Synthesis and hydrophosphorylation of π-complexes of dibenzylideneacetone and cyclic conjugated dienones with homocarbonyl and carbonylcyclopentadienyl molybdenum compounds

© 2016, Pleiades Publishing, Ltd.Reactions of dibenzylideneacetone and cyclic cross-conjugated dienones with hexacarbonylmolybdenum(0) and bis[tricarbonyl(cyclopentadienyl)molybdenum(0)] afforded the corresponding complexes with η2-(C=C),η2-(C=O) coordination of the diketone to metal center, regardless of the ligand structure and initial molybdenum compound. The reactivity of the multidentate ligands may change as a result of coordination

Modern Trends of Organic Chemistry in Russian Universities

© 2018, Pleiades Publishing, Ltd. This review is devoted to the scientific achievements of the departments of organic chemistry in higher schools of Russia within the past decade

Synthesis and hydrophosphorylation of π-complexes of dibenzylideneacetone and cyclic conjugated dienones with homocarbonyl and carbonylcyclopentadienyl molybdenum compounds

© 2016, Pleiades Publishing, Ltd.Reactions of dibenzylideneacetone and cyclic cross-conjugated dienones with hexacarbonylmolybdenum(0) and bis[tricarbonyl(cyclopentadienyl)molybdenum(0)] afforded the corresponding complexes with η2-(C=C),η2-(C=O) coordination of the diketone to metal center, regardless of the ligand structure and initial molybdenum compound. The reactivity of the multidentate ligands may change as a result of coordination

syn-3-(4-Chlorobenzyl)-1,5-dimethyl-3,7-diazabicyclo[3.3.1]nonan-9-ol

In the title compound, C16H23ClN2O, both six-membered rings adopt chair conformations, thus allowing the formation of an intramolecular N—H...N hydrogen bond. In the crystal, adjacent molecules are combined into chains running along the ac diagonal via O—H...N hydrogen bonds

Synthesis and hydrophosphorylation of π-complexes of dibenzylideneacetone and cyclic conjugated dienones with homocarbonyl and carbonylcyclopentadienyl molybdenum compounds

© 2016, Pleiades Publishing, Ltd.Reactions of dibenzylideneacetone and cyclic cross-conjugated dienones with hexacarbonylmolybdenum(0) and bis[tricarbonyl(cyclopentadienyl)molybdenum(0)] afforded the corresponding complexes with η2-(C=C),η2-(C=O) coordination of the diketone to metal center, regardless of the ligand structure and initial molybdenum compound. The reactivity of the multidentate ligands may change as a result of coordination

Synthesis and hydrophosphorylation of π-complexes of dibenzylideneacetone and cyclic conjugated dienones with homocarbonyl and carbonylcyclopentadienyl molybdenum compounds

© 2016, Pleiades Publishing, Ltd.Reactions of dibenzylideneacetone and cyclic cross-conjugated dienones with hexacarbonylmolybdenum(0) and bis[tricarbonyl(cyclopentadienyl)molybdenum(0)] afforded the corresponding complexes with η2-(C=C),η2-(C=O) coordination of the diketone to metal center, regardless of the ligand structure and initial molybdenum compound. The reactivity of the multidentate ligands may change as a result of coordination