1,404 research outputs found

    Study of deformation texture in an AZ31 magnesium alloy rolled at wide range of rolling speed and reductions

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    Having the lowest density among all structural metals, magnesium has opened new horizons for developing commercial alloys with successful use in a wide variety of applications [1-2]. However, the plasticity of Mg is restricted at low temperatures because: (a) only a small number of deformation mechanisms can be activated [3-4], and (b) a preferred crystallographic orientation (texture) develops in wrought alloys, especially in flat-rolled sheets [5-7]. Therefore, manufacturing processes such as rolling and stamping should be performed at elevated temperatures [1, 8]. These barriers to the manufacturing process increase the price of magnesium wrought alloy products and limits the use of Mg to castings [9-10]. As a result, many studies have been conducted to improve formability by investigating the effect of manufacturing process. Therefore the current sheet production techniques, based on DC casting and hot rolling, are basically slow because the demand is easily met [11]. Twin roll casting followed by hot rolling appears to be processing route which can fulfil high volumes and reduced costs. The present authors succeeded in single-pass large draught rolling of various magnesium alloy sheets at low temperature (<473K) by high speed rolling [12]. Based on the data available in those works [13- 17], the sheet obtained by high-speed rolling exhibited a fine-grained microstructure (mean grain size of 2-3 μm), with good mechanical properties. For these advantages, the high speed rolling is a promising process to produce high-quality rolled magnesium alloy sheets at a low cost. For these advantages, the HSR is a promising process to produce high-quality rolled magnesium alloy sheets at a low cost. The goal of this research is thus to investigate the mechanisms responsible for the much higher rollability and the grain refinement after HSR. To do that, in this study, different rolling speeds from 15 to 1000 m/min were employed to twin rolled cast AZ31B magnesium alloy and different reductions

    Constraints on Hf and Zr mobility in high-sulfidation epithermal systems: formation of kosnarite, KZr2(PO4)3, in the Chaquicocha gold deposit, Yanacocha district, Peru

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    We report the first occurrence of Hf-rich kosnarite [K(Hf,Zr)2(PO4)3], space group R-3c, Z = 6, in the giant Chaquicocha high-sulfidation epithermal gold deposit in the Yanacocha mining district, Peru. Kosnarite crystals are small (<100 μm) and occur in 2–3-mm-thick veins that cut intensively silicified rocks. The paragenesis includes a first stage of As-free pyrite and quartz (plus gratonite and rutile), followed by trace metal-rich pyrite [(Fe,As,Pb,Au)S2] and secondary Fe sulfates. Kosnarite is associated with quartz and is clearly late within the paragenetic sequence. Electron microprobe analyses (EMPA) of kosnarite show relatively high concentrations of HfO2 and Rb2O (7.61 and 1.05 wt.%, respectively). The re-calculated chemical formulas of kosnarite vary from KΣ1.00(Zr1.93Na0.01Hf0.01Mn0.01)Σ1.96(P3.04O4)Σ3 to (K0.92Rb0.05Na0.03)Σ1.00(Zr1.81Hf0.19)Σ2.00 [(P2.98Si0.02As0.01)Σ3.01O4]Σ3, where Hf and Rb are most likely incorporated according to a coupled substitution of Hf4+ + Rb+ ⇔ Zr4+ + K+. Back-scattered electron (BSE) images and elemental mapping of kosnarite reveal that Hf and Rb are enriched in 2–10-μm-wide oscillatory and/or sector zones. High-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) observations of such zones reveal a pattern of alternating, 5–50-nm-thick, Hf-rich and Zr-rich nanozones. These high-resolution observations indicate that the incorporation of Hf does not appear to cause significant distortion in the kosnarite structure. Semiquantitative TEM-energy-dispersive X-ray spectrometry (EDS) analyses of the nano-layers show up to 22 wt.% of HfO2, which corresponds to 31 mol% of the hypothetical, KHf2(PO4)3, end-member. The presence of kosnarite in the advanced argillic alteration zone at Yanacocha is indicative of Hf and Zr mobility under highly acidic conditions and points towards an unforeseen role of phosphates as sinks of Zr and Hf in high-sulfidation epithermal environments. Finally, potentially new geochronological applications of highly insoluble vein kosnarite, including Rb-Sr dating, may provide further age constraints in pervasively altered areas where other isotopic systems might have been reset

    Quasicontinuum γ\gamma-decay of 91,92^{91,92}Zr: benchmarking indirect (n,γn,\gamma) cross section measurements for the ss-process

