An approach to the use of hydrogen for commercial aircraft engines

This paper presents some results on the performance of hydrogen-based engines. In particular, the following aspects are addressed: benefits associated with specific fuel and energy consumption, net thrust, turbine entry temperature, and hardware changes needed in the upgrading process from kerosene to hydrogen. Hydrogen is a high-energy clean-burning fuel whose main combustion product is water vapour plus traces of nitrogen oxides. This fact suggests that, provided that the technology is available, the use of hydrogen could offer some opportunities for the environmentally friendly development and sustained growth of commercial aviation. The study has been performed in the frame of the Liquid Hydrogen Fuelled Aircraft – System Analysis (CRYOPLANE) project. This is a Fifth Framework Programme, supported by the European Commission, whose objective was to assess the feasibility of using hydrogen as a clean energy source for air transportation systems

Hard-wall Potential Function for Transport Properties of Alkali Metals Vapor

This study demonstrates that the transport properties of alkali metals are determined principally by the repulsive wall of the pair interaction potential function. The (hard-wall) Lennard-Jones(15-6) effective pair potential function is used to calculate transport collision integrals. Accordingly, reduced collision integrals of K, Rb, and Cs metal vapors are obtained from Chapman-Enskog solution of the Boltzman equation. The law of corresponding states based on the experimental-transport reduced collision integral is used to verify the validity of a LJ(15-6) hybrid potential in describing the transport properties. LJ(8.5-4) potential function and a simple thermodynamic argument with the input PVT data of liquid metals provide the required molecular potential parameters. Values of the predicted viscosity of monatomic alkali metals vapor are in agreement with typical experimental data with the average absolute deviation 2.97% for K in the range 700-1500 K, 1.69% for Rb, and 1.75% for Cs in the range 700-2000 K. In the same way, the values of predicted thermal conductivity are in agreement with experiment within 2.78%, 3.25%, and 3.63% for K, Rb, and Cs, respectively. The LJ(15-6) hybrid potential with a hard-wall repulsion character conclusively predicts best transport properties of the three alkali metals vapor.Comment: 21 pages, 5 figures, 41 reference

Site-site memory equation approach in study of density/pressure dependence of translational diffusion coefficient and rotational relaxation time of polar molecular solutions: acetonitrile in water, methanol in water, and methanol in acetonitrile

We present results of theoretical study and numerical calculation of the dynamics of molecular liquids based on combination of the memory equation formalism and the reference interaction site model - RISM. Memory equations for the site-site intermediate scattering functions are studied in the mode-coupling approximation for the first order memory kernels, while equilibrium properties such as site-site static structure factors are deduced from RISM. The results include the temperature-density(pressure) dependence of translational diffusion coefficients D and orientational relaxation times t for acetonitrile in water, methanol in water and methanol in acetonitrile, all in the limit of infinite dilution. Calculations are performed over the range of temperatures and densities employing the SPC/E model for water and optimized site-site potentials for acetonitrile and methanol. The theory is able to reproduce qualitatively all main features of temperature and density dependences of D and t observed in real and computer experiments. In particular, anomalous behavior, i.e. the increase in mobility with density, is observed for D and t of methanol in water, while acetonitrile in water and methanol in acetonitrile do not show deviations from the ordinary behavior. The variety exhibited by the different solute-solvent systems in the density dependence of the mobility is interpreted in terms of the two competing origins of friction, which interplay with each other as density increases: the collisional and dielectric frictions which, respectively, increase and decrease with increasing density.Comment: 13 pages, 8 eps-figures, 3 tables, RevTeX4-forma

Pattern formation during the evaporation of a colloidal nanoliter drop: a numerical and experimental study

An efficient way to precisely pattern particles on solid surfaces is to dispense and evaporate colloidal drops, as for bioassays. The dried deposits often exhibit complex structures exemplified by the coffee ring pattern, where most particles have accumulated at the periphery of the deposit. In this work, the formation of deposits during the drying of nanoliter colloidal drops on a flat substrate is investigated numerically and experimentally. A finite-element numerical model is developed that solves the Navier-Stokes, heat and mass transport equations in a Lagrangian framework. The diffusion of vapor in the atmosphere is solved numerically, providing an exact boundary condition for the evaporative flux at the droplet-air interface. Laplace stresses and thermal Marangoni stresses are accounted for. The particle concentration is tracked by solving a continuum advection-diffusion equation. Wetting line motion and the interaction of the free surface of the drop with the growing deposit are modeled based on criteria on wetting angles. Numerical results for evaporation times and flow field are in very good agreement with published experimental and theoretical results. We also performed transient visualization experiments of water and isopropanol drops loaded with polystyrene microsphere evaporating on respectively glass and polydimethylsiloxane substrates. Measured evaporation times, deposit shape and sizes, and flow fields are in very good agreement with the numerical results. Different flow patterns caused by the competition of Marangoni loops and radial flow are shown to determine the deposit shape to be either a ring-like pattern or a homogeneous bump

Numerical simulation of thermal properties in two-dimensional Yukawa systems

New results obtained for thermal conduction in 2D Yukawa systems. The results of numerical study of heat transfer processes for quasi equilibrium systems with parameters close to conditions in laboratory experiments with dusty plasma are presented. The Green-Kubo relations are used to calculate thermal conductivity and diffusivity coefficients. For the first time the influence of dissipation (friction) on the heat transfer in non-ideal systems is studied. New approximation is suggested for thermal diffusivity. The comparison with the existing experimental and numerical results is shown.Comment: 18 pages, 9 figure

Enhancements of nucleate boiling under microgravity conditions

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/76852/1/AIAA-2000-853-986.pd

Master singular behavior for the Sugden factor of the one-component fluids near their gas-liquid critical point

We present the master (i.e. unique) behavior of the squared capillary length - so called the Sudgen factor-, as a function of the temperature-like field along the critical isochore, asymptotically close to the gas-liquid critical point of twenty (one component) fluids. This master behavior is obtained using the scale dilatation of the relevant physical fields of the one-component fluids. The scale dilatation introduces the fluid-dependent scale factors in a manner analog with the linear relations between physical fields and scaling fields needed by the renormalization theory applied to the Ising-like universality class. The master behavior for the Sudgen factor satisfies hyperscaling and can be asymptotically fitted by the leading terms of the theoretical crossover functions for the correlation length and the susceptibility in the homogeneous domain recently obtained from massive renormalization in field theory. In the absence of corresponding estimation of the theoretical crossover functions for the interfacial tension, we define the range of the temperature-like field where the master leading power law can be practically used to predict the singular behavior of the Sudgen factor in conformity with the theoretical description provided by the massive renormalization scheme within the extended asymptotic domain of the one-component fluid "subclass"