Processing and microstructure of Nb-1 percent Zr-0.1 percent C alloy sheet

A systematic study was carried out to evaluate the effects of processing on the microstructure of Nb-1 wt. pct. Zr-0.1 wt. pct. C alloy sheet. The samples were fabricated by cold rolling different sheet bars that were single-, double- or triple-extruded at 1900 K. Heat treatment consisted on one- or two-step annealing of different samples at temperatures ranging from 1350 to 1850 K. The assessment of the effects of processing on microstructure involved characterization of the precipitates including the type, crystal structure, chemistry and distribution within the material as well as an examination of the grain structure. A combination of various analytical and metallographic techniques were used on both the sheet samples and the residue extracted from them. The results show that the relatively coarse orthorhombic Nb2C carbides in the as-rolled samples transformed to rather fine cubic monocarbides of Nb and Zr with varying Zr/Nb ratios upon subsequent heat treatment. The relative amount of the cubic carbides and the Zr/Nb ratio increased with increasing number of extrusions prior to cold rolling. Furthermore, the size and the aspect ratio of the grains appear to be strong functions of the processing history of the material. These and other results obtained will be presented with the emphasis on a possible relationship between processing and microstructure

Studies concerning transport of carbon in niobium, vanadium and vanadium-titanium alloys

The thermotransport and diffusion of carbon in vanadium and V-Ti alloys, and the effects of divanadium and diniobium carbide particles on the thermotransport of carbon in vanadium and niobium were investigated. A radioactive tracer technique was used to determine the concentration profiles;The transport of carbon is toward the hotter regions of the sample, corresponding to a negative heat of transport, Q*, for carbon in both vanadium and V-Ti alloys. The magnitude of Q* for carbon decreases monotonically with increasing titanium content from -42.27 kJ/mol in vanadium to -13.97 kJ/mol in V-20.5 at .% Ti, and approaches that in (beta)-Ti. The activation energy for diffusion of carbon, however, increases almost linearly from 116.3 kJ/mol in vanadium to 188.5 kJ/mol in V-20.5 at .% Ti, and decreases to 94.6 kJ/mol in (beta)-Ti;Carbon thermotransport in niobium, as in vanadium, is toward the hotter regions, however, the direction of net carbon flux reverses when these samples are in a two-phase condition. Prolonged heating of an initially two-phase sample results in the development of a one-phase region in its hotter portion. The magnitudes of the apparent heat of transport, Q(,app)*, obtained from the one-phase region of such samples are greater than those obtained from the one-phase samples at steady state, i.e., Q*. The one-phase region in the sample expands upon continued heating at a decreasing rate, and the magnitude of Q(,app)* approaches that of Q*. It is shown that the solvus of an interstitial-metal system can be determined from the concentration of the boundary between the one- and two-phase regions of different samples run under various conditions. Microstructural observations of the behavior of carbides indicate that they act solely as sources and sinks for the dissolved carbon, maintaining local equilibrium between the matrix and carbide phases. The concentration profiles calculated using a mathematical model for transport of interstitial solutes in one- and two-phase alloys are in good agreement with the experimental results. The phenomenological and atomistic aspects of the one- and two-phase thermotransport of interstitial solutes in;metals, the models and mechanisms for the phenomena, and the experimental techniques employed are discussed; (\u271)DOE Report IS-T-1149. This work was performed under contract No. W-7405-Eng-82 with the U.S. Department of Energy

Effect of loading direction on the bearing capacity of cold-reduced steel sheets

This study is concerned with double-shear bolted connections in cold-reduced steel sheets that undergo the pure bearing failure mode of the inside sheet. Compared to the published test results of bolted connections failing in the net section fracture, those involving the bearing failure mode had very wide scatter in the ultimate test loads of specimens having seemingly similar configurations. This technical note presents the laboratory test results of 51 specimens composed of G2 and G450 steel sheets, which have very different ductility properties. One new and significant finding is that the absolute bearing capacity can be considerably higher in the rolling direction of the cold-reduced steel sheet than in the perpendicular direction, even though the tensile strength has the opposite trend. Another result is that material ductility has a much greater effect on the bearing capacity than on the net section tension capacity. It was also found that snug tightening had little effect on the bearing capacity of specimens thicker than 1.5 mm. For the inside sheet of a double-shear bolted connection, the current American Iron and Steel Institute provision for bearing capacity is reasonably accurate if the load is applied in the rolling direction of G2 steel sheet, but is overoptimistic in the perpendicular direction

Combined bearing and shear-out capacity of structural steel bolted connections

This study is concerned with the strength limit state of serial bolted connections in structural steel plates. It points out that the ultimate load capacity of a serial bolted connection failing in combined bearing and shear-out cannot be computed as the simple sum of the respective ultimate bearing and ultimate shear-out capacities, which is implicitly permitted in design specifications worldwide. Based on the laboratory test results of 10 hot-rolled steel plate specimens composed of three different grades with nominal thicknesses ranging from 5 to 8 mm, the paper first establishes the ultimate bearing coefficient of a 20-mm bolted connection in a structural steel plate to be 3.5. Coupled with the shear-out equation previously derived, a design equation where the shear-out capacity of the downstream bolt varying quadratically with the end distance is then proposed to determine the combined bearing and shear-out capacity. The proposed equation is demonstrated through verification against independent laboratory test results involving 5-mm plates of three different grades to be significantly more accurate than the simple sum. Explanation for the unexplained results obtained by another researcher using his own equation is provided in this paper

Effects of processing and prolonged high temperature exposure on the microstructure of Nb-1Zr-C sheet