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    Nuclear level densities (NLDs) and γ\gamma-ray strength functions (γ\gammaSFs) have been extracted from particle-γ\gamma coincidences of the 92^{92}Zr(p,pγp,p' \gamma)92^{92}Zr and 92^{92}Zr(p,dγp,d \gamma)91^{91}Zr reactions using the Oslo method. The new 91,92^{91,92}Zr γ\gammaSF data, combined with photonuclear cross sections, cover the whole energy range from Eγ1.5E_{\gamma} \approx 1.5~MeV up to the giant dipole resonance at Eγ17E_{\gamma} \approx 17~MeV. The wide-range γ\gammaSF data display structures at Eγ9.5E_{\gamma} \approx 9.5~MeV, compatible with a superposition of the spin-flip M1M1 resonance and a pygmy E1E1 resonance. Furthermore, the γ\gammaSF shows a minimum at Eγ23E_{\gamma} \approx 2-3~MeV and an increase at lower γ\gamma-ray energies. The experimentally constrained NLDs and γ\gammaSFs are shown to reproduce known (n,γn, \gamma) and Maxwellian-averaged cross sections for 91,92^{91,92}Zr using the {\sf TALYS} reaction code, thus serving as a benchmark for this indirect method of estimating (n,γn, \gamma) cross sections for Zr isotopes.Comment: 10 pages and 9 figure

    Doppler color flow “proximal isovelocity surface area” method for estimating volume flow rate: Effects of orifice shape and machine factors

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    AbstractPreviously described Doppler color How mapping methods for estimating the severity of valvular regurgitation have focused on the distal jet. In this study, a newer Doppler color flow technique, focusing on the flow proximal to an orifice, was used. This method identifies a proximal isovelocity surface area (PISA) by displaying an aliasing interface. Volume flow rate (cm3/s) can be calculated as PISA (cm2) × aliasing velocity (cm/s). For planar circular orifices, a hemi-elliptic model accurately approximated the shape of PISA.Clinically, however, orifice shapes may be noncircular. In vitro flow experiments (n = 226) using orifices of various shapes (ellipse, square, triangle, star, rectangle) were performed. Volume flow rate calculated using a hemi-elliptic model for PISA was accurate, with average percent differences from actual flow rate = +4.3% for a square, −4.2% for a triangle, −4.7% for a star, −4.5% for an ellipse and −2.8% for a rectangle. However, average percent differences for calculated volume flow rates using a hemispheric model for PISA shape ranged from −11.6% (square) to −34.8% (rectangle).In addition, to evaluate whether PISA is influenced by machine factors, in vitro studies (n = 83) were performed. For a volume flow rate of 13 liters/min, the color aliasing radius was not affected by: 1) system gain(radius = 9.9 mm at −20 dB versus 10.4 mm at +20 dB); 2) wall filter(10.8 mm at high versus 11.2 mm at tow); 3) frame rate(11.2 mm at 6/s versus 10.6 mm at 22/s); 4) transmit power(10.3 mm at high versus 10.1 mm at low); and 5) packet size(10.6 mm at 4 samples/line versus 10.5 mm at 8 samples/line). The aliasing radius was lower at higher aliasing velocities. However, the calculated volume flow rate was not affected by changes in aliasing velocity.It is concluded that differences in planar orifice shape do not affect volume flow rate calculated using a hemi-elliptic model. Furthermore, changes in machine factors do not alter volume flow rate calculated using the PISA method. The PISA method may have advantages over previous Doppler color flow methods in calculating volume flow rate and may be useful clinically in estimating valvular regurgitant or shunt volume

    Pygmy dipole strength close to particle-separation energies - the case of the Mo isotopes

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    The distribution of electromagnetic dipole strength in 92, 98, 100 Mo has been investigated by photon scattering using bremsstrahlung from the new ELBE facility. The experimental data for well separated nuclear resonances indicate a transition from a regular to a chaotic behaviour above 4 MeV of excitation energy. As the strength distributions follow a Porter-Thomas distribution much of the dipole strength is found in weak and in unresolved resonances appearing as fluctuating cross section. An analysis of this quasi-continuum - here applied to nuclear resonance fluorescence in a novel way - delivers dipole strength functions, which are combining smoothly to those obtained from (g,n)-data. Enhancements at 6.5 MeV and at ~9 MeV are linked to the pygmy dipole resonances postulated to occur in heavy nuclei.Comment: 6 pages, 5 figures, proceedings Nuclear Physics in Astrophysics II, May 16-20, Debrecen, Hungary. The original publication is available at www.eurphysj.or

    Photo-disintegration cross section measurements on 186^{186}W, 187^{187}Re and 188^{188}Os: Implications for the Re-Os cosmochronology

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    Cross sections of the 186^{186}W, 187^{187}Re, 188^{188}Os(γ,n\gamma,n) reactions were measured using quasi-monochromatic photon beams from laser Compton scattering (LCS) with average energies from 7.3 to 10.9 MeV. The results are compared with the predictions of Hauser-Feshbach statistical calculations using four different sets of input parameters. In addition, the inverse neutron capture cross sections were evaluated by constraining the model parameters, especially the E1E1 strength function, on the basis of the experimental data. The present experiment helps to further constrain the correction factor FσF_{\sigma} for the neutron capture on the 9.75 keV state in 187^{187}Os. Implications of FσF_{\sigma} to the Re-Os cosmochronology are discussed with a focus on the uncertainty in the estimate of the age of the Galaxy.Comment: 11 page
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