Series impedance of distribution cables with sector-shaped conductors

Models of power distribution networks require accurate cable impedance data. For unbalanced networks, both the self-impedances and the mutual impedances are needed. However, published studies use differing approaches to determine cable impedances, leaving uncertainty over the level of detail required. This paper compares impedances provided by the manufacturer with those from several analytical methods, showing the impact of modelling the non-circular geometry and of including corrections allowing for the AC resistance. The analysis is compared to results from a freely available finite element solver where the current distribution is modelled in detail, taking account of eddy currents and the rotation of the cores relative to the neutral due to the cable lay. At 50 Hz, the analytical methods provide a good approximation but the finite element results show that eddy currents affect the impedance at harmonic frequencies. The results also show the impact of including the ground path in the impedance calculation. The current distribution in the ground has a wide cross-sectional area, suggesting that the assumption of a perfect multi-grounded neutral is inappropriate for LV networks with short cable lengths

Assumptions and approximations typically applied in modelling LV networks with high penetrations of low carbon technologies

Uncertainties in the assessment of LV network capacity to accommodate PV and other low-carbon technologies can lead to installation constraints or costly network reinforcements that may not be entirely necessary. This paper reviews the numerous assumptions often used in such assessments and highlights those relating to time resolution of demand models, harmonics, network grounding and impedance modelling as being particularly questionable. In many cases, the individual assumptions may be low risk, but there is greater uncertainty when assumptions are applied in combination

Impacts of demand data time resolution on estimates of distribution system energy losses

Copper losses in low voltage distribution circuits are a significant proportion of total energy losses and contribute to higher customer costs and carbon emissions. These losses can be evaluated using network models with customer demand data. This paper considers the under-estimation of copper losses when the spiky characteristics of real customer demands are smoothed by arithmetic mean averaging. This is investigated through simulation and by analysis of measured data. The mean losses in cables and equipment supplying a single dwelling estimated from half-hourly data were found to have significant errors of 40%, compared to calculations using high resolution data. Similar errors were found in estimates of peak thermal loading over a half-hour period, with significant variation between results for each customer. The errors reduce as the demand is aggregated, with mean losses for a group of 22 dwellings under-estimated by 7% using half-hourly data. This paper investigates the relationship between the demand data time resolution and errors in the estimated losses. Recommendations are then provided for the time resolution to be used in future measurements and simulation studies. A linear extrapolation technique is also presented whereby errors due to the use of averaged demand data can be reduced

Carbamazepine on a carbamazepine monolayer forms unique 1D supramolecular assemblies

High-resolution STM imaging of the structures formed by carbamazepine molecules adsorbed onto a pseudo-ordered carbamazepine monolayer on Au(111) shows the formation of previously unreported 1-dimensional supramolecular assemblies

Supramolecular hair dyes : a new application of cocrystallization

The manuscript presents the first report of hair dyes of various colors formed by the cocrystallization reactions. Unlike the most popular oxidative hair dye (OHD) products, these dyes are NH3 free and do not require H2O2 as a color developer. The importance of these new hair dyes products is further enhanced by recent reports which indicate that some of the OHDs may be carcinogeni

PEGylated silk nanoparticles for anticancer drug delivery

Silk has a robust clinical track record and is emerging as a promising biopolymer for drug delivery, including its use as nanomedicine. However, silk-based nanomedicines still require further refinements for full exploitation of their potential; the application of "stealth" design principals is especially necessary to support their evolution. The aim of this study was to develop and examine the potential of PEGylated silk nanoparticles as an anticancer drug delivery system. We first generated B. mori derived silk nanoparticles by driving β-sheet assembly (size 104 ± 1.7 nm, zeta potential -56 ± 5.6 mV) using nanoprecipitation. We then surface grafted polyethylene glycol (PEG) to the fabricated silk nanoparticles and verified the aqueous stability and morphology of the resulting PEGylated silk nanoparticles. We assessed the drug loading and release behavior of these nanoparticles using clinically established and emerging anticancer drugs. Overall, PEGylated silk nanoparticles showed high encapsulation efficiency (>93%) and a pH-dependent release over 14 days. Finally, we demonstrated significant cytotoxicity of drug loaded silk nanoparticles applied as single and combination nanomedicines to human breast cancer cells. In conclusion, these results, taken together with prior silk nanoparticle data, support a viable future for silk-based nanomedicines

The bright extragalactic ALMA redshift survey (BEARS) – II. Millimetre photometry of gravitational lens candidates

We present 101- and 151-GHz ALMA continuum images for 85 fields selected from Herschel observations that have 500-μm flux densities >80 mJy and 250–500-μm colours consistent with z > 2, most of which are expected to be gravitationally lensed or hyperluminous infrared galaxies. Approximately half of the Herschel 500-μm sources were resolved into multiple ALMA sources, but 11 of the 15 brightest 500-μm Herschel sources correspond to individual ALMA sources. For the 37 fields containing either a single source with a spectroscopic redshift or two sources with the same spectroscopic redshift, we examined the colour temperatures and dust emissivity indices

Factors that may mediate the relationship between physical activity and the risk for developing knee osteoarthritis

Studies investigating the effect of physical activity on risk for developing osteoarthritis at weight-bearing joints have reported conflicting results. We examine evidence to suggest that this may be due to the existence of subgroups of individuals who differ in their response to physical activity, as well as methodological issues associated with the assessment of knee joint structure and physical activity. Recommendations for future studies of physical activity and the development of knee osteoarthritis are discussed

Fractionation of potentially toxic elements in urban soils from five European cities by means of a harmonised sequential extraction procedure

The revised (four-step) BCR sequential extraction procedure has been applied to fractionate the chromium, copper, iron, manganese, nickel, lead and zinc contents in urban soil samples from public-access areas in five European cities. A preliminary inter-laboratory comparison was conducted and showed that data obtained by different laboratories participating in the study were sufficiently harmonious for comparisons to be made between cities and land types (e.g. parks, roadside, riverbanks, etc.). Analyte recoveries by sequential extraction, with respect to direct aqua regia digestion, were generally acceptable (100 ± 15%). Iron, nickel and, at most sites, chromium were found mainly in association with the residual phase of the soil matrix. Copper was present in the reducible, oxidisable and residual fractions, whilst zinc was found in all four sequential extracts. Manganese was strongly associated with reducible material as, in some cities, was lead. This is of concern because high lead concentrations were present in some soils (>500 mg kg−1) and the potential exists for remobilisation under reducing conditions. As would be expected, extractable metal contents were generally highest in older, more heavily industrialised cities. Copper, lead and zinc showed marked (and often correlated) variations in concentrations between sites within the same city whereas manganese and, especially, iron, did not. No overall relationships were, however, found between analyte concentrations and land use, nor between analyte partitioning and land use