Comparison of measurements of peroxyacyl nitrates and primary carbonaceous aerosol concentrations in Mexico City determined in 1997 and 2003

International audiencePeroxyacetyl nitrate (PAN) concentrations in ambient air can be a good indicator of air quality and the effectiveness of control strategies for reducing ozone levels in urban areas. As PAN is formed by the oxidation of reactive hydrocarbons in the presence of nitrogen dioxide (NO2), it is a direct measure of the peroxyacyl radical levels produced from reactive organic emissions in the urban air shed. Carbon soot, known as black carbon or elemental carbon, is a primary atmospheric aerosol species and is a good indicator of the levels of combustion emissions, particularly from diesel engines, in major cities. Mexico City is the second largest megacity in the world and has long suffered from poor air quality. Reported here are atmospheric measurements of PAN and black carbon obtained in Mexico City during the Mexico Megacity 2003 field study. These results are compared with measurements obtained earlier during the Investigación sobre Materia Particulada y Deterioro Atmosférico ? Aerosol and Visibility Research (IMADA-AVER) campaign in 1997 to obtain an estimate of the changes in emissions in Mexico City and the effectiveness of control strategies adopted during that time. Concentrations of PAN in 1997 reached a maximum of 34 ppb with an average daily maximum of 15 ppb. The PAN levels recorded in 2003 were quite different, with an average daily maximum of 3 ppb. This dramatic reduction in PAN levels observed in 2003 indicate that reactive hydrocarbon emissions have been reduced in the city due to controls on olefins in liquefied petroleum gas (LPG) and also due to the significant number of newer vehicles with catalytic converters that have replaced older higher emission vehicles. In contrast, black/elemental carbon levels were similar in 1997 and 2003 indicating little improvement likely due to the lack of controls on diesel vehicles in the city. Thus, while air quality and ozone production has improved, Mexico City and other megacities continue to be a major source of black carbon aerosols, which can be an important species in determining regional radiative balance and climate

Edge phonons in black phosphorus

Exfoliated black phosphorus has recently emerged as a new two-dimensional crystal that, due to its peculiar and anisotropic crystalline and electronic band structures, may have potentially important applications in electronics, optoelectronics and photonics. Despite the fact that the edges of layered crystals host a range of singular properties whose characterization and exploitation are of utmost importance for device development, the edges of black phosphorus remain poorly characterized. In this work, the atomic structure and the behavior of phonons near different black phosphorus edges are experimentally and theoretically studied using Raman spectroscopy and density functional theory calculations. Polarized Raman results show the appearance of new modes at the edges of the sample, and their spectra depend on the atomic structure of the edges (zigzag or armchair). Theoretical simulations confirm that the new modes are due to edge phonon states that are forbidden in the bulk, and originated from the lattice termination rearrangements.Comment: 15 pages, 4 figure

Chitosan in wine industry: identification of origin by a multidisciplinary approach and application in oenology

Aim: Chitosan is a promising antimicrobial agent, capable of providing control of a wide range of spoilage microorganisms. To guarantee the fugal origin of chitosan, the only authorized for oenological practices, a multidisciplinary approach based on the measurement of the stable isotope ratios, Fourier transform infrared spectrometry and thermogravimetric analysis was proposed. In addition, the activity of chitosan against food related microorganisms was evaluated by different experiments aimed to discriminate between chemical and physical action of chitosan vs. the microorganisms. Method: The measurement of the stable isotope ratios (SIR) of carbon δ13C, nitrogen δ15N, oxygen δ18O and hydrogen δ2H of 35 samples of chitosan and the data of maximum degradation temperatures (obtained by TGA) combined with those of the peak areas of amide I and NH2/Amide II (obtained by FTIR) were employed to discriminate chitosan different sources (fungal grown on different substrates vs crustacean). The antimicrobial activity was tested in static and stirred conditions, in a synthetic media, using type strains of most common technological or spoilage microorganism. Viability was evaluated by Petri plate counts. The activity of the soluble portion of chitosan was checked by inoculating microorganisms in the media after chitosan removal. Results: The Kruskal-Wallis test showed that δ13C and δ18O were the most significant parameters able to classified chitosan into three different groups (from fungus grown on C3 photosynthetic cycle plant substrate, from fungus on C4 substrate and from crustacean). HCA and PCA analysis based on TGA, FTIR and SIR data successfully distributed the tested samples into informative clusters. Tests of chitosan antimicrobial activity highlighted the different sensitivity of microorganisms to chitosans, allowing selective control of spoilage agents. However, yeast and bacteria involved in fermentation were damaged by chitosan, and the synthetic media treated with this molecule showed a less fermentative aptitude. Conclusion: A robust analytical strategy for the correct identification of chitosan samples from crustaceans or fungi was presented, based on the observation that diverse biosynthetic pathways during the formation of the chitin influenced the isotopic composition of chitosan. Results of toxicity tests suggest that chitosan is a promising tool in fermented beverage production, but an in-depth study of the biochemical interaction between chitosan and food microorganisms is necessary

