The Effect of Inkjet Ink Composition on Rheology And Jetting Behaviour

This work presents recent results on the way linear and non linear viscoelastic properties of the fluids affect the jetting mechanism. Recent progress on quantitative characterising both high frequency linear (LVE) and non-linear (NLVE) viscoelasticity of fluids allows fluids to be assessed for their jettability before using such materials in a DoD print head. In term of linear viscoelastic measurements, the Piezo Axial Vibrator (PAV) was used to probe the rheology of the fluids on a frequency range between 10Hz and 10000Hz. A filament stretching apparatus, called the “Cambridge Trimaster”, was used in combination with high speed cinematography, to characterize the fluids high speed stretching and break-up behaviour. The series of fluids investigated here consist in dilutions of mono disperse polystyrene with different molecular weight (110, 210, 306 and 488 kg/mol respectively) diluted in diethyl phthalate. The choice of polymer weights and concentrations were chosen to match both the complex viscosity and the LVE. However, non linear rheological data experiments exhibit differences in the fluid relaxation time and filament break-up mechanism. Ultra-high speed cinematography of DoD jetting events were correlated with filament break-up experiments and demonstrated that fluid rheology provides valuable information on the jetting quality of the fluids

Role of ultrasound in early pregnancy in differentiating normal and abnormal pregnancies

ABSTRACT A prospective study was carried out from November 2006 -December 2008 in which a total of 304 patients with early pregnancy were examined by ultrasound (US). Of these, 203 (66.8%) cases were normal pregnancies (including 8 cases of twin pregnancy), 32 (10.5%) missed abortions, 19 (6.3%) incomplete abortions, 14 (4.6%) complete abortions, 12 (4.0%) blighted ovums, 11 (3.6%) without sonographic evidence of pregnancy, 7 (2.3%) ectopic pregnancies and 6 (1.9%) molar pregnancies. US in early pregnancy gave a reliable and accurate differentiation between a viable normal pregnancy and an abnormal/ pathological pregnancy

De-aluminated metakaolin-cement composite modified with commercial titania as a new green building material for gamma-ray shielding applications

Sustainable disposal of dealuminated metakaolin (DAK) is a crucial environmental issue for the alum production industry. In previous studies, DAK was utilized as eco-friendly cementitious materials, but only 10 wt% was used instead of cement as DAK's high percentage has a detri-mental effect on the mechanical properties, so the environmental problem of DAK has not yet been solved. In this study, commercial titanium oxide (TiO2) was incorporated in a cement matrix containing DAK that reached 50 wt% to benefit from TiO2's properties in enhancing the me-chanical performance of binding materials and producing cementitious blends used as blocking materials against harmful gamma radiation. Five pastes were prepared to reach the main target; ordinary Portland cement (OPC), OPC-10%DAK (D10), OPC-30%DAK (D30), OPC-50%DAK (D50) and OPC-45%DAK-5%TiO2 (D45-T5). By means of a mini-slump test, all fresh blends have very close flowability using the appreciated additions of polycarboxylate superplasticizer. The hardened composites were cured in tap water for up to 28-days. Compressive strength results at 28 days for OPC, D10, D30 and D50 were 80, 94.6, 60.8 and 57.6 MPa, respectively. An obvious turning point in strength value from 57.6 to 88 MPa after replacement of DAK by 5 wt% TiO2 (D45-T5). A gamma-ray shielding test was performed using two radioactive isotopes (Co-60 and Cs-137). The inclusion of 5% TiO2 has a great impact on the development of shielding power of D45-T5 compared with OPC; the linear attenuation coefficient (mu) values were enhanced from 0.127 +/- 0.003 cm(-1) to 0.199 +/- 0.007 cm(-1) at 661.6 Kev and from 0.118 +/- 0.003 cm(-1) to 0.144 +/- 0.005 cm(-1) at 1332.5 Kev. The unique properties of specimens containing the anatase phase may be attributed to the fact that the TiO2 may act as a nano-filler and active seeds for the formation of further hydration products such as CSHs, CAHs and CASHs as detected by X-ray diffraction (XRD), thermal analyses techniques (TGA/DSC) and scanning electron microscope (SEM/EDX). TiO2 caused rearrangement of the textural structure of D45-T5 composite to meso pores, as proved by N-2-adsorption/desorption technique. Moreover, the TiO2's tetragonal struc-ture makes it has dosimetric characteristics of high adsorbent for gamma rays

