823 research outputs found
Mapping deuterated methanol toward L1544: I. Deuterium fraction and comparison with modeling
The study of deuteration in pre-stellar cores is important to understand the
physical and chemical initial conditions in the process of star formation. In
particular, observations toward pre-stellar cores of methanol and deuterated
methanol, solely formed on the surface of dust grains, may provide useful
insights on surface processes at low temperatures. Here we analyze maps of CO,
methanol, formaldehyde and their deuterated isotopologues toward a well-known
pre-stellar core. This study allows us to test current gas-dust chemical
models. Single-dish observations of CHOH, CHDOH, HCO,
H_2\,^{13}CO, HDCO, DCO and CO toward the prototypical pre-stellar
core L1544 were performed at the IRAM 30 m telescope. We analyze their column
densities, distributions, and compare these observations with gas-grain
chemical models. The maximum deuterium fraction derived for methanol is
[CHDOH]/[CHOH] 0.080.02, while the measured deuterium
fractions of formaldehyde at the dust peak are [HDCO]/[HCO]
0.030.02, [DCO]/[HCO] 0.040.03 and [DCO]/[HDCO]
1.20.3. Observations differ significantly from the predictions of
models, finding discrepancies between a factor of 10 and a factor of 100 in
most cases. It is clear though that to efficiently produce methanol on the
surface of dust grains, quantum tunneling diffusion of H atoms must be switched
on. It also appears that the currently adopted reactive desorption efficiency
of methanol is overestimated and/or that abstraction reactions play an
important role. More laboratory work is needed to shed light on the chemistry
of methanol, an important precursor of complex organic molecules in space.Comment: Accepted for publication in A&
Imaging the symmetry breaking of molecular orbitals in carbon nanotubes
Carbon nanotubes have attracted considerable interest for their unique
electronic properties. They are fascinating candidates for fundamental studies
of one dimensional materials as well as for future molecular electronics
applications. The molecular orbitals of nanotubes are of particular importance
as they govern the transport properties and the chemical reactivity of the
system. Here we show for the first time a complete experimental investigation
of molecular orbitals of single wall carbon nanotubes using atomically resolved
scanning tunneling spectroscopy. Local conductance measurements show
spectacular carbon-carbon bond asymmetry at the Van Hove singularities for both
semiconducting and metallic tubes, demonstrating the symmetry breaking of
molecular orbitals in nanotubes. Whatever the tube, only two types of
complementary orbitals are alternatively observed. An analytical tight-binding
model describing the interference patterns of ? orbitals confirmed by ab initio
calculations, perfectly reproduces the experimental results
LAGOVirtual: A Collaborative Environment for the Large Aperture GRB Observatory
We present the LAGOVirtual Project: an ongoing project to develop platform to
collaborate in the Large Aperture GRB Observatory (LAGO). This continental-wide
observatory is devised to detect high energy (around 100 GeV) component of
Gamma Ray Bursts, by using the single particle technique in arrays of Water
Cherenkov Detectors (WCD) at high mountain sites (Chacaltaya, Bolivia, 5300 m
a.s.l., Pico Espejo, Venezuela, 4750 m a.s.l., Sierra Negra, Mexico, 4650 m
a.s.l). This platform will allow LAGO collaboration to share data, and computer
resources through its different sites. This environment has the possibility to
generate synthetic data by simulating the showers through AIRES application and
to store/preserve distributed data files collected by the WCD at the LAGO
sites. The present article concerns the implementation of a prototype of
LAGO-DR adapting DSpace, with a hierarchical structure (i.e. country,
institution, followed by collections that contain the metadata and data files),
for the captured/simulated data. This structure was generated by using the
community, sub-community, collection, item model; available at the DSpace
software. Each member institution-country of the project has the appropriate
permissions on the system to publish information (descriptive metadata and
associated data files). The platform can also associate multiple files to each
item of data (data from the instruments, graphics, postprocessed-data, etc.).Comment: Second EELA-2 Conference Choroni, Venezuela, November 25th to 27th
200
An overview and prospective on Al and Al-ion battery technologies
Aluminum batteries are considered compelling electrochemical energy storage systems because of the natural abundance of aluminum, the high charge storage capacity of aluminum of 2980 mA h g−1/8046 mA h cm−3, and the sufficiently low redox potential of Al3+/Al. Several electrochemical storage technologies based on aluminum have been proposed so far. This review classifies the types of reported Al-batteries into two main groups: aqueous (Al-ion, and Al-air) and non-aqueous (aluminum graphite dual-ion, Al-organic dual-ion, Al-ion, and Al-sulfur). Specific focus is given to Al electrolyte chemistry based on chloroaluminate melts, deep eutectic solvents, polymers, and “chlorine-free” formulations
Convergence of the Magnus series
The Magnus series is an infinite series which arises in the study of linear
ordinary differential equations. If the series converges, then the matrix
exponential of the sum equals the fundamental solution of the differential
equation. The question considered in this paper is: When does the series
converge? The main result establishes a sufficient condition for convergence,
which improves on several earlier results.Comment: 11 pages; v2: added justification for conjecture, minor
clarifications and correction
Page size aware cache prefetching
The increase in working set sizes of contemporary applications outpaces the growth in cache sizes, resulting in frequent main memory accesses that deteriorate system per- formance due to the disparity between processor and memory speeds. Prefetching data blocks into the cache hierarchy ahead of demand accesses has proven successful at attenuating this bottleneck. However, spatial cache prefetchers operating in the physical address space leave significant performance on the table by limiting their pattern detection within 4KB physical page boundaries when modern systems use page sizes larger than 4KB to mitigate the address translation overheads. This paper exploits the high usage of large pages in modern systems to increase the effectiveness of spatial cache prefetch- ing. We design and propose the Page-size Propagation Module (PPM), a µarchitectural scheme that propagates the page size information to the lower-level cache prefetchers, enabling safe prefetching beyond 4KB physical page boundaries when the accessed blocks reside in large pages, at the