Too anxious to control : the relation between math anxiety and inhibitory control processes

Based on the attentional control theory, math anxiety has been explained in terms of impaired inhibition, a key cognitive control function associated with the central executive. Inhibition allows us to suppress task-irrelevant interference when needed. Inspired by the Dual Mechanisms of Control theory, the current study aimed to disentangle the effect of math anxiety on two cognitive control aspects that can be identified in inhibition. Reactive control occurs after interference is detected and is mostly used in a context where interference is scarce. Proactive control is used to prevent and anticipate interference before it occurs and is preferred in contexts where interference is frequent. We used an arrow flanker task where the proportion of interference was manipulated to stimulate the use of a reactive or proactive control strategy. The results showed that response times on trials containing interference increased with math anxiety, but only in a reactive task context. In a proactive task context response times were not influenced by math anxiety. Our results suggest that math anxiety impairs reactive control. We hypothesize that this finding can be explained by a higher state of distractibility, triggered both by the reactive context and by math anxiety

The “Historical Materials BAG”: A new facilitated access to synchrotron X-ray diffraction analyses for cultural heritage materials at the European Synchrotron Radiation Facility

(This article belongs to the Special Issue Advances in Analytical Strategies to Study Cultural Heritage Samples)The European Synchrotron Radiation Facility (ESRF) has recently commissioned the new Extremely Brilliant Source (EBS). The gain in brightness as well as the continuous development of beamline instruments boosts the beamline performances, in particular in terms of accelerated data acquisition. This has motivated the development of new access modes as an alternative to standard proposals for access to beamtime, in particular via the “block allocation group” (BAG) mode. Here, we present the recently implemented “historical materials BAG”: a community proposal giving to 10 European institutes the opportunity for guaranteed beamtime at two X-ray powder diffraction (XRPD) beamlines—ID13, for 2D high lateral resolution XRPD mapping, and ID22 for high angular resolution XRPD bulk analyses—with a particular focus on applications to cultural heritage. The capabilities offered by these instruments, the specific hardware and software developments to facilitate and speed-up data acquisition and data processing are detailed, and the first results from this new access are illustrated with recent applications to pigments, paintings, ceramics and wood.The Historical materials BAG has been implemented with support from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 870313, Streamline, which also supports APC. L. H. is funded via the PANOSC project (European Union’s Horizon 2020 Research and Innovation programme under Grant Agreement No. 823852). I. F. is funded by a grant from the Marie Skłodowska-Curie COFUND Programme “InnovaXN” (contract number 847439 with the European Commission). The ESRF beamtime was granted through the peer-review BAG proposal HG-172 at ID13 and ID22 and in-house beamtime at ID21. The project on wood vessels received financial support from MINECO (Spain), Ref. PID2019-105823RB-I00. The project on cadmium red pigments was financially supported from the Horizon 2020 project IPERION-HS (H2020-INFRAIA-2019-1, GA No. 871034) and the Italian project AMIS (Dipartimenti di Eccellenza 2018–2022, funded by MIUR and Perugia University). V.G. has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 945298-ParisRegionFP. E.A.C. and K.J. would like to acknowledge the project Smart*Light funded by the Interreg V Flanders-Netherlands program with financial support from the European Regional Development Fund (ERDF) for funding in assessing the damage caused by X-rays to model paints. K.J. acknowledges FWO (Brussels) for financial support through grants G054719N and I001919N. F.V. and K.J. acknowledge BELSPO (Brussels) for funding of the FEDtWIN mandate Macro-Imaging. C.C. (Christelle Chauffeton) is grateful to the Fondation Bettencourt-Schueller and the Cité de la Céramique Sèvres-Limoges, France for founding her work in the frame of her PhD thesis. A part of this study has been funded by the Grant-in-Aid for Scientific Research [18700680], JSPS Grant-in-Aid for Young Scientists (B) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.Peer ReviewedArticle signat per 28 autors/es: Marine Cotte, Victor Gonzalez, Frederik Vanmeert, Letizia Monico, Catherine Dejoie, Manfred Burghammer, Loïc Huder, Wout de Nolf, Stuart Fisher, Ida Fazlic, Christelle Chauffeton, Gilles Wallez, Núria Jiménez, Francesc Albert-Tortosa, Nati Salvadó, Elena Possenti, Chiara Colombo, Marta Ghirardello, Daniela Comelli, Ermanno Avranovich Clerici, Riccardo Vivani, Aldo Romani, Claudio Costantino, Koen Janssens, Yoko Taniguchi, Joanne McCarthy, Harald Reichert and Jean Susini.Postprint (published version

