Nano-scale analysis of titanium dioxide fingerprint-development powders

Titanium dioxide based powders are regularly used in the development of latent fingerprints on dark surfaces. For analysis of prints on adhesive tapes, the titanium dioxide is suspended in a surfactant and used in the form of a small particle reagent (SPR). Analysis of commercially available products shows varying levels of effectiveness of print development, with some powders adhering to the background as well as the print. Scanning electron microscopy (SEM) images of prints developed with different powders show a range of levels of aggregation of particles. Analytical transmission electron microscopy (TEM) of the fingerprint powder shows TiO2 particles with a surrounding coating, tens of nanometres thick, consisting of Al and Si rich material. X ray photoelectron spectroscopy (XPS) is used to determine the composition and chemical state of the surface of the powders; with a penetration depth of approximately 10nm, this technique demonstrates differing Ti: Al: Si ratios and oxidation states between the surfaces of different powders. Levels of titanium detected with this technique demonstrate variation in the integrity of the surface coating. The thickness, integrity and composition of the Al/Si-based coating is related to the level of aggregation of TiO2 particles and efficacy of print development

Near-surface remote sensing of spatial and temporal variation in canopy phenology

There is a need to document how plant phenology is responding to global change factors, particularly warming trends. “Near-surface” remote sensing, using radiometric instruments or imaging sensors, has great potential to improve phenological monitoring because automated observations can be made at high temporal frequency. Here we build on previous work and show how inexpensive, networked digital cameras (“webcams”) can be used to document spatial and temporal variation in the spring and autumn phenology of forest canopies. We use two years of imagery from a deciduous, northern hardwood site, and one year of imagery from a coniferous, boreal transition site. A quantitative signal is obtained by splitting images into separate red, green, and blue color channels and calculating the relative brightness of each channel for “regions of interest” within each image. We put the observed phenological signal in context by relating it to seasonal patterns of gross primary productivity, inferred from eddy covariance measurements of surface–atmosphere CO2 exchange. We show that spring increases, and autumn decreases, in canopy greenness can be detected in both deciduous and coniferous stands. In deciduous stands, an autumn red peak is also observed. The timing and rate of spring development and autumn senescence varies across the canopy, with greater variability in autumn than spring. Interannual variation in phenology can be detected both visually and quantitatively; delayed spring onset in 2007 compared to 2006 is related to a prolonged cold spell from day 85 to day 110. This work lays the foundation for regional- to continental-scale camera-based monitoring of phenology at network observatory sites, e.g., National Ecological Observatory Network (NEON) or AmeriFlux

On the direct indecomposability of infinite irreducible Coxeter groups and the Isomorphism Problem of Coxeter groups

In this paper we prove, without the finite rank assumption, that any irreducible Coxeter group of infinite order is directly indecomposable as an abstract group. The key ingredient of the proof is that we can determine, for an irreducible Coxeter group, the centralizers of the normal subgroups that are generated by involutions. As a consequence, we show that the problem of deciding whether two general Coxeter groups are isomorphic, as abstract groups, is reduced to the case of irreducible Coxeter groups, without assuming the finiteness of the number of the irreducible components or their ranks. We also give a description of the automorphism group of a general Coxeter group in terms of those of its irreducible components.Comment: 30 page

Motion and homogenization of vortices in anisotropic Type II superconductors

The motion of vortices in an anisotropic superconductor is considered. For a system of well-separated vortices, each vortex is found to obey a law of motion analogous to the local induction approximation, in which velocity of the vortex depends upon the local curvature and orientation. A system of closely packed vortices is then considered, and a mean field model is formulated in which the individual vortex lines are replaced by a vortex density

Theory of pattern-formation of metallic microparticles in poorly conducting liquid

We develop continuum theory of self-assembly and pattern formation in metallic microparticles immersed in a poorly conducting liquid in DC electric field. The theory is formulated in terms of two conservation laws for the densities of immobile particles (precipitate) and bouncing particles (gas) coupled to the Navier-Stokes equation for the liquid. This theory successfully reproduces correct topology of the phase diagram and primary patterns observed in the experiment [Sapozhnikov et al, Phys. Rev. Lett. v. 90, 114301 (2003)]: static crystals and honeycombs and dynamic pulsating rings and rotating multi-petal vortices.Comment: 4 pages, 5 figures, submitted to Phys. Rev. Let

Effect of liposomally trapped antitumour drugs on a drug-resistant mouse lymphoma in vivo

A TLX-5 mouse lymphoma which was resistant to 1-β-D-arabinofuranosyl cytosine (AraC) was used in vivo to study the possibility of using liposomes as drug-delivery vehicles in order to overcome drug resistance

Reaction Diffusion and Ballistic Annihilation Near an Impenetrable Boundary

The behavior of the single-species reaction process $A+A\to O$ is examined near an impenetrable boundary, representing the flask containing the reactants. Two types of dynamics are considered for the reactants: diffusive and ballistic propagation. It is shown that the effect of the boundary is quite different in both cases: diffusion-reaction leads to a density excess, whereas ballistic annihilation exhibits a density deficit, and in both cases the effect is not localized at the boundary but penetrates into the system. The field-theoretic renormalization group is used to obtain the universal properties of the density excess in two dimensions and below for the reaction-diffusion system. In one dimension the excess decays with the same exponent as the bulk and is found by an exact solution. In two dimensions the excess is marginally less relevant than the bulk decay and the density profile is again found exactly for late times from the RG-improved field theory. The results obtained for the diffusive case are relevant for Mg$^{2+}$ or Cd$^{2+}$ doping in the TMMC crystal's exciton coalescence process and also imply a surprising result for the dynamic magnetization in the critical one-dimensional Ising model with a fixed spin. For the case of ballistic reactants, a model is introduced and solved exactly in one dimension. The density-deficit profile is obtained, as is the density of left and right moving reactants near the impenetrable boundary.Comment: to appear in J. Phys.

Electric and magnetic Weyl tensors in higher dimensions

Recent results on purely electric (PE) or magnetic (PM) spacetimes in n dimensions are summarized. These include: Weyl types; diagonalizability; conditions under which direct (or warped) products are PE/PM.Comment: 4 pages; short summary of (parts of) arXiv:1203.3563. Proceedings of "Relativity and Gravitation - 100 Years after Einstein in Prague", Prague, June 25-29, 2012 (http://ae100prg.mff.cuni.cz/