1,102 research outputs found

    Consumption Patterns of Male and Female Headed Households in Pakistan: Evidence from PSLM 2007-08

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    Recent years have witnessed growing interest in analysing the welfare outcomes of female headed households (FHHs) in the developing world. The theoretical argument for examining female headship and family welfare is underpinned by two important considerations. The first concerns households’ access to resources, while the second pertains to control over the allocation of resources within the household [DeGraff and Bilsborrow (1993)]. A priori female headed households are expected to have access to a lower level of resources than the conventional male-headed households for a variety of reasons.1 However, this lower resource envelop experienced by female headed households may be partially offset by the way resources are allocated within such households. Several studies have revealed that resources under the control of women are more likely to be allocated for productive purposes that promote family welfare as compared to resource allocation under the control of men. In the context of Pakistan, the present paper aims to explore how resource allocation within female headed households differs from male headed households by examining the consumption patterns of both female and male headed households in the country

    Optimization of simultaneous production of waste cooking oil based-biodiesel using iron-manganese doped zirconia-supported molybdenum oxide nanopeprintss catalyst

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    Biodiesel derived from simultaneous esterification and transesterification of waste cooking oil has been attracting consideration as a replacement green fuel for diesel fuels, as it is economically feasible and circumvents the issue of energy versus food, which is estimated to take place with current biodiesel production techniques. In this optimization study, iron-manganese doped zirconia-supported molybdenum oxide catalyst has been prepared and used in the synthesis of waste cooking oil based biodiesel by a simultaneous esterification and transesterification method. The catalyst is prepared via an impregnation method and consequently characterized by XRD, TEM, TGA (thermogravimetric analysis), TPD-NH3, and Brunauer–Emmer–Teller (BET) techniques. The simultaneous process for biodiesel production has been assessed and improved statistically via response surface methodology in combination with the central composite design. It has been established that the process for synthesis of waste cooking oil based biodiesel achieved about 96.8% biodiesel yield at a best condition of 200 °C, waste cooking oil/ methanol molar ratio of 1:30 and 5.0 wt. % as loading of the catalyst. The highest ester yield of 96.8% has been obtained due to the improved physicochemical properties of zirconia-supported molybdenum oxide catalyst which accesses diffusion of the reactants to the active sites

    Assessment of the influence of intrinsic environmental and geographical factors on the bacterial ecology of pit latrines

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    Funding Information: This research received financial support from the Bill and Melinda Gates Foundation (grant number OPP52641). AWW and JP were supported by the Wellcome Trust [grant number 098051]. AWW and the Rowett Institute of Nutrition and Health, University of Aberdeen, receive core funding support from the Scottish Government Rural and Environmental Science and Analysis Service (RESAS). UZ is funded by Natural Environment Research Council (NERC) Independent Research Fellowship (NE/L011956/1). CQ is funded through an Medical Research Council fellowship (MR/M50161X/1) as part of the MRC Cloud Infrastructure for Microbial Bioinformatics consortium (MR/L015080/1).Peer reviewedPublisher PD

    Behavior of thin-walled tubes with combined cross-sectional geometries under oblique loading

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    Hollow tubes are the most important part of any structure because of their load-bearing capacity, lightweight and inexpensive manufacturing cost. One of the methods for improving the performance under quasi-static loading is to vary the cross-sectional shapes. In the real case, structures are seldom subjected to pure axial or pure bending rather they are subjected to a combination of two load cases i.e. oblique loading. In this paper, the circular cross-section was combined with four different polygonal cross-sections namely tetragon, hexagon, octagon and decagon and a total of 13 geometries were obtained. The buckling behavior of each tube was investigated numerically at various angles of inclination. Each tube was modeled in SOLIDWORKS and then was analyzed in ANSYS. Linear buckling code was used for finding the critical load at various angles ranging from 0° to 14°. The overall result was then compared and it was found that the proposed geometry can be a good alternative over conventional circular tubes in terms of load-bearing capacity at angular load

