Novel strain-induced low dimensional confinement structures

We propose new confinement structures similar to heterostructures and superlattices. The new heteostructures can be obtained by applying strain to a single material in a periodic or aperiodic way. The conversion of an indirect gap into an optical active direct or quasi-direct gap problem has also been investigated together with the role of zone folding in this phenomenon.Comment: 4 pages, 5 figure

Demixing and orientational ordering in mixtures of rectangular particles

Using scaled-particle theory for binary mixtures of two-dimensional hard particles with rotational freedom, we analyse the stability of nematic phases and the demixing phase behaviour of a variety of mixtures, focussing on cases where at least one of the components consists of hard rectangles or hard squares. A pure fluid of hard rectangles may exhibit, aside from the usual uniaxial nematic phase, an additional (tetratic) oriented phase, possessing two directors, which is the analogue of the biaxial or cubatic phases in three- dimensional fluids. There is computer simulation evidence that the tetratic phase might be stable with respect to phases with spatial order for rectangles with low aspect ratios. As hard rectangles are mixed with other particles not possessing stable tetratic order by themselves, the tetratic phase is destabilised, via a first- or second-order phase transition, to uniaxial nematic or isotropic phases; for hard rectangles of low aspect ratio tetratic order persists in a relatively large range of volume fractions. The order of these transitions depends on the particle geometry, dimensions and thermodynamic conditions of the mixture. The second component of the mixture has been chosen to be hard discs or disco-rectangles, the geometry of which is different from that of rectangles, leading to packing frustration and demixing behaviour, or simply rectangles of different aspect ratio. These mixtures may be good candidates for observing thermodynamically stable tetratic phases in monolayers of hard particles. Finally, demixing between fluid (isotropic--tetratic or tetratic--tetratic) phases is seen to occur in mixtures of hard squares of different sizes when the size ratio is sufficiently large.Comment: 27 pages, 9 figure

Compressive behaviour at High Temperatures of Fibre Reinforced Concretes

This paper summarizes the research that is being carried out at the Universities of Coimbra and Rio de Janeiro, on fibre reinforced concretes at high temperatures. Several high strength concrete compositions reinforced with fibres (polypropylene, steel and glass fibres) were developed. The results of compressive tests at high temperatures (300 °C, 500 °C and 600 °C) and after heating and cooling down of the concrete are presented in the paper. In both research studies, the results indicated that polypropylene fibers prevent concrete spalling.

Using binary statistics in Taurus-Auriga to distinguish between brown dwarf formation processes

Whether BDs form as stars through gravitational collapse ("star-like") or BDs and some very low-mass stars constitute a separate population which form alongside stars comparable to the population of planets, e.g. through circumstellar disk ("peripheral") fragmentation, is one of the key questions of the star-formation problem. For young stars in Taurus-Auriga the binary fraction is large with little dependence on primary mass above ~0.2Msun, while for BDs it is <10%. We investigate a case in which BDs in Taurus formed dominantly through peripheral fragmentation. The decline of the binary frequency in the transition region between star-like and peripheral formation is modelled. A dynamical population synthesis model is employed in which stellar binary formation is universal. Peripheral objects form separately in circumstellar disks with a distinctive initial mass function (IMF), own orbital parameter distributions for binaries and a low binary fraction. A small amount of dynamical processing of the stellar component is accounted for as appropriate for the low-density Taurus-Auriga embedded clusters. The binary fraction declines strongly between the mass-limits for star-like and peripheral formation. The location of characteristic features and the steepness depend on these mass-limits. Such a trend might be unique to low density regions hosting dynamically unprocessed binary populations. The existence of a strong decline in the binary fraction -- primary mass diagram will become verifiable in future surveys on BD and VLMS binarity in the Taurus-Auriga star forming region. It is a test of the (non-)continuity of star formation along the mass-scale, the separateness of the stellar and BD populations and the dominant formation channel for BDs and BD binaries in regions of low stellar density hosting dynamically unprocessed populations.Comment: accepted for publication in A&A, 11 pages, 4 figures, 1 tabl

Cambios a largo plazo en la riqueza de especies en una comunidad de aves nidificantes en un pequeño archipiélago mediterráneo

