An innovative, fast and facile soft-template approach for the fabrication of porous PDMS for oil-water separation

Oil wastewater and spilled oil caused serious environmental pollution and damage to public health in the last years. Therefore, considerable efforts are made to develop sorbent materials able to separate oil from water with high selectivity and sorption capacity. However most of them are low reusable, with low volume absorption capacity and poor mechanical properties. Moreover, the synthesis is time-consuming, complex and expensive limiting its practical application in case of emergency. Here we propose an innovative approach for the fabrication of porous PDMS starting from an inverse water-in-silicone procedure able to selectively collect oil from water in few seconds. The synthesis is dramatically faster than previous approaches, permitting the fabrication of the material in few minutes independently from the dimension of the sponges. The porous material evidenced a higher volume sorption capacity with respect to other materials already proposed for oil sorption from water and excellent mechanical and reusability properties.This innovative fast and simple approach can be successful in case of emergency, as oil spill accidents, permitting in situ fabrication of porous absorbents

Wrinkling in engineering fabrics: a comparison between two different comprehensive modelling approaches

We consider two ‘comprehensive’ modelling approaches for engineering fabrics. We distinguish the two approaches using the terms ‘semi-discrete’ and ‘continuum’, reflecting their natures. We demonstrate a fitting procedure, used to identify the constitutive parameters of the continuum model from predictions of the semi-discrete model, the parameters of which are in turn fitted to experimental data. We, then, check the effectiveness of the continuum model by verifying the correspondence between semi-discrete and continuum model predictions using test cases not previously used in the identification process. Predictions of both modelling approaches are compared against full-field experimental kinematic data, obtained using stereoscopic digital image correlation techniques, and also with measured force data. Being a reduced order model and being implemented in an implicit rather than an explicit finite-element code, the continuum model requires significantly less computational power than the semi-discrete model and could therefore be used to more efficiently explore the mechanical response of engineering fabrics

Breakup of Pangaea and plate kinematics of the central Atlantic and Atlas regions

A new central Pangaea fit (type A) is proposed for the late Ladinian (230 Ma), together with a plate motions model for the subsequent phases of rifting, continental breakup and initial spreading in the central Atlantic. This model is based on: (1) a reinterpretation of the process of formation of the East Coast Magnetic Anomaly along the eastern margin of North America and the corresponding magnetic anomalies at the conjugate margins of northwest Africa and the Moroccan Meseta; (2) an analysis of major rifting events in the central Atlantic, Atlas and central Mediterranean and (3) a crustal balancing of the stretched margins of North America, Moroccan Meseta and northwest Africa. The process of fragmentation of central Pangaea can be described by three major phases spanning the time interval from the late Ladinian (230 Ma) to the Tithonian (147.7 Ma). During the first phase, from the late Ladinian (230 Ma) to the latest Rhaetian (200 Ma), rifting proceeded along the eastern margin of North America, the northwest African margin and theHigh, Saharan and Tunisian Atlas, determining the formation of a separate Moroccan microplate at the interface between Gondwana and Laurasia. During the second phase, from the latest Rhaetian (200 Ma) to the late Pliensbachian (185 Ma), oceanic crust started forming between the East Coast and Blake Spur magnetic anomalies, whereas the Morrocan Meseta simply continued to rift away from North America. During this time interval, the Atlas rift reached its maximum extent. Finally, the third phase, encompassing the time interval from the late Pliensbachian (185 Ma) to chron M21 (147.7 Ma), was triggered by the northward jump of the main plate boundary connecting the central Atlantic with the Tethys area. Therefore, as soon as rifting in the Atlas zone ceased, plate motion started along complex fault systems between Morocco and Iberia, whereas a rift/drift transition occurred in the northern segment of the central Atlantic, between Morocco and the conjugate margin of Nova Scotia. The inversion of the Atlas rift and the subsequent formation of the Atlas mountain belt occurred during the Oligocene–early Miocene time interval. In the central Atlantic, this event was associated with higher spreading rates of the ridge segments north of the Atlantis FZ. An estimate of 170 km of dextral offset of Morocco relative to northwest Africa, in the central Atlantic, is required by an analysis of marine magnetic anomalies. Five plate tectonic reconstructions and a computer animation are proposed to illustrate the late Triassic and Jurassic process of breakup of Pangaea in the central Atlantic and Atlas regions

Reconstructing blockages in a symmetric duct via quasi-isospectral horn operators

This paper proposes a new method for the reconstruction of the blockage area function in a symmetric duct by resonant frequencies under a given set of end conditions, i.e., open open or closed-closed ends. The analysis is based on the explicit determination of quasi-isospectral ducts, that is duct profiles which have the same spectrum as a given duct with the exception of a single eigenfrequency which is free to move in a prescribed interval. The analytical reconstruction was numerically implemented and tested for the detection of blockages. Numerical results show that the accuracy of identification increases with the number of eigenfrequencies used and that the reconstruction is rather stable with respect to the shape, the size and the position of the blockages

Self-writing as a tool for change: The effectiveness of a psychotherapy using diary

