Anomalous temperature dependence of the band-gap in Black Phosphorus

Black Phosphorus (BP) has gained renewed attention due to its singular anisotropic electronic and optical properties that might be exploited for a wide range of technological applications. In this respect, the thermal properties are particularly important both to predict its room temperature operation and to determine its thermoelectric potential. From this point of view, one of the most spectacular and poorly understood phenomena is, indeed, the BP temperature-induced band-gap opening: when temperature is increased the fundamental band-gap increases instead of decreasing. This anomalous thermal dependence has also been observed, recently, in its monolayer counterpart. In this work, based on \textit{ab-initio} calculations, we present an explanation for this long known, and yet not fully explained, effect. We show that it arises from a combination of harmonic and lattice thermal expansion contributions, which are, in fact, highly interwined. We clearly narrow down the mechanisms that cause this gap opening by identifying the peculiar atomic vibrations that drive the anomaly. The final picture we give explains both the BP anomalous band-gap opening and the frequency increase with increasing volume (tension effect).Comment: Published in Nano Letter

Cluster size entropy in the Axelrod model of social influence: small-world networks and mass media

We study the Axelrod's cultural adaptation model using the concept of cluster size entropy, $S_{c}$ that gives information on the variability of the cultural cluster size present in the system. Using networks of different topologies, from regular to random, we find that the critical point of the well-known nonequilibrium monocultural-multicultural (order-disorder) transition of the Axelrod model is unambiguously given by the maximum of the $S_{c}(q)$ distributions. The width of the cluster entropy distributions can be used to qualitatively determine whether the transition is first- or second-order. By scaling the cluster entropy distributions we were able to obtain a relationship between the critical cultural trait $q_c$ and the number $F$ of cultural features in regular networks. We also analyze the effect of the mass media (external field) on social systems within the Axelrod model in a square network. We find a new partially ordered phase whose largest cultural cluster is not aligned with the external field, in contrast with a recent suggestion that this type of phase cannot be formed in regular networks. We draw a new $q-B$ phase diagram for the Axelrod model in regular networks.Comment: 21 pages, 7 figure

Bond behavior of self consolidating concrete

The new generation of innovative projects has led to the use of greater amounts of reinforcement and the development of concrete with specific characteristics. It is necessary to use a material that ensures the uniformity of the cross section, as well as the adherence of the existing reinforcement, and due to this, the self-consolidating concrete becomes an technique alternative has great potential to achieve these properties. The aim of this paper is to analyze the bond behavior of self-consolidating concrete that was obtained by means of the Beam Test performed within a large experimental campaign of characterization. Four types of SCC were studied with two strength levels (40 MPa and 60MPa) and two different types of granular skeletons, using two specimens at each age (3, 7, and 28 days). All specimens were tested with a corrugated steel bar 10 mm in diameter. The results show that the adhesion tension independently of resistance presents a rapidly evolving at 7 days reached 95% of the total adhesion by 28 days.Postprint (published version

Effects of Soil Silicon Amendment and Nitrogen Levels on Rice Insect Pest Complex

Rice plants are consistently subjected to various pressures by insect pests throughout the growing season. The main insect pest complex reported in Louisiana are the rice water weevil (major early-season insect pest), fall armyworm (sporadic early-season pest), sugarcane borer and rice stalk borer (long- established but sporadic stem boring pests), Mexican rice borer (an invasive stem-boring pest), and rice stink bug (major late-season pest). Soil silicon amendment has been shown to enhance plant resistance against herbivorous pests. Rice is a typical silicon-accumulating graminaceous crop. Field and greenhouse experiments were conducted from 2015 to 2017 to investigate the effects of soil silicon amendment and nitrogen levels on the rice insect pest complex In Louisiana. In the greenhouse, we found that force required to penetrate rice stem was higher on silicon-treated rice plants compared to untreated plants. Total phenolic content on the other hand, decreased when nitrogen rate was increased. In the field experiment, the effects of soil silicon amendment on rice water weevil densities, whitehead incidences, stink bug population, and yields were found to be weaker than the effects of nitrogen fertilization. Furthermore, separate field experiments were conducted in 2016 and 2017 to investigate the effects of silicon fertilization and rice cultivars on the rice insect pests. Results showed reductions in weevil larval densities in silicon treated plots compared to untreated plots in one core sampling in 2016. Similarly, higher yields were observed in silicon treated plots compared to untreated plots in 2016. Silicon amendment did not affect whitehead incidences and rice stink bug densities in both years. The levels of infestations of rice water weevil, stem borers, and rice stink bugs were also were also found to vary among the rice cultivars evaluated in the study. Despite the weak effect of silicon on insect pests in this study, silicon could still play an important role in rice production considering the positive effects on yield and documented effects on disease suppression

Vaccination of Cattle with the N Terminus of LppQ of Mycoplasma mycoides subsp. mycoides Results in Type III Immune Complex Disease upon Experimental Infection

Contagious bovine pleuropneumonia (CBPP) is a serious respiratory disease of cattle caused by Mycoplasma mycoides subsp. mycoides. Current vaccines against CBPP induce short-lived immunity and can cause severe postvaccine reactions. Previous studies have identified the N terminus of the transmembrane lipoprotein Q (LppQ-N') of M. mycoides subsp. mycoides as the major antigen and a possible virulence factor. We therefore immunized cattle with purified recombinant LppQ-N' formulated in Freund's adjuvant and challenged them with M. mycoides subsp. mycoides. Vaccinated animals showed a strong seroconversion to LppQ, but they exhibited significantly enhanced postchallenge glomerulonephritis compared to the placebo group (P = 0.021). Glomerulonephritis was characterized by features that suggested the development of antigen-antibody immune complexes. Clinical signs and gross pathological scores did not significantly differ between vaccinated and placebo groups. These findings reveal for the first time the pathogenesis of enhanced disease as a result of antibodies against LppQ during challenge and also argue against inclusion of LppQ-N' in a future subunit vaccine for CBPP

Solution structure of ψ(32)-modified anticodon stem–loop of Escherichia coli tRNA(Phe)

Nucleoside base modifications can alter the structures and dynamics of RNA molecules and are important in tRNAs for maintaining translational fidelity and efficiency. The unmodified anticodon stem–loop from Escherichia coli tRNA(Phe) forms a trinucleotide loop in solution, but Mg(2+) and dimethylallyl modification of A(37) N6 destabilize the loop-proximal base pairs and increase the mobility of the loop nucleotides. The anticodon arm has three additional modifications, ψ(32), ψ(39), and A(37) C2-thiomethyl. We have used NMR spectroscopy to investigate the structural and dynamical effects of ψ(32) on the anticodon stem-loop from E.coli tRNA(Phe). The ψ(32) modification does not significantly alter the structure of the anticodon stem–loop relative to the unmodified parent molecule. The stem of the RNA molecule includes base pairs ψ(32)-A(38) and U(33)–A(37) and the base of ψ(32) stacks between U(33) and A(31). The glycosidic bond of ψ(32) is in the anti configuration and is paired with A(38) in a Watson–Crick geometry, unlike residue 32 in most crystal structures of tRNA. The ψ(32) modification increases the melting temperature of the stem by ∼3.5°C, although the ψ(32) and U(33) imino resonances are exchange broadened. The results suggest that ψ(32) functions to preserve the stem integrity in the presence of additional loop modifications or after reorganization of the loop into a translationally functional conformation