Metaldehyde removal from drinking water by adsorption onto filtration media: mechanisms and optimisation

Trace micropollutants should be removed during drinking water production without increasing the disinfection-by-product formation potential or energy demand of the treatment process. We demonstrate the efficacy of different filtration media to remove metaldehyde through controlled batch experiments on water augmented with metaldehyde. Equilibrium concentrations of metaldehyde and surrogate organics were successfully described by the Freundlich isotherm. Metaldehyde can be attenuated to varying degrees with activated carbon and sand with an active and inactive biofilm with kf values ranging from 0.006–0.3 (mg g−1)(L mg−1)1/n. The presence of the active biofilm improved metaldehyde adsorption by sand media, due to additional biosorption mechanisms, a greater surface area or biodegradation. Baseline levels of competing natural organic matter surrogates (NOM) reduced overall adsorption efficacy but increasing concentrations of NOM did not impact metaldehyde removal efficacy in a significant way. Biological activated carbon was identified as the most suitable adsorbent of metaldehyde (94% removal) but sand with an acclimated biofilm was capable of acting as a bio-adsorbent of metaldehyde even under environmentally relevant concentrations (41% adsorption from 0.002.5 mg L−1). Moreover, we observed that thermal hydrolysis of metaldehyde occurred at 60 °C, suggesting that thermal regeneration of GAC for this pesticide was possible at relatively low temperatures. Biological adsorption and thermal hydrolysis approaches presented herein offered a way forward to increase efficiency and cost effectiveness of existing treatments for metaldehyde

Ricerche di Geomatica 2011

Questo volume raccoglie gli articoli che hanno partecipato al Premio AUTeC 2011. Il premio è stato istituito nel 2005. Viene conferito ogni anno ad una tesi di Dottorato giudicata particolarmente significativa sui temi di pertinenza del SSD ICAR/06 (Topografia e Cartografia) nei diversi Dottorati attivi in Italia

Relationships with Parents, Motivation Factors, and Resilience in Latinx College Students

This study used both parental factors and students’ individual motivational factors to understand college students’ academic achievement and resilience. Students bring various strengths with them to college that may be especially important as they experience challenges, including individual motivational strategies and joint collaboration with parents in pursuing educational goals (parental shared agency). Based on cultural backgrounds and values, we hypothesized differences between parental shared agencies for White and Latinx students. Consistent with previous literature, we expected parental shared agencies and motivational factors to independently predict high levels of academic buoyancy and academic achievement, respectively. Unique to this study, we proposed an interaction between shared agency and motivation in predicting academic outcomes. College students at a rural postsecondary institution in California were surveyed (N = 98). Participants completed an online questionnaire that contained the Academic Buoyancy Scale (Martin & Marsh, 2008), the Shared Agency Scale (Chang, 2009), and the Optimization in Primary and Secondary Control Scales in the Domain of Education (Heckhausen, 1998). Results show no significant differences between Latinx and White students in parental shared agencies. Similarly, no significant results were found in the hierarchical regression models predicting academic buoyancy nor academic achievement. Further research with a larger sample size is needed to gain additional insights into the constructs at hand. Further exploration of these factors may also lead us to understand the achievement gap using a strengths-based perspective, allowing us to consider suitable interventions

Analysis and correction of the magnetic field effects in the Hybrid Photo-Detectors of the RICH2 Ring Imaging Cherenkov detector of LHCb

The Ring Imaging Cherenkov detectors of the LHCb experiment at the Large Hadron Collider at CERN are equipped with Hybrid Photo-Detectors. These vacuum photo-detectors are affected by the stray magnetic field of the LHCb magnet, which degrades their imaging properties. This effect increases the error on the Cherenkov angle measurement and would reduce the particle identification capabilities of LHCb. A system has been developed for the RICH2 Ring Imaging Cherenkov detector to perform a detailed characterisation of the magnetic distortion effects. It is described, along with the methods implemented to correct for these effects, restoring the optimal resolution.Comment: 16 pages, 11 figure

3D MODELING FOR UNDERWATER ARCHAEOLOGICAL DOCUMENTATION: METRIC VERIFICATIONS

The survey in underwater environment has always presented considerable difficulties both operative and technical and this has sometimes made it difficult to use the techniques of survey commonly used for the documentation of Cultural Heritage in dry environment. The work of study concerns the evaluation in terms of capability and accuracy of the Autodesk123DCatch software for the reconstruction of a three-dimensional model of an object in underwater context. The subjects of the study are models generated from sets of photographs and sets of frames extracted from video sequence. The study is based on comparative method, using a reference model, obtained with laser scanner technique

The effect of spatial resolution on optical and near-IR studies of stellar clusters: Implications for the origin of the red excess

Recent ground based near-IR studies of stellar clusters in nearby galaxies have suggested that young clusters remain embedded for 7-10Myr in their progenitor molecular cloud, in conflict with optical based studies which find that clusters are exposed after 1-3Myr. Here, we investigate the role that spatial resolution plays in this apparent conflict. We use a recent catalogue of young ($5000$~\msun) clusters in the nearby spiral galaxy, M83, along with Hubble Space Telescope (HST) imaging in the optical and near-IR, and ground based near-IR imaging, to see how the colours (and hence estimated properties such as age and extinction) are affected by the aperture size employed, in order to simulate studies of differing resolution. We find that the near-IR is heavily affected by the resolution, and when aperture sizes $>40$~pc are used, all young/blue clusters move red-ward in colour space, which results in their appearance as heavily extincted clusters. However, this is due to contamination from nearby sources and nebular emission, and is not an extinction effect. Optical colours are much less affected by resolution. Due to the larger affect of contamination in the near-IR, we find that, in some cases, clusters will appear to show near-IR excess when large ($>20$~pc) apertures are used. Our results explain why few young ($<6$~Myr), low extinction (\av < 1~mag) clusters have been found in recent ground based near-IR studies of cluster populations, while many such clusters have been found in higher resolution HST based studies. Additionally, resolution effects appear to (at least partially) explain the origin of the near-IR excess that has been found in a number of extragalactic YMCs.Comment: 8 pages, 5 figures, accepted for publication in MNRA

Quantitative analysis of the morphological changes of the pubic symphyseal face and the auricular surface and implications for age at death estimation

YesAge estimation methods are often based on the age-related morphological changes of the auricular surface and the pubic bone. In this study, a mathematical approach to quantify these changes has been tested analyzing the curvature variation on 3D models from CT and laser scans. The sample consisted of the 24 Suchey–Brooks (SB) pubic bone casts, 19 auricular surfaces from the Buckberry and Chamberlain (BC) “recording kit” and 98 pelvic bones from the Terry Collection (Smithsonian Institution). Strong and moderate correlations between phases and curvature were found in SB casts (ρ 0.60–0.93) and BC “recording kit” (ρ 0.47–0.75), moderate and weak correlations in the Terry Collection bones (pubic bones: ρ 0.29–0.51, auricular surfaces: ρ 0.33–0.50) but associated with large individual variability and overlap of curvature values between adjacent decades. The new procedure, requiring no expert judgment from the operator, achieved similar correlations that can be found in the classic methods