4,004 research outputs found
Three-photon resonant four-photon ionization of H_2 via the C^1 â_u state
Ab initio calculations are presented for the vibrational branching ratios in three-photon resonant four-photon ionization of H_2 via the C^1Î _u state. Energy and internuclear distance dependences of the boundfree electronic transition matrix element are explicitly included to estimate deviations from the Franck-Condon approximation. While our calculated branching ratios confirm certain important trends seen experimentally, some differences remain
Resonant enhanced multiphoton ionization studies of atomic oxygen
In resonant enhanced multiphoton ionization (REMPI), an atom absorbs several photons making a transition to a resonant intermediate state and subsequently ionizing out of it. With currently available tunable narrow-band lasers, the extreme sensitivity of REMPI to the specific arrangement of levels can be used to selectively probe minute amounts of a single species (atom) in a host of background material. Determination of the number density of atoms from the observed REMPI signal requires a knowledge of the multiphoton ionization cross sections. The REMPI of atomic oxygen was investigated through various excitation schemes that are feasible with available light sources. Using quantum defect theory (QDT) to estimate the various atomic parameters, the REMPI dynamics in atomic oxygen were studied incorporating the effects of saturation and a.c. Stark shifts. Results are presented for REMPI probabilities for excitation through various 2p(3) (4S sup o) np(3)P and 2p(3) (4S sup o) nf(3)F levels
Photoionization cross sections of rovibrational levels of the B^1ÎŁ^+_u state of H_2
We report theoretical cross sections for direct photoionization of specific rovibrational levels of the Bâ^1ÎŁ^+_u electronic state of H_2. The calculated cross sections differ considerably from values recently determined by resonant enhanced multiphoton ionization (REMPI) studies. In an attempt to understand the disagreement, we analyze in detail the REMPI dynamics and find that the multiphoton ionization probability is extremely sensitive to the spatial and temporal profiles of the laser pulses. Accurate characterization of laser profiles and their jitter is therefore necessary for a comparison between theory and experiment
(2+1) resonant enhanced multiphoton ionization of H_2 via the E, F^(1)ÎŁ^+_g state
In this paper, we report the results of ab initio calculations of photoelectron angular distributions and vibrational branching ratios for the (2+1) REMPI of H_2 via the E, F^(1)ÎŁ^+_g state, and compare these with the experimental data of Anderson et al. [Chem. Phys. Lett. 105, 22 (1984)]. These results show that the observed nonâFranckâCondon behavior is predominantly due to the R dependence of the transition matrix elements, and to a lesser degree to the energy dependence. This work presents the first molecular REMPI study employing a correlated wave function to describe the Rydbergâvalence mixing in the resonant intermediate state
Shape resonances in the photoionization of cyanogen
We have studied the photoionization cross sections and photoelectron asymmetry parameters for ionization of the 1pig(X 2Pig), 5sigmag(A 2Sigma + g), and 4sigmau(B 2Sigma + u) levels of cyanogen using frozen-core HartreeâFock photoelectron continuum orbitals. The main purpose of these studies has been to extend our understanding of the dynamics of shape resonances from earlier studies of diatomic and smaller polyatomic molecules to a larger polyatomic system. The results do, in fact, reveal a rich shape resonant structure in the electronic continuum of this polyatomic system. There is a low-energy sigmau resonance which, as expected, is the CâC analog of the l=3 shape resonance seen in N2(3sigma - 1g) and several other diatomics. In contrast to this diatomic-like behavior, the presence of the two CN groups in C2N2 results in a second sigmau and a sigmag resonance corresponding to linear combinations of a l=3 shape resonance localized on the CN sites. Moreover, our results also show a pronounced shape resonant behavior in the piu continuum, which, to our knowledge, has not been seen in smaller molecules
Micromegas TPC studies at high magnetic fields using the charge dispersion signal
The International Linear Collider (ILC) Time Projection Chamber (TPC)
transverse space-point resolution goal is 100 microns for all tracks including
stiff 90 degree tracks with the full 2 meter drift. A Micro Pattern Gas
Detector (MPGD) readout TPC can achieve the target resolution with existing
techniques using 1 mm or narrower pads at the expense of increased detector
cost and complexity. The new MPGD readout technique of charge dispersion can
achieve good resolution without resorting to narrow pads. This has been
demonstrated previously for 2 mm x 6 mm pads with GEMs and Micromegas in cosmic
ray tests and in a KEK beam test in a 1 Tesla magnet. We have recently tested a
Micromegas-TPC using the charge dispersion readout concept in a high field
super-conducting magnet at DESY. The measured Micromegas gain was found to be
constant within 0.5% for magnetic fields up to 5 Tesla. With the strong
suppression of transverse diffusion at high magnetic fields, we measure a flat
50 micron resolution at 5 Tesla over the full 15 cm drift length of our
prototype TPC.Comment: 7 pages, 3 figure
Magnetoelectric effect due to local noncentrosymmetry
Magnetoelectrics often possess ions located in noncentrosymmetric
surroundings. Based on this fact we suggest a microscopic model of
magnetoelectric interaction and show that the spin-orbit coupling leads to
spin-dependent electric dipole moments of the electron orbitals of these ions,
which results in non-vanishing polarization for certain spin configurations.
The approach accounts for the macroscopic symmetry of the unit cell and is
valid both for commensurate and complex incommensurate magnetic structures. The
model is illustrated by the examples of MnWO4, MnPS3 and LiNiPO4. Application
to other magnetoelectrics is discussed.Comment: 11 pages, 2 figures, 2 table
Z_N Phases in Hot Gauge Theories
We argue that the \zn phases of hot gauge theories cannot be realized as a
real system with an Hermitean density matrix.Comment: 7 page
Realization of astrosat Model with Fused Deposition Modelling
The current work focuses on the challenges faced while realizing the 3D Model of ASTROSAT using Fused Deposition Modelling (FDM) - A material extrusion based additive manufacturing technology. Initially, the entire assembly of the ASTROSAT was studied and modified appropriately to suit the demonstration model. The modified assembly was scaled down to 1:6 scale. The scaled down model was then re-modified at the local subsystems (or individual component) level, according to the manufacturability through FDM and this was the major challenge faced due to constraint on minimum printable feature size. All the subsystems or individual components were converted to STL format and were printed on FORTUS 400MC of Stratasys. Thus obtained 3D printed parts were assembled as per the assembly drawing. It was found that, the FDM technology and Additive Manufacturing technology as a whole, is very useful in realizing the complicated demonstration modelsin a very short duration, without compromising the prominent engineering features
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