    Sensory hypoinnervation in club foot

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    Abstract We have compared the density of nerve fibres in the synovium in club foot with that of specimens obtained from the synovium of the hip at operations for developmental dysplasia. The study focused on the sensory neuropeptides substance P; calcitonin gene-related peptide; protein gene product 9.5, a general marker for mature peripheral nerve fibres; and growth associated protein 43, a neuronal marker for new or regenerating nerve fibres. In order to establish whether there might be any inherent difference we analysed the density of calcitonin gene-related peptide-positive nerve fibres in the hip and ankle joints in young rats. Semi-quantitative analysis showed a significant reduction in the number of sensory and mature nerve fibres in the synovium in club foot compared with the control hips. Calcitonin gene-related peptide (CGRP) positive fibres were reduced by 28%, substance P-positive fibres by 36% and protein gene product 9.5-positive fibres by 52% in club foot. The growth associated protein 43-positive fibres also seemed to be less in six samples of club foot. No difference in the density of CGRP-positive nerve fibres was observed in the synovium between ankle and hip joints in rats. The lack of sensory input may be responsible for the fibrosis and soft-tissue contractures associated with idiopathic club foot

    Muscle healing and nerve regeneration in a muscle contusion model in the rat

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    The nervous system is known to be involved in inflammation and repair. We aimed to determine the effect of physical activity on the healing of a muscle injury and to examine the pattern of innervation. Using a drop-ball technique, a contusion was produced in the gastrocnemius in 20 rats. In ten the limb was immobilised in a plaster cast and the remaining ten had mobilisation on a running wheel. The muscle and the corresponding dorsal-root ganglia were studied by histological and immunohistochemical methods.In the mobilisation group, there was a significant reduction in lymphocytes (p = 0.016), macrophages (p = 0.008) and myotubules (p = 0.008) between three and 21 days. The formation of myotubules and the density of nerve fibres was significantly higher (both p = 0.016) compared with those in the immobilisation group at three days, while the density of CGRP-positive fibres was significantly lower (p = 0.016) after 21 days.Mobilisation after contusional injury to the muscle resulted in early and increased formation of myotubules, early nerve regeneration and progressive reduction in inflammation, suggesting that it promoted a better healing response

    Ordering of droplets and light scattering in polymer dispersed liquid crystal films

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    We study the effects of droplet ordering in initial optical transmittance through polymer dispersed liquid crystal (PDLC) films prepared in the presence of an electrical field. The experimental data are interpreted by using a theoretical approach to light scattering in PDLC films that explicitly relates optical transmittance and the order parameters characterizing both the orientational structures inside bipolar droplets and orientational distribution of the droplets. The theory relies on the Rayleigh-Gans approximation and uses the Percus-Yevick approximation to take into account the effects due to droplet positional correlations.Comment: revtex4, 18 pages, 8 figure

    The effect of sulfate contents on the surface properties of iron–manganese doped sulfated zirconia catalysts

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    The iron–manganese doped sulfated zirconia catalysts were prepared via precipitation method; the sulfation was carried out by impregnation with different amounts of sulfate (4%, 10% and 16% SO4− 2 by weight) with the addition of Fe–Mn doped and calcined at 600 °C for 3 h. The prepared catalysts were characterized by TGA-DTA, XRD, BET, FT-IR, TEM, TPD-NH3 and XPS. XRD and BET results revealed that the addition of sulfate imparts special stabilization to the catalytically active tetragonal phase of zirconia. All the iron–manganese doped sulfated zirconia catalysts were found to have strong acid sites, high surface area and small crystallite size

    Synthesis of ferric-manganese doped tungstated zirconia nanoparticles as heterogeneous solid superacid catalyst for biodiesel production from waste cooking oil

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    The solid superacid catalyst ferric-manganese doped tungstated zirconia (FMWZ) nanoparticles was prepared by impregnation reaction followed by calcination at 600°C for 3 hr and had been characterized by X-ray diffraction (XRD), thermal gravimetric analysis (TGA), temperature programmed desorption of NH3 (TPD-NH3), X-ray fluorescence (XRF), transmission electron microscopy (TEM), and Brunner-Emmett-Teller (BET) surface area measurement. The transesterification reaction was used to determine the optimum conditions of methanolysis of waste cooking oil with FMWZ nanoparticles as heterogeneous solid superacid catalyst. The reactions variables such as reaction temperatures, catalyst loading, molar ratio of methanol/oil and reusability were also assessed which effects the waste cooking oil methyl esters (WCOME’s) production yield. The catalyst was reused ten times without any loss in activity and maximum yield of 96% was achieved at the optimized conditions of reaction temperature of 200°C; stirring speed of 600 rpm, 1:25 molar ratio of oil to alcohol and 4% w/w catalyst loading. The fuel properties of the WCOME’s were discussed in light of ASTM D6751 biodiesel standard
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