cost of augmenting the first-level caches’ Miss Status Holding Register (MSHR) entries with one additional bit. PPM is compatible with any cache prefetcher without implying design modifications. We capitalize on PPM’s benefits by designing a module that consists of two page size aware prefetchers that inherently use different page sizes to drive prefetching. The composite module uses adaptive logic to dynamically enable the most appropriate page size aware prefetcher. Finally, we show that the proposed designs are transparent to which cache prefetcher is used. We apply the proposed page size exploitation techniques to four state-of-the-art spatial cache prefetchers. Our evalua- tion shows that our proposals improve single-core geomean performance by up to 8.1% (2.1% at minimum) over the original implementation of the considered prefetchers, across 80 memory-intensive workloads. In multi-core contexts, we report geomean speedups up to 7.7% across different cache prefetchers and core configurations.This work is supported by the Spanish Ministry of Science and Technology through the PID2019-107255GB project, the Generalitat de Catalunya (contract 2017-SGR-1414), the European Union Horizon 2020 research and innovation program under grant agreement No 955606 (DEEP-SEA EU project), the National Science Foundation through grants CNS-1938064 and CCF-1912617, and the Semiconductor Research Corporation project GRC 2936.001. Georgios Vavouliotis has been supported by the Spanish Ministry of Economy, Industry, and Competitiveness and the European Social Fund under the FPI fellowship No. PRE2018-087046. Marc Casas has been partially supported by the Grant RYC2017-23269 funded by MCIN/AEI/10.13039/501100011033 and ESF ‘Investing in your future’.Peer ReviewedPostprint (author's final draft
Non-line-of-sight snapshots and background mapping with an active corner camera
The ability to form reconstructions beyond line-of-sight view could be transformative in a variety of fields, including search and rescue, autonomous vehicle navigation, and reconnaissance. Most existing active non-line-of-sight (NLOS) imaging methods use data collection steps in which a pulsed laser is directed at several points on a relay surface, one at a time. The prevailing approaches include raster scanning of a rectangular grid on a vertical wall opposite the volume of interest to generate a collection of confocal measurements. These and a recent method that uses a horizontal relay surface are inherently limited by the need for laser scanning. Methods that avoid laser scanning to operate in a snapshot mode are limited to treating the hidden scene of interest as one or two point targets. In this work, based on more complete optical response modeling yet still without multiple illumination positions, we demonstrate accurate reconstructions of foreground objects while also introducing the capability of mapping the stationary scenery behind moving objects. The ability to count, localize, and characterize the sizes of hidden objects, combined with mapping of the stationary hidden scene, could greatly improve indoor situational awareness in a variety of applications
New results for the missing quantum numbers labeling the quadrupole and octupole boson basis
The many -pole boson states, with ,
realize the irreducible representation (IR) for the group reduction chains
. They have been analytically
studied and widely used for the description of nuclear systems. However, no
analytical expression for the degeneracy of the 's IR,
determined by the reduction , is available. Thus, the
number of distinct values taken by has been so far obtained by
solving some complex equations. Here we derive analytical expressions for the
degeneracy characterizing the octupole and quadrupole boson states,
respectively. The merit of this work consists of the fact that it completes the
analytical expressions for the -pole boson basis.Comment: 10page
An Arbitrary Curvilinear Coordinate Method for Particle-In-Cell Modeling
A new approach to the kinetic simulation of plasmas in complex geometries,
based on the Particle-in- Cell (PIC) simulation method, is explored. In the two
dimensional (2d) electrostatic version of our method, called the Arbitrary
Curvilinear Coordinate PIC (ACC-PIC) method, all essential PIC operations are
carried out in 2d on a uniform grid on the unit square logical domain, and
mapped to a nonuniform boundary-fitted grid on the physical domain. As the
resulting logical grid equations of motion are not separable, we have developed
an extension of the semi-implicit Modified Leapfrog (ML) integration technique
to preserve the symplectic nature of the logical grid particle mover. A
generalized, curvilinear coordinate formulation of Poisson's equations to solve
for the electrostatic fields on the uniform logical grid is also developed. By
our formulation, we compute the plasma charge density on the logical grid based
on the particles' positions on the logical domain. That is, the plasma
particles are weighted to the uniform logical grid and the self-consistent mean
electrostatic fields obtained from the solution of the logical grid Poisson
equation are interpolated to the particle positions on the logical grid. This
process eliminates the complexity associated with the weighting and
interpolation processes on the nonuniform physical grid and allows us to run
the PIC method on arbitrary boundary-fitted meshes.Comment: Submitted to Computational Science & Discovery December 201
Open Science in Software Engineering
Open science describes the movement of making any research artefact available
to the public and includes, but is not limited to, open access, open data, and
open source. While open science is becoming generally accepted as a norm in
other scientific disciplines, in software engineering, we are still struggling
in adapting open science to the particularities of our discipline, rendering
progress in our scientific community cumbersome. In this chapter, we reflect
upon the essentials in open science for software engineering including what
open science is, why we should engage in it, and how we should do it. We
particularly draw from our experiences made as conference chairs implementing
open science initiatives and as researchers actively engaging in open science
to critically discuss challenges and pitfalls, and to address more advanced
topics such as how and under which conditions to share preprints, what
infrastructure and licence model to cover, or how do it within the limitations
of different reviewing models, such as double-blind reviewing. Our hope is to
help establishing a common ground and to contribute to make open science a norm
also in software engineering.Comment: Camera-Ready Version of a Chapter published in the book on
Contemporary Empirical Methods in Software Engineering; fixed layout issue
with side-note
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