SR-FTiR microscopy and FTIR imaging in the earth sciences

During the last decades, several books have been devoted to the application of spectroscopic methods in mineralogy. Several short courses and meetings have addressed particular aspects of spectroscopy, such as the analysis of hydrous components in minerals and Earth materials. In these books, complete treatment of the infrared theory and practical aspects of instrumentation and methods, along with an exhaustive list of references, can be found. The present chapter is intended to cover those aspects of infrared spectroscopy that have been developed in the past decade and are not included in earlier reviews such as Volume 18 of Reviews in Mineralogy. These new topics involve primarily: (1) the use of synchrotron radiation (SR), which, although not a routine method, is now rather extensively applied in infrared studies, in particular those requiring ultimate spatial and time resolution and the analysis of extremely small samples (a few tens of micrometers); (2) the development of imaging techniques also for foreseen time resolved studies of geo-mineralogical processes and environmental studies.Comment: 36 pages, 24 figures - Reviews in Mineralogy & Geochemistry - Vol. 78 (2013) in pres

Modelling the closest double degenerate system RXJ0806.3+1527 and its decreasing period

In the hypothesis that the 5.4m binary RXJ0806.3+1527 consists of a low mass helium white dwarf (donor) transferring mass towards its more massive white dwarf companion (primary), we consider as possible donors white dwarfs which are the result of common envelope evolution occurring when the helium core mass of the progenitor giant was still very small (~ 0.2Msun), so that they are surrounded by a quite massive hydrogen envelope (~1/100Msun or larger), and live for a very long time supported by proton--proton burning. Mass transfer from such low mass white dwarfs very probably starts during the hydrogen burning stage, and the donor structure will remain dominated by the burning shell until it loses all the hydrogen envelope and begins transferring helium. We model mass transfer from these low mass white dwarfs, and show that the radius of the donor decreases while they shed the hydrogen envelope. This radius behavior, which is due to the fact that the white dwarf is not fully degenerate, has two important consequences on the evolution of the binary: 1) the orbital period decreases, with a timescale consistent with the period decrease of the binary RXJ0806.3+1527; 2) the mass transfer rate is a factor of about 10 smaller than from a fully degenerate white dwarf, easing the problem connected with the small X-ray luminosity of this object. The possibility that such evolution describes the system RXJ0806.3+1527 is also consistent with the possible presence of hydrogen in the optical spectrum of the star, whose confirmation would become a test of the model.Comment: 13 pages, 4 figures, accepted for publication on ApJ, main journa

The oxygen vs. sodium (anti)correlation(s) in omega Cen

Recent exam of large samples of omega Cen giants shows that it shares with mono-metallic globular clusters the presence of the sodium versus oxygen anticorrelation, within each subset of stars with iron content in the range -1.9<~[Fe/H]<~-1.3. These findings suggest that, while the second generation formation history in omega Cen is more complex than that of mono-metallic clusters, it shares some key steps with those simpler cluster. In addition, the giants in the range -1.3<[Fe/H]<~-0.7 show a direct O--Na correlation, at moderately low O, but Na up to 20 times solar. These peculiar Na abundances are not shared by stars in other environments often assumed to undergo a similar chemical evolution, such as in the field of the Sagittarius dwarf galaxy. These O and Na abundances match well the yields of the massive asymptotic giant branch stars (AGB) in the same range of metallicity, suggesting that the stars at [Fe/H]>-1.3 in omega Cen are likely to have formed directly from the pure ejecta of massive AGBs of the same metallicities. This is possible if the massive AGBs of [Fe/H]>-1.3 in the progenitor system evolve when all the pristine gas surrounding the cluster has been exhausted by the previous star formation events, or the proto--cluster interaction with the Galaxy caused the loss of a significant fraction of its mass, or of its dark matter halo, and the supernova ejecta have been able to clear the gas out of the system. The absence of dilution in the metal richer populations lends further support to a scenario of the formation of second generation stars in cooling flows from massive AGB progenitors. We suggest that the entire formation of omega Cen took place in a few 10^8yr, and discuss the problem of a prompt formation of s--process elements.Comment: The Astrophysical Journal, in pres

A unique model for the variety of multiple populations formation(s) in globular clusters: a temporal sequence

