Rice straw-based activated carbons doped with SiC for enhanced hydrogen adsorption

Activated carbons (ACs) based on rice straw (RS) were synthesised using potassium carbonate as activating agent at three different K2CO3/RS weight ratios. Morphological, chemical, structural as well as textural characterisations were carried out in order to establish relationships between the physicochemical properties of the materials and their hydrogen adsorption capacities. The ACs contained potassium and silicon as the main impurities. Si was identified by XRD in both phases of silicon dioxide and silicon carbide. The presence of SiC was particularly surprising due to the rather low activation temperature, much lower than what is usually required for SiC synthesis. ACs exhibited well-developed surface areas (approximatively 2000–2100 m2 g-1) and high micropore volumes, making them suitable for hydrogen storage applications. RS-based ACs showed higher hydrogen storage capacities than those previously obtained with KOH-activated sucrose. The latter exhibited hydrogen uptakes (excess, 10 MPa, 298 K) up to 0.55 wt. %, whereas 0.65 wt. % was measured for RS-based ACs in the same conditions. The higher hydrogen capacities and isosteric heats of adsorption found here were attributed to the presence of SiC

Association Between Variants in Arsenic (+3 Oxidation State) Methyltranserase ( AS3MT ) and Urinary Metabolites of Inorganic Arsenic: Role of Exposure Level

Variants in AS3MT, the gene encoding arsenic (+3 oxidation state) methyltranserase, have been shown to influence patterns of inorganic arsenic (iAs) metabolism. Several studies have suggested that capacity to metabolize iAs may vary depending on levels of iAs exposure. However, it is not known whether the influence of variants in AS3MT on iAs metabolism also vary by level of exposure. We investigated, in a population of Mexican adults exposed to drinking water As, whether associations between 7 candidate variants in AS3MT and urinary iAs metabolites were consistent with prior studies, and whether these associations varied depending on the level of exposure. Overall, associations between urinary iAs metabolites and AS3MT variants were consistent with the literature. Referent genotypes, defined as the genotype previously associated with a higher percentage of urinary dimethylated As (DMAs%), were associated with significant increases in the DMAs% and ratio of DMAs to monomethylated As (MAs), and significant reductions in MAs% and iAs%. For 3 variants, associations between genotypes and iAs metabolism were significantly stronger among subjects exposed to water As >50 versus ≤50 ppb (water As X genotype interaction P < .05). In contrast, for 1 variant (rs17881215), associations were significantly stronger at exposures ≤50 ppb. Results suggest that iAs exposure may influence the extent to which several AS3MT variants affect iAs metabolism. The variants most strongly associated with iAs metabolism—and perhaps with susceptibility to iAs-associated disease—may vary in settings with exposure level

Microbiological Impact of the Use of Reclaimed Wastewater in Recreational Parks

Reclaimed wastewater for irrigation is an opportunity for recovery of this natural resource. In this study, microbial risk from the use of treated wastewater for irrigation of recreational parks in the city of Chihuahua, evaluating the effect of distribution distance, season, and presence of storage tanks, was analyzed. Escherichia coli, Salmonella, and multidrug-resistant bacteria were recovered from samples of reclaimed water and soils at recreational parks in Chihuahua by the membrane filtration method, using selected agars for microbial growth. Samples were taken at three different seasons. No correlation in the presence of microbial indicators and multidrug-resistant bacteria (p &gt; 0.05) was found between the distance from the wastewater treatment plant to the point of use. Presence of storage tanks in parks showed a significant effect (p &lt; 0.05) with a higher level of E. coli. The highest count in wastewater occurred in summer. We isolated 392 multidrug-resistant bacteria from water and soil; cluster analysis showed that the microorganisms at each location were of different origins. Irrigation with reclaimed wastewater did not have a negative effect on the presence of microbial indicators of the quality of soils in the parks. However, the prevalence of multidrug-resistant bacteria still represents a potential risk factor for human health

Iron influence on uranium removal from water using cellulose acetate membranes doped with activated carbon

International audienceUltrafiltration removal of uranium from water was investigated using cellulose triacetate-activated carbon (CTA-AC) composite membranes. Two different approaches were adopted: (i) adding iron chloride to the uranyl solution (FeCl3 at 0.5, 1.0, and 2.0ppm), and (ii) filtration of pure uranyl nitrate throughout composite membranes made of CTA filled with AC doped with iron. The solution to be filtrated was mixed with uranyl nitrate dissolutions at very low concentration (1.2ppm), with pH 6-8. AC was added to CTA using a casting film process to obtain dense membranes. Average uranium removal was 22 +/- 3%. The presence of iron in the membrane, either dissolved or incorporated into the activated carbon, contributed to uranium filtration, allowing reaching up to 50% removal efficiency (RE). The lowest RE value (4%) was obtained using a membrane prepared with AC oxidized with nitric acid (3HNO-AC) which does not present a significant amount of iron. Another parameter driving uranium transport is the pH, as uranium forms high molecular weight compounds in alkaline solutions, and therefore remains trapped into membrane structure. This explains the RE value of 21%, using 3HNO-AC membrane at high pH. AC dispersion also plays an important role during uranium transport. If it is well dispersed into the polymeric matrix, high RE is attained due to the high surface area available into the material. On the contrary, if AC agglomerates, uranium can go throughout the membrane, thereby increasing its permeability