There is an abundance of literature investigating the relationship between self-writing and well-being in cases of trauma or life-changing events, but no such research has assessed the value of keeping a daily diary in promoting small changes, describing an individual's identity in its slow, but realistic evolution. This study examined how the use of diary as a narration tool contributed to improving a patient's awareness of his personal emotions and feelings during a course of psychotherapy. It investigated the changes occurring in the prevailing writing style of a 200-page diary written by a patient suffering from hypochondria over a period of two and a half years. Sentences relating to the need for change, to the self, to suffering and to the function attributed to the self-writing activity were analyzed on the basis of specific criteria deriving from dialogical self theory, which conceptualizes ways to adopt new identity positions during the course of change. Respondent validation identified a good correspondence between the findings of the textual analysis and the writer's own point of view. Results showed an improvement in awareness of moods and feelings. Identity positions became more integrated and writing more enjoyable. These findings demonstrate the potential of innovative use of diary writing as a longitudinal tool for consolidating strategies for change and as an additional means for assessing psychotherapy efficacy. Writing a diary proved effective both in supporting the patient's personal reflections and changes and in making it easier for him to share his thoughts with the therapist

On the whole spectrum of Timoshenko beams. Part I: a theoretical revisitation

The problem of free vibrations of the Timoshenko beam model is here addressed. A careful analysis of the governing equations allows identifying that the vibration spectrum consists of two parts, separated by a transition frequency, which, depending on the applied boundary conditions, might be itself part of the spectrum. For both parts of the spectrum, the values of natural frequencies are computed and the expressions of eigenmodes are provided. This allows to acknowledge that the nature of vibration modes changes when moving across the transition frequency. Among all possible combination of end constraints which can be applied to single-span beams, the case of a simply supported beam is considered. These theoretical results can be used as benchmarks for assessing the correctness of the numerical values provided by several numerical techniques, e.g. traditional Lagrangian-based finite element models or the newly developed isogeometric approach

Equilibria determination of elastic articulated duoskelion beams in 2D via a Riks-type algorithm

The overall behavior of an articulated beam structure constituted by elements arranged according to a specific chirality is studied. The structure as a whole, due to its slenderness and geometry, is called duoskelion beam. The name duoskelion is a neologism which is inspired by the Greek word δύοσκέλιον (two-legged). A discrete model for shearable beams, formulated recently, is exploited to investigate its mechanics. A purposely designed numerical scheme, adapting the Riks rationale, is used to calculate large displacement and deformation equilibria of duoskelion beams. Aimed at computing the current step correction, the Riks arc-length method is modified and made more efficient by applying a specific orthogonality condition, defined via the stiffness matrix, to an adapted extrapolation step. The robustness of the resulting scheme and its capability to follow equilibrium branches allows, in principle, for the exploration of the whole set of local energy minima in the introduced space of configurations, by using suitably modulated perturbative external loads. The developed numerical tool can be used to understand the mechanics of duoskelion beams. It is proved that there exists a stable principal equilibrium branch in which only compression is observed for any compression load. Additional stable equilibrium branches are found in compression such that the clamped–clamped compressed beam assumes a characteristic S shape which, upon reaching a critical load, is significantly amplified. A mechanically relevant stable equilibrium is also found in extension, being observed the S-shaped configuration experimentally found in Misra et al. (2020)

Isogeometric analysis of plane-curved beams

A curved beam element based on the Timoshenko model and non-uniform rational B-splines (NURBS) interpolation both for geometry and displacements is presented. Such an element can be used to suitably analyse plane-curved beams and arches. Some numerical results will explore the effectiveness and accuracy of this novel method by comparing its performance with those of some accurate finite elements proposed in the technical literature, and also with analytical solutions: for the cases where such closed-form solutions were not available in the literature, they have been computed by exact integration of the governing differential equations. It is shown that the presented element is almost insensitive to both membrane- and shear-locking, and that such phenomena can be easily controlled by properly choosing the number of elements or the NURBS degree

An analytical assessment of finite element and isogeometric analyses of the whole spectrum of Timoshenko beams

The theoretical results relevant to the vibration modes of Timoshenko beams are here used as benchmarks for assessing the correctness of the numerical values provided by several finite element models, based on either the traditional Lagrangian interpolation or on the recently developed isogeometric approach. Comparison of results is performed on both spectrum error (in terms of the detected natural frequencies) and on the l2 relative error (in terms of the computed eigenmodes): this double check allows detecting for each finite element model, and for a discretization based on the same number of degrees-of-freedom, N, the frequency threshold above which some prescribed accuracy level is lost, and results become more and more unreliable. Hence a quantitative way of measuring the finite element performance in modeling a Timoshenko beam is proposed. The use of Fast Fourier Transform is finally employed, for a selected set of vibration modes, to explain the reasons of the accuracy decay, mostly linked to a poor separation of the natural frequencies in the spectrum, which is responsible of some aliasing of modes

A nonlinear Lagrangian particle model for grains assemblies including grain relative rotations

International audienceWe formulate a discrete Lagrangian model for a set of interacting grains, which is purely elastic. The considered degrees of freedom for each grain include placement of barycenter and rotation. Further, we limit the study to the case of planar systems. A representative grain radius is introduced to express the deformation energy to be associated to relative displacements and rotations of interacting grains. We distinguish inter‐grains elongation/compression energy from inter‐grains shear and rotations energies, and we consider an exact finite kinematics in which grain rotations are independent of grain displacements. The equilibrium configurations of the grain assembly are calculated by minimization of deformation energy for selected imposed displacements and rotations at the boundaries. Behaviours of grain assemblies arranged in regular patterns, without and with defects, and similar mechanical properties are simulated. The values of shear, rotation, and compression elastic moduli are varied to investigate the shapes and thicknesses of the layers where deformation energy, relative displacement, and rotations are concentrated. It is found that these concentration bands are close to the boundaries and in correspondence of grain voids. The obtained results question the possibility of introducing a first gradient continuum models for granular media and justify the development of both numerical and theoretical methods for including frictional, plasticity, and damage phenomena in the proposed model