Aharonov-Bohm phase as quantum gate in two-electron charge qubits

We analyze the singlet-triplet splitting on a planar array of quantum dots coupled capacitively to a set of external voltage gates. The system is modelled using an extended Hubbard Hamiltonian keeping two excess electrons on the array. The voltage dependence of the low-energy singlet and triplet states is analyzed using the Feshbach formalism. The formation of a well decoupled two-level system in the ground state is shown to rely on the fact of having two particles in the system. Coherent operation of the array is studied with respect to single quantum bit operations. One quantum gate is implemented via voltage controls, while for the necessary second quantum gate, a uniform external magnetic field is introduced. The Aharonov-Bohm phases on the closed loop tunnel connections in the array are used to effectively suppress the tunneling, despite a constant tunneling amplitude in the structure. This allows one to completely stall the qubit in any arbitrary quantum superposition, providing full control of this interesting quantum system.Comment: 6 pages, 5 figures (submitted to PRB

Magnon spin Hall magnetoresistance of a gapped quantum paramagnet

Motivated by recent experimental work, we consider spin transport between a normal metal and a gapped quantum paramagnet. We model the latter as the magnonic Mott-insulating phase of an easy-plane ferromagnetic insulator. We evaluate the spin current mediated by the interface exchange coupling between the ferromagnet and the adjacent normal metal. For the strongly interacting magnons that we consider, this spin current gives rise to a spin Hall magnetoresistance that strongly depends on the magnitude of the magnetic field, rather than its direction. This Letter may motivate electrical detection of the phases of quantum magnets and the incorporation of such materials into spintronic devices.Comment: 5 pages, 5 figure

Physicochemical parameters and bioactive compounds of strawberry Ttee (Arbutus unedo L.) honey

Botanical origin, physicochemical properties (ash, colour, diastase activity, electrical conductivity (EC), hydroxymethylfurfural (HMF), moisture, optical rotation (OP), pH, reducing sugars, total acidity, total soluble solids, and water activity), bioactive compounds (BC), and antioxidant activity obtained from strawberry tree honey from South Portugal were investigated. Results showed that the pollen analysis and physicochemical parameters were found within to meet international honey specifications. Significant differences (P < 0.05) in results of ash content, EC, HMF, OP and colour when were compared with analogous famous Italian honey (Sardinia island). For BC, total phenolic and total flavonoid content were 94.47mg gallic acid/100 g and 5.33 mg quercetin/100 g, respectively. Concerning Portuguese honey, it was also found that radical scavenging activity (DPPH assay) was 43.46% and antioxidant activity was 18.85 mg ascorbic acid equivalent/100 g and 9.92 mg quercetin equivalent/100 g. These results confirmed that Portuguese strawberry tree honey has the highest antioxidant activity, when compared with other kinds of honey. This complete report demonstrates advantages and can help to promote consumption and shown their benefical properties (e.g., antioxidant); which will may increase the commercial value.Erasmus Mundus European Program [2008-1022/002

Helicoidal Fields and Spin Polarized Currents in CNT-DNA Hybrids

We report on theoretical studies of electronic transport in the archetypical molecular hybrid formed by DNA wrapped around single-walled carbon nanotubes (CNTs). Using a Green's function formalism in a $\pi$-orbital tight-binding representation, we investigate the role that spin-orbit interactions play on the CNT in the case of the helicoidal electric field induced by the polar nature of the adsorbed DNA molecule. We find that spin polarization of the current can take place in the absence of magnetic fields, depending strongly on the direction of the wrapping and length of the helicoidal field. These findings open new routes for using CNTs in spintronic devices.Comment: 4 pages, 5 figure

Potential landscapes and induced charges near metallic islands in three dimensions

We calculate electrostatic potential landscapes for an external probe charge in the presence of a set of metallic islands. Our numerical calculation in three dimensions (3D)uses an efficient grid relaxation technique. The well-known relaxation algorithm for solving the Poisson equation in two dimensions is generalized to 3D. In addition,all charges on the system, free as well as induced charges,are determined accurately and self-consistently to satisfy the desired boundary conditions. This allows the straightforward calculation of the potential on the outer boundary using the free space electrostatic Green's function,as well as the calculation of the entire capacitance matrix of the system. Physically interesting examples of nanoscale systems are presented and analyzed.Comment: 6 pages, 6 figures, submitted to PR

Currents and pseudomagnetic fields in strained graphene rings

We study the effects of strain on the electronic properties and persistent current characteristics of a graphene ring using the Dirac representation. For a slightly deformed graphene ring flake, one obtains sizable pseudomagnetic (gauge) fields that may effectively reduce or enhance locally the applied magnetic flux through the ring. Flux-induced persistent currents in a flat ring have full rotational symmetry throughout the structure; in contrast, we show that currents in the presence of a circularly symmetric deformation are strongly inhomogeneous, due to the underlying symmetries of graphene. This result illustrates the inherent competition between the `real' magnetic field and the `pseudo' field arising from strains, and suggest an alternative way to probe the strength and symmetries of pseudomagnetic fields on graphene systems

ELECTROCHEMICAL CHARACTERIZATION OF NEW 1,5-BENZODIAZEPINE DERIVATIVES

Indexación: Web of Science; Scielo.Cyclic voltammetry was used to study the electrochemical behavior of new 1,5-benzodiazepine derivatives on a glassy carbon electrode. Well-defined oxidation peaks were observed in DMSO. The Electrochemical response of the glassy carbon electrode was evaluated as function of the scan rate, showing that the electron transfer process for compound (5) and (6) resulted to be controlled by diffusion.http://ref.scielo.org/3nfd9