Geomagnetic anomalies observed at volcano Popocatepetl, Mexico

International audienceResults of the ULF geomagnetic monitoring of the volcano Popocatepetl (Mexico) and their analysis are summarized and presented for the period 2003?2006. Our analysis reveals some anomalies which are considered to be of local volcanic origin: the EM background in the vicinity of the volcano was found to be significantly noisier than at other reference stations; sporadic strong noise-like geomagnetic activity was observed in the H-component; some geomagnetic pulsations were observed only at the Tlamacas station (located at 4 km near the volcano). The results are discussed in terms of a physical mechanism involving the presence of a second magmatic chamber within the volcano and, finally, further perspective directions to study volcanic geodynamical processes besides the traditional ones are given

Optical absorption and photoluminescence spectroscopy of the growth of silver nanoparticles

Results obtained from the optical absorption and photoluminescence (PL) spectroscopy experiments have shown the formation of excitons in the silver-exchanged glass samples. These findings are reported here for the first time. Further, we investigate the dramatic changes in the photoemission properties of the silver-exchanged glass samples as a function of postannealing temperature. Observed changes are thought to be due to the structural rearrangements of silver and oxygen bonding during the heat treatments of the glass matrix. In fact, photoelectron spectroscopy does reveal these chemical transformations of silver-exchanged soda glass samples caused by the thermal effects of annealing in a high vacuum atmosphere. An important correlation between temperature-induced changes of the PL intensity and thermal growth of the silver nanoparticles has been established in this Letter through precise spectroscopic studies.Comment: 15 pages,4 figures,PDF fil

Spanning tree generating functions and Mahler measures

We define the notion of a spanning tree generating function (STGF) $\sum a_n z^n$, which gives the spanning tree constant when evaluated at $z=1,$ and gives the lattice Green function (LGF) when differentiated. By making use of known results for logarithmic Mahler measures of certain Laurent polynomials, and proving new results, we express the STGFs as hypergeometric functions for all regular two and three dimensional lattices (and one higher-dimensional lattice). This gives closed form expressions for the spanning tree constants for all such lattices, which were previously largely unknown in all but one three-dimensional case. We show for all lattices that these can also be represented as Dirichlet $L$-series. Making the connection between spanning tree generating functions and lattice Green functions produces integral identities and hypergeometric connections, some of which appear to be new.Comment: 26 pages. Dedicated to F Y Wu on the occasion of his 80th birthday. This version has additional references, additional calculations, and minor correction

A Deep View of a Fossil Relic in the Galactic Bulge: The Globular Cluster HP \,1

HP$\,$1 is an $\alpha$-enhanced and moderately metal-poor bulge globular cluster with a blue horizontal branch. These combined characteristics make it a probable relic of the early star formation in the innermost Galactic regions. Here we present a detailed analysis of a deep near-infrared (NIR) photometry of HP$\,$1 obtained with the NIR GSAOI+GeMS camera at the Gemini-South telescope. $J$ and $K_{\rm S}$ images were collected with an exquisite spatial resolution (FWHM $\sim 0.1$ arcsec), reaching stars at two magnitudes below the MSTO. We combine our GSAOI data with archival F606W-filter $HST$ ACS/WFC images to compute relative proper motions and select bona fide cluster members. Results from statistical isochrone fits in the NIR and optical-NIR colour-magnitude diagrams indicate an age of $12.8^{+0.9}_{-0.8}$ Gyr, confirming that HP$\,$1 is one of the oldest clusters in the Milky Way. The same fits also provide apparent distance moduli in the $K_{\rm S}$ and $V$ filters in very good agreement with the ones from 11 RR Lyrae stars. By subtracting the extinction in each filter, we recover a heliocentric distance of $6.59^{+0.17}_{-0.15}$ kpc. Furthermore, we refine the orbit of HP$\,$1 using this accurate distance and update and accurate radial velocities (from high resolution spectroscopy) and absolute proper motions (from Gaia DR2), reaching mean perigalactic and apogalactic distances of $\sim$0.12 and $\sim$3 kpc respectively.Comment: 22 pages, 22 figures, accepted for publication in MNRA