Plasmonic gold-embedded TiO2 thin films as photocatalytic self-cleaning coatings

Transparent photocatalytic TiO2 thin films hold great potential in the development of self-cleaning glass surfaces, but suffer from a poor visible light response that hinders the application under actual sunlight. To alleviate this problem, the photocatalytic film can be modified with plasmonic nanoparticles that interact very effectively with visible light. Since the plasmonic effect is strongly concentrated in the near surroundings of the nanoparticle surface, an approach is presented to embed the plasmonic nanostructures in the TiO2 matrix itself, rather than deposit them loosely on the surface. This way the interaction interface is maximised and the plasmonic effect can be fully exploited. In this study, pre-fabricated gold nanoparticles are made compatible with the organic medium of a TiO2 solgel coating suspension, resulting in a one-pot coating suspension. After spin coating, homogeneous, smooth, highly transparent and photoactive gold-embedded anatase thin films are obtained

Protection of Stone Monuments Using a Brushing Treatment with Ammonium Oxalate

Stone monuments and buildings are susceptible to weathering. Carbonate-based stones are especially vulnerable in acidic environments, whereas magmatic acidic stones are more susceptible to chemical weathering in basic environments. To slow down surface corrosion of limestone and marble artworks/buildings, protective coatings which inhibit calcite dissolution have been proposed. In this work, samples from two stone types with different porosity were treated with ammonium oxalate (AmOx) to create a protective layer of calcium oxalate (CaOx) using the previously developed brushing method. Two different synchrotron microscopy experiments were performed to determine its protective capability. X-ray powder diffraction (SR-μ-XRPD) in transmission geometry allowed visualization of the distributions of calcium carbonate and oxalates along the sample depths. In a second step, X-ray fluorescence (SR-μ-XRF) was used to check the efficiency/integrity of the protective surface coating layer. This was done by measuring the sulfur distribution on the stone surface after exposing the protected stones to sulfuric acid. XRPD showed the formation of a protective oxalate layer with a thickness of 5–15 µm on the less porous stone, while a 20–30 µm thick layer formed on the more porous stone. The XRF study showed that the optimal treatment time depends on the stone porosity. Increasing the treatment time from 1 to 3 h resulted in a decreased efficiency of the protective layer for the low porosity stone. We assume that this is due to the formation of vertical channels (cracks) in the protective layer

Probing the chemistry of CdS paints in The Scream by in situ noninvasive spectroscopies and synchrotron radiation x-ray techniques

The degradation of cadmium sulfide (CdS)-based oil paints is a phenomenon potentially threatening the iconic painting The Scream (ca. 1910) by Edvard Munch (Munch Museum, Oslo) that is still poorly understood. Here, we provide evidence for the presence of cadmium sulfate and sulfites as alteration products of the original CdS-based paint and explore the external circumstances and internal factors causing this transformation. Macroscale in situ noninvasive spectroscopy studies of the painting in combination with synchrotron-radiation x-ray microspectroscopy investigations of a microsample and artificially aged mock-ups show that moisture and mobile chlorine compounds are key factors for promoting the oxidation of CdS, while light (photodegradation) plays a less important role. Furthermore, under exposure to humidity, parallel/secondary reactions involving dissolution, migration through the paint, and recrystallization of water-soluble phases of the paint are associated with the formation of cadmium sulfates

