Raman spectroscopy, a non-destructive solution to the study of glass and its alteration

This paper presents the potential of Raman spectroscopy, a non-destructive technique which can be applied in-situ, for the analyses of glass and their alteration. Recent analytical developments are summarised for different glass composition and practical examples are given. The paper describes how to extract compositional information from the glass, first based on the spectra profile to distinguish rapidly alkali silicate from alkaline-earth alkali silicate and lead alkali silicate glass, then using the spectral decomposition and correlations to extract quantitative data. For alkali silicate glasses, that are most prone to alteration, the spectral characteristics are described to interpret the alteration process (selective leaching or dissolution of the glass) from the Raman spectra of the altered glass. These developments have greatly widened the potential of the technique and supplement well its ability to measure the thickness of the altered layer and identify the crystalline deposits

Low Energy States of 3181Ga50^{81}_{31} Ga_{50} : Elements on the Doubly-Magic Nature of 78^{78}Ni

Excited levels were attributed to $^{81}_{31}$Ga$_{50}$ for the first time which were fed in the $\beta$-decay of its mother nucleus $^{81}$Zn produced in the fission of $^{nat}$U using the ISOL technique. We show that the structure of this nucleus is consistent with that of the less exotic proton-deficient N=50 isotones within the assumption of strong proton Z=28 and neutron N=50 effective shell effects.Comment: 4 pages, REVTeX 4, 5 figures (eps format

Monomorphic trypanozoon:Towards reconciling phylogeny and pathologies

Trypanosoma brucei evansi and T. brucei equiperdum are animal infective trypanosomes conventionally classified by their clinical disease presentation, mode of transmission, host range, kinetoplast DNA (kDNA) composition and geographical distribution. Unlike other members of the subgenus Trypanozoon, they are non-tsetse transmitted and predominantly morphologically uniform (monomorphic) in their mammalian host. Their classification as independent species or subspecies has been long debated and genomic studies have found that isolates within T. brucei evansi and T. brucei equiperdum have polyphyletic origins. Since current taxonomy does not fully acknowledge these polyphyletic relationships, we re-analysed publicly available genomic data to carefully define each clade of monomorphic trypanosome. This allowed us to identify, and account for, lineage-specific variation. We included a recently published isolate, IVM-t1, which was originally isolated from the genital mucosa of a horse with dourine and typed as T. equiperdum. Our analyses corroborate previous studies in identifying at least four distinct monomorphic T. brucei clades. We also found clear lineage-specific variation in the selection efficacy and heterozygosity of the monomorphic lineages, supporting their distinct evolutionary histories. The inferred evolutionary position of IVM-t1 suggests its reassignment to the T. brucei evansi type B clade, challenging the relationship between the Trypanozoon species, the infected host, mode of transmission and the associated pathological phenotype. The analysis of IVM-t1 also provides, to our knowledge, the first evidence of the expansion of T. brucei evansi type B, or a fifth monomorphic lineage represented by IVM-t1, outside of Africa, with important possible implications for disease diagnosis

Natural deep eutectic solvents as thermostabilizer for Humicola insolens cutinase

As a new generation of green solvents, deep eutectic solvents (DESs) are considered a promising alternative to current harsh organic solvents and find application in many chemical processing methods such as extraction and synthesis. DESs, normally formed by two or more components via various hydrogen bond interactions, offer high potential as medium for biocatalysis reactions where they can improve efficiency by enhancing substrate solubility and the activity and stability of the enzymes. In the current study, the stabilization of Humicola insolens cutinase (HiC) in natural deep eutectic solvents (NADESs) was assessed. The best hydrogen bond donor among sorbitol, xylitol, erythritol, glycerol and ethylene glycol, and the best acceptor among betaine, choline chloride, choline acetate, choline dihydrogen citrate and tetramethylammonium chloride, were selected, evaluating binding energies and molecular orientations through molecular docking simulations, and finally used to prepare NADES aqueous solutions. The effects of component ratio and NADES concentration on HiC thermostability at 90 degrees C were also investigated. The choline dihydrogen citrate:xylitol, in a 1:1 ratio with a 20 wt% concentration, was selected as the best combination in stabilizing HiC, increasing its half-life three-fold