We explain the multiple populations recently found in the 'prototype' Globular Cluster (GC) NGC 2808 in the framework of the asymptotic giant branch (AGB) scenario. The chemistry of the five -or more- populations is approximately consistent with a sequence of star formation events, starting after the supernovae type II epoch, lasting approximately until the time when the third dredge up affects the AGB evolution (age ~90-120Myr), and ending when the type Ia supernovae begin exploding in the cluster, eventually clearing it from the gas. The formation of the different populations requires episodes of star formation in AGB gas diluted with different amounts of pristine gas. In the nitrogen-rich, helium-normal population identified in NGC 2808 by the UV Legacy Survey of GCs, the nitrogen increase is due to the third dredge up in the smallest mass AGB ejecta involved in the star formation of this population. The possibly-iron-rich small population in NGC 2808 may be a result of contamination by a single type Ia supernova. The NGC 2808 case is used to build a general framework to understand the variety of 'second generation' stars observed in GCs. Cluster-to-cluster variations are ascribed to differences in the effects of the many processes and gas sources which may be involved in the formation of the second generation. We discuss an evolutionary scheme, based on pollution by delayed type II supernovae, which accounts for the properties of s-Fe-anomalous clusters.Comment: 20 pages, 7 figures, in press on MNRA

Gas and dust from solar metallicity AGB stars

We study the asymptotic giant branch (AGB) evolution of stars with masses between $1~M_{\odot} - 8.5~M_{\odot}$. We focus on stars with a solar chemical composition, which allows us to interpret evolved stars in the Galaxy. We present a detailed comparison with models of the same chemistry, calculated with a different evolution code and based on a different set of physical assumptions. We find that stars of mass $\ge 3.5~M_{\odot}$ experience hot bottom burning at the base of the envelope. They have AGB lifetimes shorter than $\sim 3\times 10^5$ yr and eject into their surroundings gas contaminated by proton-capture nucleosynthesis, at an extent sensitive to the treatment of convection. Low mass stars with $1.5~M_{\odot} \le M \le 3~M_{\odot}$ become carbon stars. During the final phases the C/O ratio grows to $\sim 3$. We find a remarkable agreement between the two codes for the low-mass models and conclude that predictions for the physical and chemical properties of these stars, and the AGB lifetime, are not that sensitive to the modelling of the AGB phase. The dust produced is also dependent on the mass: low-mass stars produce mainly solid carbon and silicon carbide dust, whereas higher mass stars produce silicates and alumina dust. Possible future observations potentially able to add more robustness to the present results are also discussed.Comment: 27 pages, 24 figures; accepted for publication in MNRA

The helium spread in the Globular cluster 47 Tuc

Spectroscopy has shown the presence of the CN band dicothomy and the Na-O anticorrelations for 50--70% of the investigated samples in the cluster 47 Tuc, otherwise considered a "normal" prototype of high metallicity clusters from the photometric analysis. Very recently, the re-analysis of a large number of archival HST data of the cluster core has been able to put into evidence the presence of structures in the Sub Giant Branch: it has a brighter component with a spread in magnitude by $\sim$0.06 mag and a second one, made of about 10% of stars, a little fainter (by $\sim$0.05 mag). These data also show that the Main Sequence of the cluster has an intrinsic spread in color which, if interpreted as due to a small spread in helium abundance, suggests $\Delta$Y$\sim$0.027. In this work we examine in detail whether the Horizontal Branch morphology and the Sub Giant structure provide further independent indications that a real --although very small-helium spread is present in the cluster. We re--analyze the HST archival data for the Horizontal Branch of 47 Tuc, obtaining a sample of $\sim$500 stars with very small photometric errors, and build population synthesis based on new models to show that its particular morphology can be better explained by taking into account a spread in helium abundance of 2% in mass. The same variation in helium is able to explain the spread in luminosity of the Sub Giant Branch, while a small part of the second generation is characterized by a small C+N+O increase and provides an explanation for the fainter Sub Giant Branch. We conclude that three photometric features concur to form the paradigm that a small but real helium spread is present in a cluster that has no spectacular evidence for multiple populations like those shown by other massive clusters.Comment: Accepted for publication in the MNRAS on 2010 June 8. Received 2010 May 19; in original form 2010 February 9. 7 pages and 3 figures. No table

The formation of multiple populations in the globular cluster 47 Tuc

We use the combination of photometric and spectroscopic data of 47 Tuc stars to reconstruct the possible formation of a second generation of stars in the central regions of the cluster, from matter ejected from massive Asymptotic Giant Branch stars, diluted with pristine gas. The yields from massive AGB stars with the appropriate metallicity (Z=0.004, i.e. [Fe/H]=-0.75) are compatible with the observations, in terms of extension and slope of the patterns observed, involving oxygen, nitrogen, sodium and aluminium. Based on the constraints on the maximum helium of 47 Tuc stars provided by photometric investigations, and on the helium content of the ejecta, we estimate that the gas out of which second generation stars formed was composed of about one-third of gas from intermediate mass stars, with M>= 5Mo and about two-thirds of pristine gas. We tentatively identify the few stars whose Na, Al and O abundances resemble the undiluted AGB yields with the small fraction of 47 Tuc stars populating the faint subgiant branch. From the relative fraction of first and second generation stars currently observed, we estimate that the initial FG population in 47 Tuc was about 7.5 times more massive than the cluster current total mass.Comment: Accepted for publication in MNRA