Progressive Collapse Resistance of RC Beam–Slab Substructures Made with Rubberized Concrete

Abnormal loads can produce localized damage that can eventually cause progressive collapse of the whole reinforced concrete (RC) structure. This might have devastating financial repercussions and cause numerous severe casualties. Numerical simulation, using the finite element method (FEM), of the consequences of abnormal loads on buildings is thus required to avoid the significant expenses associated with testing full-scale buildings and to save time. In this paper, FEM simulations, using ABAQUS software, were employed to investigate the progressive collapse resistance of the full-scale three-dimensional (3D) beam–slab substructures, considering two concrete mixes, namely: normal concrete (NC) and rubberized concrete (RuC) which was made by incorporating crumb rubber at 20% by volume replacement for sand. The FEM accuracy and dependability were validated using available experimental test results. Concrete and steel material non-linearity were considered in the FE modelling. The numerical study is extended to include eight new models with various specifics (a set of parameters) for further understanding of progressive collapse. Results showed that slabs contribute more than a third of the load resistance, which also significantly improves the building’s progressive collapse resistance. Moreover, the performance of the RuC specimens was excellent in the catenary stage, which develops additional resilience to significant deformation to prevent or even mitigate progressive collapse

Effect of Systematically Tuning Conjugated Donor Polymer Lowest Unoccupied Molecular Orbital Levels via Cyano Substitution on Organic Photovoltaic Device Performance

We report a systematic study into the effects of cyano substitution on the electron accepting ability of the common acceptor 4,7-bis(thiophen-2-yl)-2,1,3-benzothiadiazole (DTBT). We describe the synthesis of DTBT monomers with either 0, 1, or 2 cyano groups on the BT unit and their corresponding copolymers with the electron rich donor dithienogermole (DTG). The presence of the cyano group is found to have a strong influence on the optoelectronic properties of the resulting donor–acceptor polymers, with the optical band gap red-shifting by approximately 0.15 eV per cyano substituent. We find that the polymer electron affinity is significantly increased by ∼0.25 eV upon addition of each cyano group, while the ionization potential is less strongly affected, increasing by less than 0.1 eV per cyano substituent. In organic photovoltaic (OPV) devices power conversion efficiencies (PCE) are almost doubled from around 3.5% for the unsubstituted BT polymer to over 6.5% for the monocyano substituted BT polymer. However, the PCE drops to less than 1% for the dicyano substituted BT polymer. These differences are mainly related to differences in the photocurrent, which varies by 1 order of magnitude between the best (1CN) and worst devices (2CN). The origin of this variation in the photocurrent was investigated by studying the charge generation properties of the photoactive polymer–fullerene blends using fluorescence and transient absorption spectroscopic techniques. These measurements revealed that the improved photocurrent of 1CN in comparison to 0CN was due to improved light harvesting properties while maintaining a high exciton dissociation yield. The addition of one cyano group to the BT unit optimized the position of the polymer LUMO level closer to that of the electron acceptor PC71BM, such that the polymer’s light harvesting properties were improved without sacrificing either the exciton dissociation yield or device VOC. We also identify that the drop in performance for the 2CN polymer is caused by very limited yields of electron transfer from the polymer to the fullerene, likely caused by poor orbital energy level alignment with the fullerene acceptor (PC71BM). This work highlights the impact that small changes in chemical structure can have on the optoelectronic and device properties of semiconducting polymer. In particular this work highlights the effect of LUMO–LUMO offset on the excited state dynamics of polymer–fullerene blends

European Stroke Organisation (ESO) guideline on screening for subclinical atrial fibrillation after stroke or transient ischaemic attack of undetermined origin