Common variable immunodeficiency in two kindreds with heterogeneous phenotypes caused by novel heterozygous NFKB1 mutations

NFKB1 haploinsufficiengcy was first described in 2015 in three families with common variable immunodeficiency (CVID), presenting heterogeneously with symptoms of increased infectious susceptibility, skin lesions, malignant lymphoproliferation and autoimmunity. The described mutations all led to a rapid degradation of the mutant protein, resulting in a p50 haploinsufficient state. Since then, more than 50 other mutations have been reported, located throughout different domains of NFKB1 with the majority situated in the N-terminal Rel homology domain (RHD). The clinical spectrum has also expanded with possible disease manifestations in almost any organ system. In silico prediction tools are often used to estimate the pathogenicity of NFKB1 variants but to prove causality between disease and genetic findings, further downstream functional validation is required. In this report, we studied 2 families with CVID and two novel variants in NFKB1 (c.1638-2A>G and c.787G>C). Both mutations affected mRNA and/or protein expression of NFKB1 and resulted in excessive NLRP3 inflammasome activation in patient macrophages and upregulated interferon stimulated gene expression. Protein-protein interaction analysis demonstrated a loss of interaction with NFKB1 interaction partners for the p.V263L mutation. In conclusion, we proved pathogenicity of two novel variants in NFKB1 in two families with CVID characterized by variable and incomplete penetrance.Peer reviewe

Common variable immunodeficiency in two kindreds with heterogeneous phenotypes caused by novel heterozygous NFKB1 mutations

NFKB1 haploinsufficiengcy was first described in 2015 in three families with common variable immunodeficiency (CVID), presenting heterogeneously with symptoms of increased infectious susceptibility, skin lesions, malignant lymphoproliferation and autoimmunity. The described mutations all led to a rapid degradation of the mutant protein, resulting in a p50 haploinsufficient state. Since then, more than 50 other mutations have been reported, located throughout different domains of NFKB1 with the majority situated in the N-terminal Rel homology domain (RHD). The clinical spectrum has also expanded with possible disease manifestations in almost any organ system. In silico prediction tools are often used to estimate the pathogenicity of NFKB1 variants but to prove causality between disease and genetic findings, further downstream functional validation is required. In this report, we studied 2 families with CVID and two novel variants in NFKB1 (c.1638-2A>G and c.787G>C). Both mutations affected mRNA and/or protein expression of NFKB1 and resulted in excessive NLRP3 inflammasome activation in patient macrophages and upregulated interferon stimulated gene expression. Protein-protein interaction analysis demonstrated a loss of interaction with NFKB1 interaction partners for the p.V263L mutation. In conclusion, we proved pathogenicity of two novel variants in NFKB1 in two families with CVID characterized by variable and incomplete penetrance.Peer reviewe

The “Historical Materials BAG”: A New Facilitated Access to Synchrotron X-ray Diffraction Analyses for Cultural Heritage Materials at the European Synchrotron Radiation Facility

The European Synchrotron Radiation Facility (ESRF) has recently commissioned the new Extremely Brilliant Source (EBS). The gain in brightness as well as the continuous development of beamline instruments boosts the beamline performances, in particular in terms of accelerated data acquisition. This has motivated the development of new access modes as an alternative to standard proposals for access to beamtime, in particular via the “block allocation group” (BAG) mode. Here, we present the recently implemented “historical materials BAG”: a community proposal giving to 10 European institutes the opportunity for guaranteed beamtime at two X-ray powder diffraction (XRPD) beamlines—ID13, for 2D high lateral resolution XRPD mapping, and ID22 for high angular resolution XRPD bulk analyses—with a particular focus on applications to cultural heritage. The capabilities offered by these instruments, the specific hardware and software developments to facilitate and speed-up data acquisition and data processing are detailed, and the first results from this new access are illustrated with recent applications to pigments, paintings, ceramics and wood