We analyzed the pattern of species richness changes in a bird–breeding bird community on a small western Mediterranean archipelago (Columbretes Islands) over a 40–year period (1964–2003). The aim of this study was to qualitatively account for the relative roles of local and regional factors in shaping the community. As expected, we found that regional factors (at the metapopulation spatial scale) increased diversity whereas local factors (i.e. ecological) probably prevented further increases in diversity. We found that the archipelago gained four new species (two seabirds and two falconids) during the study period, whereas no extinctions were recorded. The community seems partially or completely closed to some groups of species (e.g. small–sized birds such as passerines and storm–petrels), probably owing to predatory exclusion by Eleonora falcons (Falco eleonorae). As newly arrived species have breeding calendars that do not fully overlap with those of resident species, competition for space in a rather saturated area is prevented. Preservation of rare species which increase gamma (regional) diversity rather than alpha diversity with common species should be the main local conservation goal.Este trabajo analiza los patrones de cambio en la riqueza de especies en una comunidad de aves nidificantes de un pequeño archipiélago mediterráneo (las islas Columbretes, Castellón) durante un periodo de 40 años (1964–2003). El estudio pretende valorar cualitativamente la influencia relativa de los factores locales y regionales. Como se esperaba, se encontró que los factores regionales (a la escala espacial de la metapoblación) aumentaron la diversidad, mientras que los factores ecológicos locales evitaron mayores incrementos. El archipiélago ganó cuatro especies durante el periodo de estudio (dos aves marinas y dos falcónidos), mientras que no se produjo ninguna extinción. La comunidad parece parcial o totalmente cerrada a ciertos grupos de especies, tales como las aves de pequeña talla (p.ej. Paseriformes y paíños) probablemente debido a la depredación excluyente por parte de los halcones de Eleonor (Falco eleanorae). Dado que las especies que son colonizadoras recientes tienen calendarios de cría que no se solapan completamente con los de las especies residentes, se evita la competencia por el espacio de cría en un área bastante saturada. La principal meta conservacionista debe ser la protección de las especies raras, que incrementan la diversidad gamma (regional), más que la diversidad alpha de las especies comunes

High spatial resolution optical imaging of the multiple T Tauri system LkH{\alpha} 262/LkH{\alpha} 263

We report high spatial resolution i' band imaging of the multiple T Tauri system LkH$\alpha$ 262/LkH$\alpha$ 263 obtained during the first commissioning period of the Adaptive Optics Lucky Imager (AOLI) at the 4.2 m William Herschel Telescope, using its Lucky Imaging mode. AOLI images have provided photometry for each of the two components LkH$\alpha$ 263 A and B (0.41 arcsec separation) and marginal evidence for an unresolved binary or a disc in LkH$\alpha$ 262. The AOLI data combined with previously available and newly obtained optical and infrared imaging show that the three components of LkH$\alpha$ 263 are co-moving, that there is orbital motion in the AB pair, and, remarkably, that LkH$\alpha$ 262-263 is a common proper motion system with less than 1 mas/yr relative motion. We argue that this is a likely five-component gravitationally bounded system. According to BT-settl models the mass of each of the five components is close to 0.4 M$_{\odot}$ and the age is in the range 1-2 Myr. The presence of discs in some of the components offers an interesting opportunity to investigate the formation and evolution of discs in the early stages of multiple very low-mass systems. In particular, we provide tentative evidence that the disc in 263C could be coplanar with the orbit of 263AB.Comment: 11 pages, 7 figures, Accepted 2016 May

In situ electrochemical cells to study the oxygen evolution reaction by near ambient pressure x-ray photoelectron spectroscopy

In this contribution, we report the development of in situ electrochemical cells based on proton exchange membranes suitable for studying interfacial structural dynamics of energy materials under operation by near ambient pressure X-ray photoelectron spectroscopy. We will present both the first design of a batch-type two-electrode cell prototype and the improvements attained with a continuous flow three-electrode cell. Examples of both sputtered metal films and carbon-supported metal nanostructures are included demonstrating the high flexibility of the cells to study energy materials. Our immediate focus was on the study of the oxygen evolution reaction, however, the methods described herein can be broadly applied to reactions relevant in energy conversion and storage devices

Customization, extension and reuse of outdated hydrogeological software

Each scientist is specialized in his or her field of research and in the tools that he or she uses during the research in a specified site. Thus, he or she is the most suitable person for improving the tools by overcoming their limitations to realize faster and higher quality analysis. However, most scientists are not software developers. Hence, it is necessary to provide them with an easy approach that enables non-software developers to improve and customize their tools. This paper presents an approach for easily improving and customizing any hydrogeological software. It is the result of experiences with updating several interdisciplinary case studies. The main insights of this approachhave been demonstrated using four examples: MIX (FORTRAN-based), BrineMIX (C++-based), EasyQuim and EasyBal (both spreadsheet-based). The improved software has been proven to be a better tool for enhanced analysis by substantially reducing the computation time and the tedious processing of the input and output data files