We aimed to provide practical recommendations for the screening of subclinical atrial fibrillation (AF) in patients with ischaemic stroke or transient ischaemic attack (TIA) of undetermined origin. These guidelines are based on the Grading of Recommendations, Assessment, Development and Evaluation (GRADE) methodology. Five relevant Population, Intervention, Comparator, Outcome questions were defined by a multidisciplinary module working group (MWG). Longer duration of cardiac rhythm monitoring increases the detection of subclinical AF, but the optimal monitoring length is yet to be defined. We advise longer monitoring to increase the rate of anticoagulation, but whether longer monitoring improves clinical outcomes needs to be addressed. AF detection does not differ from in- or out-patient ECG-monitoring with similar monitoring duration, so we consider it reasonable to initiate in-hospital monitoring as soon as possible and continue with outpatient monitoring for more than 48 h. Although insertable loop recorders (ILR) increase AF detection based on their longer monitoring duration, comparison with non-implantable ECG devices for similar monitoring time is lacking. We suggest the use of implantable devices, if feasible, for AF detection instead of non-implantable devices to increase the detection of subclinical AF. There is weak evidence of a useful role for blood, ECG and brain imaging biomarkers for the identification of patients at high risk of AF. In patients with patent foramen ovale, we found insufficient evidence from RCT, but prolonged cardiac monitoring in patients >55 years is advisable for subclinical AF detection. To conclude, in adult patients with ischaemic stroke or TIA of undetermined origin, we recommend longer duration of cardiac rhythm monitoring of more than 48 h and if feasible with IRL to increase the detection of subclinical AF

Potential Use of Rendering Mortar Waste Powder as a Cement Replacement Material: Fresh, Mechanical, Durability and Microstructural Properties

The difficulty of decomposing solid waste over time has made it a significant global problem because of its environmental impact and the need for large areas for disposal. Among these residues is the waste of the rendering mortar that is produced (falls to the ground) while applied to wall surfaces. The quantity of these materials may reach 200 to 500 g/m2. As a result of local urban development (in Iraq), thousands of tons of these wastes are produced annually. On the other hand, the emission of greenhouse gases in the cement industry has had a great environmental impact. One of the solutions to this problem is to reduce the cement content in the mix by replacing it with less emissive materials. Residues from other industries are considered a relatively ideal option due to their disposal on the one hand and the reduction of harmful emissions of the cement industry on the other hand. Therefore, this research aims to reuse rendering mortar waste powder (RMWP) as a possible alternative to cement in mortar. RMWP replaced the cement in proportions (0, 10, 15, 20, 25, and 30% by weight). The flow rate, flexural and compressive strengths, ultrasonic pulse velocity, bulk density, dynamic modulus of elasticity, electrical resistivity, and water absorption tests of the produced mortar were executed. Microstructural analysis of the produced mortar was also investigated. Results indicated that, for sustainable development, an eco-friendly mortar can be made by replacing cement with RMWP at a rate of 15%, resulting in a 17% decrease in compressive strength while maintaining or improving durability properties. Moreover, the microstructure became denser and more homogeneous in the presence of RMWP

New ternary blend strategy based on a vertically self-assembled passivation layer enabling efficient and photostable inverted organic solar cells

Herein, a new ternary strategy to fabricate efficient and photostable inverted organic photovoltaics (OPVs) is introduced by combining a bulk heterojunction (BHJ) blend and a fullerene self-assembled monolayer (C60 -SAM). Time-of-flight secondary-ion mass spectrometry - analysis reveals that the ternary blend is vertically phase separated with the C60 -SAM at the bottom and the BHJ on top. The average power conversion efficiency - of OPVs based on the ternary system is improved from 14.9% to 15.6% by C60 -SAM addition, mostly due to increased current density (Jsc ) and fill factor -. It is found that the C60 -SAM encourages the BHJ to make more face-on molecular orientation because grazing incidence wide-angle X-ray scattering - data show an increased face-on/edge-on orientation ratio in the ternary blend. Light-intensity dependent Jsc data and charge carrier lifetime analysis indicate suppressed bimolecular recombination and a longer charge carrier lifetime in the ternary system, resulting in the enhancement of OPV performance. Moreover, it is demonstrated that device photostability in the ternary blend is enhanced due to the vertically self-assembled C60 -SAM that successfully passivates the ZnO surface and protects BHJ layer from the UV-induced photocatalytic reactions of the ZnO. These results suggest a new perspective to improve both performance and photostability of OPVs using a facial ternary method