High temperature stability of the microstructure of Nb-1Zr sheet containing 0.1 and 0.06 wt. percent C was studied as affected by processing and prolonged 1350 K exposure with and without applied stress. Sheets were fabricated by cold rolling bars that were single-, double-, or triple-extruded at 1900 K. Creep samples were double-annealed (1 h at 1755 K + 2 h at 1475 K) prior to testing at 1350 K and 10,000 - 34,500 h. The microstructures of the as-cast, extruded, rolled, DA, and crept samples were characterized using various metallographic and analytical methods. The precipitates were rather coarse Nb2C initially, but transformed to finer (less than or equal to 1 micron) carbides of (Zr, Nb)C with each subsequent high temperature process. The grain size, and the relative amount and morphology of (Zr, Nb)C were found to be affected by the number of extrusions and to some extent by C-content. However, the microstructures of all the crept samples were similar with (Zr, Nb)C distributed throughout the matrix indicating that prolonged exposure to 1350 K gave rise to complete transformation of Nb2C to (Zr, Nb)C regardless of the processing history. These and other observations are presented with the emphasis on the correlation between processing, microstructure, and creep properties

Block shear failure planes of bolted connections - direct experimental verifications

This paper presents direct experimental verifications of the active shear planes in bolted connections, previously identified by the first author for determining the block shear capacity. The laboratory test results were obtained by independent researchers for specimens where the applied loads were resisted by the block in shear only. The first set consists of five bolted connection specimens in the webs of wide flange sections where the tensile resistance planes had been sawn off. The second set consists of ten bolted connection specimens each in one leg of an angle section that had fractured completely along the net tensile plane through a block shear failure. Comparisons among the gross, net, and active shear planes against the independent laboratory test results showed that the critical shear planes of bolted connections were best represented by the active shear planes rather than either the gross or the net shear planes. It is also pointed out that full or almost full shear strain hardening was generally achieved at the ultimate limit state of block shear failure of bolted connections in hot-rolled steel plates or sections, irrespective of the connection length. Verification against independent laboratory test results of tee sections bolted at the web reinforces this point

Characterization of the microstructure of Nb-1wt.%Zr-0.1wt.%C tubes as affected by thermomechanical processing

Microstructure of Nb-1Zr-0.1C tubes were characterized as affected by extrusion temperature of the tube shell and its thermomechanical processing to tubing. Two tube shells of about 40-mm outside diameter (OD) and 25-mm inside diameter (ID) were extruded 8:1 from a vacuum arc-melted ingot at 1900 and 1550 K. Two different OD tubes of approximately 0.36-mm wall thickness were fabricated from each tube shell by a series of 26 cold drawing operations with two in process anneals. The microstructure of tube shells and the tubing before and after a 2-step heat treatment were characterized. Residue extracted chemically from each sample was also analyzed to identify the precipitates. The results concerning the effect of the initial extrusion temperature and subsequent processing on the microstructure of the tubes are presented together with a review of results from similar work on Nb-1Zr-0.1C sheet stock

Effects of thermomechanical processing on tensile and long-time creep behavior of Nb-1 percent Zr-0.1 percent C sheet

Effects of thermomechanical processing on the mechanical properties of Nb-1 wt. percent Zr-0.1 wt. percent C, a candidate alloy for use in advanced space power systems, were investigated. Sheet bars were cold rolled into 1-mm thick sheets following single, double, or triple extrusion operations at 1900 K. All the creep and tensile specimens were given a two-step heat treatment 1 hr at 1755 K + 2 hr 1475 K prior to testing. Tensile properties were determined at 300 as well as at 1350 K. Microhardness measurements were made on cold rolled, heat treated, and crept samples. Creep tests were carried out at 1350 K and 34.5 MPa for times of about 10,000 to 19,000 hr. The results show that the number of extrusions had some effects on both the microhardness and tensile properties. However, the long-time creep behavior of the samples were comparable, and all were found to have adequate properties to meet the design requirements of advanced power systems regardless of thermomechanical history. The results are discussed in correlation with processing and microstructure, and further compared to the results obtained from the testing of Nb-1 wt. percent Zr and Nb-1 wt. percent Zr-0.06 wt. percent C alloys

Effects of thermomechanical processing on the microstructure and mechanical properties of Nb-1Zr-C alloys

A systematic study to evaluate the effects of thermomechanical processing on the microstructure and mechanical properties of Nb-1Zr alloy sheet containing 0.06 and 0.1 wt.%C (PWC-11) was conducted and compared to the results of Nb-1Zr. Coarse orthorhombic Nb2C precipitates were present in all the cast, extruded and cold rolled Nb-Zr samples containing C. After high temperature (greater than 0.5 T(sub m)) exposure (with or without applied stress), the Nb2C transforms to very fine and extremely stable FCC (Zr, Nb)C dispersoid, resulting in a highly creep resistant material. Only ZrO2 precipitates were found in Nb-1Zr. The creep strength of the 0.06C and the 0.1C carbide strengthened alloys were much superior to Nb-1Zr. At 1350 K the strength of the 0.06C alloy was about three times that of Nb-1Zr, while the 0.1C alloy had about five times the creep stress capability of Nb-1Zr. The tensile strength, long term creep strength, and stability of the microstructure of the PWC-11 sheet appear to be independent of the number of 1900 K extrusions performed prior to cold rolling. The microhardness of these single, double and triple extnided PWC-11 sheets also were comparable. The tensile strength of PWC-11 and Nb-1Zr at room temperature and 1350 K were comparable