admixture (AWA) to form a high-viscosity underwater concrete to minimise the dispersion of concrete material into the surrounding water. The reduction of quality for conventional concrete is mainly due to the washing out of cement and fine particles upon casting in the water. This research focused on the detailed investigations into the setting time, washout effect, compressive strength, and chemical composition analysis of alkali-activated fly ash (AAFA) paste through underwater placement in seawater and freshwater. Class C fly ash as source materials, sodium silicate, and sodium hydroxide solution as alkaline activator were used for this study. Specimens produced through underwater placement in seawater showed impressive performance with strength 71.10 MPa on 28 days. According to the Standard of the Japan Society of Civil Engineers (JSCE), the strength of specimens for underwater placement must not be lower than 80% of the specimen’s strength prepared in dry conditions. As result, the AAFA specimens only showed 12.11% reduction in strength compared to the specimen prepared in dry conditions, thus proving that AAFA paste has high potential to be applied in seawater and freshwater applications.</jats:p

The Suitability of Photocatalyst Precursor Materials in Geopolymer Coating Applications: A Review

Today, the building and construction sector demands environmentally friendly and sustainable protective coatings using inorganic coating materials for safe, non-hazardous, and great performance. Many researchers have been working on sustainable solutions to protect concrete and metal infrastructures against corrosion and surface deterioration with the intention of introducing green alternatives to conventional coatings. This article presents a review of developments of geopolymer pastes doped with different types of photocatalyst precursors including factors affecting geopolymer properties for enhancing coating with photocatalytic performance. Photodegradation using geopolymer photocatalyst has great potential for resolving harmless substances and removing pollutants when energized with ultraviolet (UV) light. Although geopolymer is a potentially new material with great properties, there has been less research focusing on the development of this coating. This study demonstrated that geopolymer binders are ideal precursor support materials for the synthesis of photocatalytic materials, with a significant potential for optimizing their distinctive properties

A theoretical approach of the heat transfer in nanofluids

Using the fractal space-time theory (scale relativity theory), the dynamics of the fluid/nano-particle interface was analyzed. In the general case, the heat transfer through the interface reproduces a d.c. or an a.c. Josephson effects of thermal type, while in the linear approximation, the standard form of heat transfer is given. Consequently, a negative differential thermal conductance appears and an increase in of heat transfer in nanofluids results. © 2007 The Japan Institute of Metals

Wave-particle duality through an extended model of the scale relativity theory

Considering that the chaotic effect of associated wave packet on the particle itself results in movements on the fractal (continuous and non-differentiable) curves of fractal dimension DF, wave-particle duality through an extension of the scale relativity theory is given. It results through an equation of motion for the complex speed field, that in a fractal fluid, the convection, dissipation and dispersion are reciprocally compensating at any scale (differentiable or non-differentiable). From here, for an irrotational movement, a generalized Schrödinger equation is obtained. The absence of dispersion implies a generalized Navier-Stokes type equation, whereas, for the irrotational movement and the fractal dimension, DF = 2, the usual Schrödinger equation results. The absence of dissipation implies a generalized Korteweg-de Vries type equation. In such conjecture, at the differentiable scale, the duality is achieved through the flowing regimes of the fractal fluid, i.e. the wave character by means of the non-quasi-autonomous flowing regime and the particle character by means of the quasi-autonomous flowing regime. These flowing regimes are separated by &apos;0.7 structure&apos;. At the non-differentiable scale, a fractal potential acts as an energy accumulator and controls through the coherence the duality. The correspondence between the differentiable and non-differentiable scales implies a Cantor space-time. Moreover, the wave-particle duality implies at any scale a fractal. © 2008 The Royal Swedish Academy of Sciences

Fractal characteristics of the solidification process

Assimilating the solid-liquid interface to a binary domain described by a set of coupled equations, one studies the solidification process. The numerical solutions of the thermal breather, the thermal breather pair and the thermal cluster type are associated to a virtual crystallization germ, a stable crystallization germ and a crystalline grain, respectively. The fractal characteristics of the solidification process are analyzed by means of fractal dimension dynamics

Ceramics and Composites

В книге представлен современный обзор керамики и композитов. Она фокусируется на гибком и эффективном производстве изделий определенной формы, сложности и индивидуальных характеристик и свойств.Используемые программы Adobe AcrobatThe book presents a state-of-the-art survey of ceramics and composites. It focuses on the flexible and efficient manufacture of objects with specific shapes, complexity and tailor-made characteristics and properties