Controlling fragmentation of the acetylene cation in the vacuum ultraviolet via transient molecular alignment

Artículo escrito por un elevado número de autores, solo se referencian el que aparece en primer lugar, los autores pertenecientes a la UAM y el nombre del grupo de colaboración, si lo hubiereAn open-loop control scheme of molecular fragmentation based on transient molecular alignment combined with single-photon ionization induced by a shortwavelength free electron laser (FEL) is demonstrated for the acetylene cation. Photoelectron spectra are recorded, complementing the ion yield measurements, to demonstrate that such control is the consequence of changes in the electronic response with molecular orientation relative to the ionizing field. We show that stable C2H2 + cations are mainly produced when the molecules are parallel or nearly parallel to the FEL polarization, while the hydrogen fragmentation channel (C2H2 + → C2H+ + H) predominates when the molecule is perpendicular to that direction, thus allowing one to distinguish between the two photochemical processes. The experimental findings are supported by state-of-the art theoretical calculationsAn open-loop control scheme of molecular fragmentation based on transient molecular alignment combined with single-photon ionization induced by a shortwavelength free electron laser (FEL) is demonstrated for the acetylene cation. Photoelectron spectra are recorded, complementing the ion yield measurements, to demonstrate that such control is the consequence of changes in the electronic response with molecular orientation relative to the ionizing field. We show that stable C2H2 + cations are mainly produced when the molecules are parallel or nearly parallel to the FEL polarization, while the hydrogen fragmentation channel (C2H2 + → C2H+ + H) predominates when the molecule is perpendicular to that direction, thus allowing one to distinguish between the two photochemical processes. The experimental findings are supported by state-of-the art theoretical calculation

Controlling Fragmentation of the Acetylene Cation in the Vacuum Ultraviolet via Transient Molecular Alignment.

An open-loop control scheme of molecular fragmentation based on transient molecular alignment combined with single-photon ionization induced by a short-wavelength free electron laser (FEL) is demonstrated for the acetylene cation. Photoelectron spectra are recorded, complementing the ion yield measurements, to demonstrate that such control is the consequence of changes in the electronic response with molecular orientation relative to the ionizing field. We show that stable C2H2+ cations are mainly produced when the molecules are parallel or nearly parallel to the FEL polarization, while the hydrogen fragmentation channel (C2H2+ → C2H+ + H) predominates when the molecule is perpendicular to that direction, thus allowing one to distinguish between the two photochemical processes. The experimental findings are supported by state-of-the art theoretical calculations

Near threshold two photon double ionization of Kr in the vacuum ultraviolet

We report angle resolved measurements on photoelectrons emitted upon near threshold two photon double ionization TPDI of Kr irradiated by free electron laser FEL pulses. These photoelectron angular distributions PADs are compared with the results of semirelativistic R matrix calculations. As reported by Augustin et al., it is found that the presence of autoionizing resonances within the bandwidth of the exciting FEL pulse strongly influences the PADs. In contrast to measurements on lower Z targets such as Ne and Ar, the larger spin orbit interaction, inherent in 4p subshell hole states of Kr, permits us to resolve and study PADs associated with some of the fine structure components of the Kr and Kr2 ion

Two-color XUV+NIR femtosecond photoionization of neon in the near-threshold region

Results of angle-resolved electron spectroscopy of near-threshold photoionization of Ne atoms bycombined femtosecond extreme ultraviolet and near infraredfields are presented. The dressed-electron spectra show an energetic distribution into so-called sidebands, being separated by thephoton energy of the dressing laser. Surprisingly, for the low kinetic energy(few eV)sidebands, thephotoelectron energy varies as a function of the emission angle. Such behavior has not yet beenobserved in sideband creation and has not been predicted in commonly used theoretical descriptionssuch as strongfield approximation and soft photon approach. Describing the photoionization with atime-dependent Schrödinger equation allows a qualitative description of the observed effect, as well asthe prediction offine structure in the sideband distributio