First in-beam γ -ray study of the level structure of neutron-rich S 39

R. Chapman et al. ; 8 págs.; 6 figs.; 1 tab.The neutron-rich S39 nucleus has been studied using binary grazing reactions produced by the interaction of a 215-MeV beam of S36 ions with a thin Pb208 target. The magnetic spectrometer, PRISMA, and the γ-ray array, CLARA, were used in the measurements. Gamma-ray transitions of the following energies were observed: 339, 398, 466, 705, 1517, 1656, and 1724 keV. Five of the observed transitions have been tentatively assigned to the decay of excited states with spins up to (11/2-). The results of a state-of-the-art shell-model calculation of the level scheme of S39 using the SDPF-U effective interaction are also presented. The systematic behavior of the excitation energy of the first 11/2- states in the odd-A isotopes of sulfur and argon is discussed in relation to the excitation energy of the first excited 2+ states of the adjacent even-A isotopes. The states of S39 that have the components in their wave functions corresponding to three neutrons in the 1f7/2 orbital outside the N=20 core have also been discussed within the context of the 0 ω shell-model calculations presented here. ©2016 American Physical SocietyThis work was supported in part by the EPSRC (UK) and by the European Union under Contract No. RII3-CT- 2004-506065. Five of us (D.O., M.B., A.H., K.K., and A.P.) acknowledge financial support from the EPSRC. Z.M.W. acknowledges support from ORSAS and from the University of the West of Scotland. A.N.D. acknowledges support from the STFC. A.J. acknowledges financial support from the Spanish Ministerio de Ciencia e Innovación under Contracts No. FPA2007-66069 and No. FPA2009-13377-C02-02. Zs.D. acknowledges financial support from OTKA under Project No. K100835. S.S. acknowledges support from the Croatian Science Foundation under Project No. 7194. The contribution of the accelerator and target-fabrication staff at the INFN Legnaro National Laboratory is gratefully acknowledged.Peer Reviewe

Particle-core coupling in S 37

R. Chapman et al. ; 8 págs.; 6 figs.; 2 tabs.Excited states of the neutron-rich N=21 S37 nucleus have been studied using binary grazing reactions produced by the interaction of a 215-MeV beam of S36 ions with a thin Pb208 target. The magnetic spectrometer, PRISMA, and the γ-ray array, CLARA, were used in the measurements. The level scheme of S37 was established to an excitation energy of 4196 keV and a number of new transitions were observed, in particular that corresponding to the decay of the proposed Jπ=(11/2-) level at an excitation energy of 2776 keV. The structure of the state is discussed within the context of state-of-the-art shell-model calculations using the SDPF-U effective interaction; the main component of the wave function corresponds to the coupling of the odd 1f7/2 neutron to the first 2+ state of the S36 core. The electromagnetic decay properties of the state are discussed within the context of a particle-core coupling model and the shell model. The other members of the multiplet of states are also discussed. ©2016 American Physical SocietyWe would like to thank the technical staff of the INFN Legnaro National Laboratory for their support during this experiment. This work was supported by the EPSRC (U.K). Four of us (A.H,M.B, K.L.K., and A.P.) would like to acknowledge the receipt of financial support from EPSRC during the course of this work. A.J. would like to acknowledge support from the Spanish Ministerio de Economía y Competitividad under Contract No. FPA2014-57196-C5-4-P. Z.D. acknowledges financial support from OTKA Grant No. K100835.Peer Reviewe

Study of the N=50 major shell effect close to 78^{78}Ni : First evidence of a weak coupling structure in 83_32^{83}\_{32}Ge_51\_{51} and three-proton configuration states in 81_31^{81}\_{31}Ga_50\_{50}

New levels were attributed to $^{81}\_{31}$Ga$\_{50}$ and $^{83}\_{32}$Ge$\_{51}$ which were fed by the $\beta$-decay of their respective mother nuclei $^{81}\_{30}$Zn$\_{51}$ and $^{83}\_{31}$Ga$\_{52}$ produced by fission at the "PARRNe" ISOL set-up installed at the Tandem accelerator of the Institut de Physique Nucl\'eaire, Orsay. We show that the low energy structure of $^{81}\_{31}$Ga$\_{50}$ and $^{83}\_{32}$Ge$\_{51}$ can easily be explained within the natural hypothesis of a strong energy gap at N=50 and a doubly-magic character for $^{78}$Ni.Comment: 2 pages, pdf file, To be published in the Proceedings of "International Symposium on Structure of Exotic Nuclei and Nuclear Forces (SENUF 06)", March 2006, Tokyo, Japa

Modeling the bremsstrahlung emission from converters

The bremsstrahlung angular and energy theoretical distributions delivered from W and UCx thick converters are reported. This study is focussed on initial kinetic energies of the electron beam included in the range 30-60 MeV, suitable for the production of large radiative yields able to induce the $^{238}$U fission. These results offer the possibility to evaluate the required shielding for a neutron rich nuclei source

Search for Fingerprints of Tetrahedral Symmetry in 156Gd^{156}Gd

Theoretical predictions suggest the presence of tetrahedral symmetry as an explanation for the vanishing intra-band E2-transitions at the bottom of the odd-spin negative parity band in $^{156}Gd$. The present study reports on experiment performed to address this phenomenon. It allowed to determine the intra-band E2 transitions and branching ratios B(E2)/B(E1) of two of the negative-parity bands in $^{156}Gd$.Comment: presented by Q.T. Doan at XLII Zakopane School of Physics: Breaking Frontiers: Submicron Structures in Physics and Biology, May 2008. 5 pages, minor corrections. To be published in the proceeding