Efficiency of a stirred chemical reaction in a closed vessel

We perform a numerical study of the reaction efficiency in a closed vessel. Starting with a little spot of product, we compute the time needed to complete the reaction in the container following an advection-reaction-diffusion process. Inside the vessel it is present a cellular velocity field that transports the reactants. If the size of the container is not very large compared with the typical length of the velocity field one has a plateau of the reaction time as a function of the strength of the velocity field, $U$. This plateau appears both in the stationary and in the time-dependent flow. A comparison of the results for the finite system with the infinite case (for which the front speed, $v_f$, gives a simple estimate of the reacting time) shows the dramatic effect of the finite size.Comment: 4 pages, 4 figure

Linear and anomalous front propagation in system with non Gaussian diffusion: the importance of tails

We investigate front propagation in systems with diffusive and sub-diffusive behavior. The scaling behavior of moments of the diffusive problem, both in the standard and in the anomalous cases, is not enough to determine the features of the reactive front. In fact, the shape of the bulk of the probability distribution of the transport process, which determines the diffusive properties, is important just for pre-asymptotic behavior of front propagation, while the precise shape of the tails of the probability distribution determines asymptotic behavior of front propagation.Comment: 7 pages, 3 figure

Reaction spreading on percolating clusters

Reaction-diffusion processes in two-dimensional percolating structures are investigated. Two different problems are addressed: reaction spreading on a percolating cluster and front propagation through a percolating channel. For reaction spreading, numerical data and analytical estimates show a power-law behavior of the reaction product as M(t) \sim t^dl, where dl is the connectivity dimension. In a percolating channel, a statistically stationary traveling wave develops. The speed and the width of the traveling wave are numerically computed. While the front speed is a low-fluctuating quantity and its behavior can be understood using a simple theoretical argument, the front width is a high-fluctuating quantity showing a power-law behavior as a function of the size of the channelComment: 7 pages, 8 figure

Invasions in heterogeneous habitats in the presence of advection

We investigate invasions from a biological reservoir to an initially empty, heterogeneous habitat in the presence of advection. The habitat consists of a periodic alternation of favorable and unfavorable patches. In the latter the population dies at fixed rate. In the former it grows either with the logistic or with an Allee effect type dynamics, where the population has to overcome a threshold to grow. We study the conditions for successful invasions and the speed of the invasion process, which is numerically and analytically investigated in several limits. Generically advection enhances the downstream invasion speed but decreases the population size of the invading species, and can even inhibit the invasion process. Remarkably, however, the rate of population increase, which quantifies the invasion efficiency, is maximized by an optimal advection velocity. In models with Allee effect, differently from the logistic case, above a critical unfavorable patch size the population localizes in a favorable patch, being unable to invade the habitat. However, we show that advection, when intense enough, may activate the invasion process.Comment: 16 pages, 11 figures J. Theor. Biol. to appea

Discreteness effects in a reacting system of particles with finite interaction radius

9 pages.-- PACS numbers: 05.40.-a, 82.39.-k, 82.40.-g.-- Final full-text version of the paper available at: http://dx.doi.org/10.1103/PhysRevE.76.031139.An autocatalytic reacting system with particles interacting at a finite distance is studied. We investigate the effects of the discrete-particle character of the model on properties like reaction rate, quenching phenomenon, and front propagation, focusing on differences with respect to the continuous case. We introduce a renormalized reaction rate depending both on the interaction radius and the particle density, and we relate it to macroscopic observables (e.g., front speed and front thickness) of the system.We have benefited from a MEC-MIUR joint program (Italy-Spain Integral Actions). C.L. acknowledges support from FEDER and MEC (Spain), through project CONOCE2 (FIS2004-00953). A.V. and D.V. acknowledge support from PRIN-MIUR project "Dinamica Statistica di sistemi a molti e pochi gradi di libertà"

Front speed in reactive compressible stirred media

We investigated a nonlinear advection-diffusion-reaction equation for a passive scalar field. The purpose is to understand how the compressibility can affect the front dynamics and the bulk burning rate. We study two classes of flows: periodic shear flow and cellular flow both in the case of fast advection regime, analysing the system at varying the extent of compressibility and the reaction rate. We find that the bulk burning rate in a shear flow increases with compressibility intensity. Furthermore, the faster the reaction the more important the difference with respect to the laminar case. The effect has been quantitatively measured and it turns out to be generally little. For the cellular flow, the two extreme cases have been investigated, with the whole perturbation situated either in the centre of the vortex or in the periphery. The dependence in this case does not show a monotonic scaling with different behaviour in the two cases. The enhancing remains modest and always less than 20%Comment: 9 pages, 5 figures, under press on Physical Review E (2013

Markovian approximation in foreign exchange markets

In this paper we test the random walk hypothesis on the high frequency dataset of the bid--ask Deutschemark/US dollar exchange rate quotes registered by the inter-bank Reuters network over the period October 1, 1992 to September 30, 1993. Then we propose a stochastic model for price variation which is able to describe some important features of the exchange market behavior. Besides the usual correlation analysis we have verified the validity of this model by means of other approaches inspired by information theory . These techniques are not only severe tests of the approximation but also evidence some aspects of the data series which have a clear financial relevance.Comment: 19 pages, LaTeX, uses elsart.cls and JournalOfFinance.sty, 7 eps figures, submitted to J. of Int. Money and Financ

Inverse velocity statistics in two dimensional turbulence

We present a numerical study of two-dimensional turbulent flows in the enstrophy cascade regime, with different large-scale forcings and energy sinks. In particular, we study the statistics of more-than-differentiable velocity fluctuations by means of two recently introduced sets of statistical estimators, namely {\it inverse statistics} and {\it second order differences}. We show that the 2D turbulent velocity field, $\bm u$, cannot be simply characterized by its spectrum behavior, $E(k) \propto k^{-\alpha}$. There exists a whole set of exponents associated to the non-trivial smooth fluctuations of the velocity field at all scales. We also present a numerical investigation of the temporal properties of $\bm u$ measured in different spatial locations.Comment: 9 pages, 12 figure