971 research outputs found

    Rigorous Multicomponent Reactive Separations Modelling : Complete Consideration of Reaction-Diffusion Phenomena

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    This paper gives the first step of the development of a rigorous multicomponent reactive separation model. Such a model is highly essential to further the optimization of acid gases removal plants (CO2 capture, gas treating, etc.) in terms of size and energy consumption, since chemical solvents are conventionally used.Firstly, two main modelling approaches are presented: the equilibrium-based and the rate-based approaches. Secondly, an extended rate-based model with rigorous modelling methodology for diffusion-reaction phenomena is proposed. The film theory and the generalized Maxwell-Stefan equations are used in order to characterize multicomponent interactions. The complete chain of chemical reactions is taken into account. The reactions can be kinetically controlled or at chemical equilibrium, and they are considered for both liquid film and liquid bulk. Thirdly, the method of numerical resolution is described. Coupling the generalized Maxwell-Stefan equations with chemical equilibrium equations leads to a highly non-linear Differential-Algebraic Equations system known as DAE index 3. The set of equations is discretized with finite-differences as its integration by Gear method is complex. The resulting algebraic system is resolved by the Newton- Raphson method. Finally, the present model and the associated methods of numerical resolution are validated for the example of esterification of methanol. This archetype non-electrolytic system permits an interesting analysis of reaction impact on mass transfer, especially near the phase interface. The numerical resolution of the model by Newton-Raphson method gives good results in terms of calculation time and convergence. The simulations show that the impact of reactions at chemical equilibrium and that of kinetically controlled reactions with high kinetics on mass transfer is relatively similar. Moreover, the Fick’s law is less adapted for multicomponent mixtures where some abnormalities such as counter-diffusion take place

    Exorcizing the Landau Ghost in Non Commutative Quantum Field Theory

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    We show that the simplest non commutative renormalizable field theory, the ϕ4\phi^4 model on four dimensional Moyal space with harmonic potential is asymptotically safe to all orders in perturbation theor

    One-loop Beta Functions for the Orientable Non-commutative Gross-Neveu Model

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    We compute at the one-loop order the beta-functions for a renormalisable non-commutative analog of the Gross Neveu model defined on the Moyal plane. The calculation is performed within the so called x-space formalism. We find that this non-commutative field theory exhibits asymptotic freedom for any number of colors. The beta-function for the non-commutative counterpart of the Thirring model is found to be non vanishing.Comment: 16 pages, 9 figure

    Impact of Burnout on Risk-Taking: The Role of Managerial Political Skill

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    The purpose of this study is to examine the relationships between burnout, moral disengagement, risk-taking attitude, and managerial political skill. Using conservation of resources (COR) theory, this study seeks to determine what happens when employees who are experiencing burnout continue working within the organization. The study specifically focuses on the darker side of burnout, and its relationship with moral disengagement and risk-taking attitude by testing the proposition that employees who are experiencing burnout will utilize moral disengagement to rationalize their risk-taking attitude. The impact of managerial political skill on these relationships was also examined as managerial political skill was proposed to moderate the positive relationship between burnout and moral disengagement and moral disengagement and risk-taking attitude. To test the proposed hypotheses, Prolific, an online survey company, was utilized to collect data from 266 respondents. The survey was conducted in two phases, with each phase collected one month apart. The results of the study confirmed a positive relationship between moral disengagement and risk-taking attitude. Contrary to the hypotheses, the relationship between burnout and moral disengagement was not supported. Political skill was proposed to moderate the positive relationship between burnout and moral disengagement and moral disengagement and risk-taking attitude. These relationships were not supported. In addition, burnout did not have a significant indirect effect on risk-taking attitude through moral disengagement. Implications of the findings and future directions are discussed

    Renormalization of the commutative scalar theory with harmonic term to all orders

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    The noncommutative scalar theory with harmonic term (on the Moyal space) has a vanishing beta function. In this paper, we prove the renormalizability of the commutative scalar field theory with harmonic term to all orders by using multiscale analysis in the momentum space. Then, we consider and compute its one-loop beta function, as well as the one on the degenerate Moyal space. We can finally compare both to the vanishing beta function of the theory with harmonic term on the Moyal space.Comment: 16 page

    Disparity in the natural cycles of Borrelia burgdorferi and the agent of human granulocytic ehrlichiosis.

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    We studied the prevalence of Borrelia burgdorferi and the agent of human granulocytic ehrlichiosis (HGE) among questing nymphal and adult Ixodes scapularis ticks of the same generation and the infectivity of wild white-footed mice for ticks feeding on them. The prevalence of B. burgdorferi infection in host-seeking ticks increased less than twofold from nymphal (31% to 33%) to adult (52% to 56%) stage, and 52% of white-footed mice were infected. Prevalence of the agent of HGE increased 4.5- to 10.6-fold from nymphal (1.5% to 1.8%) to adult stage (7.6% to 19.0%), while only 18% of mice were infectious to ticks. B. burgdorferi infection was more common in mouse-fed ticks than in ticks collected from vegetation, whereas the agent of HGE was half as common in mouse-fed ticks as in ticks collected from vegetation. The different prevalence in nature of these pathogens in ticks suggests that their maintenance cycles are also different

    Using network analysis to identify factors influencing the heath-related quality of life of parents caring for an autistic child

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    BACKGROUND: Raising an autistic child is associated with increased parenting stress relative to raising typically developing children. Increased parenting stress is associated with lower parent wellbeing, which in turn can negatively impact child wellbeing. AIMS: The current study sought to quantify parenting stress and parent health-related quality of life (HRQOL) in the autism context, and further understand the relationship between them by employing a relatively novel statistical method, Network Analysis. METHODS AND PROCEDURES: This cross-sectional study involved 476 parents of an autistic child. Parents completed an online survey requesting information on parent and child characteristics, parent's perceptions of their autistic child's symptoms and problem behaviours, and assessed their parenting stress and HRQOL. OUTCOMES AND RESULTS: Relative to normative data, parent HRQOL was significantly lower in terms of physical health and mental wellbeing. The structure extracted by the Network Analysis indicated that child age and externalising behaviours were the main contributors to parenting stress, and that externalising behaviours, ASD core behavioural symptoms, and parenting stress predicted HRQOL. CONCLUSIONS AND IMPLICATIONS: Parental responses to child-related factors likely determine parent HRQOL. Findings are discussed in relation to the transactional model, emphasising the importance of both parent and child wellbeing.fals

    Centrality statistics of symptom networks of schizophrenia: a systematic review

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    The network theory of psychological disorders posits that systems of symptoms cause, or are associated with, the expression of other symptoms. Substantial literature on symptom networks has been published to date, although no systematic review has been conducted exclusively on symptom networks of schizophrenia, schizoaffective disorder, and schizophreniform (people diagnosed with schizophrenia; PDS). This study aims to compare statistics of the symptom network publications on PDS in the last 21 years and identify congruences and discrepancies in the literature. More specifically, we will focus on centrality statistics. Thirty-two studies met the inclusion criteria. The results suggest that cognition, and social, and occupational functioning are central to the network of symptoms. Positive symptoms, particularly delusions were central among participants in many studies that did not include cognitive assessment. Nodes representing cognition were most central in those studies that did. Nodes representing negative symptoms were not as central as items measuring positive symptoms. Some studies that included measures of mood and affect found items or subscales measuring depression were central nodes in the networks. Cognition, and social, and occupational functioning appear to be core symptoms of schizophrenia as they are more central in the networks, compared to variables assessing positive symptoms. This seems consistent despite heterogeneity in the design of the studies.fals
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