Non-uniform carrier density in Cd3_3As2_2 evidenced by optical spectroscopy

We report the detailed optical properties of Cd$_3$As$_2$ crystals in a wide parameter space: temperature, magnetic field, carrier concentration and crystal orientation. We investigate high-quality crystals synthesized by three different techniques. In all the studied samples, independently of how they were prepared and how they were treated before the optical experiments, our data indicate conspicuous fluctuations in the carrier density (up to 30%). These charge puddles have a characteristic scale of 100 $\mu$m, they become more pronounced at low temperatures, and possibly, they become enhanced by the presence of crystal twinning. The Drude response is characterized by very small scattering rates ($\sim 1$ meV) for as-grown samples. Mechanical treatment, such as cutting or polishing, influences the optical properties of single crystals, by increasing the Drude scattering rate and also modifying the high frequency optical response. Magneto-reflectivity and Kerr rotation are consistent with electron-like charge carriers and a spatially non-uniform carrier density.Comment: Accepted in Physical Review

2 Aminoadipic Acid C O Glutamate Based Prostate Specific Membrane Antigen Ligands for Potential Use as Theranostics

The design and synthesis of prostate specific membrane antigen (PSMA) ligands derived from 2-aminoadipic acid, a building block that has not previously been used to construct PSMA ligands, are reported. The effects of both the linker length and of an N-substituent of our PSMA ligands were probed, and X-ray structures of five of these ligands bound to PSMA were obtained. Among the ligands disclosed herein, 13b showed the highest inhibitory activity for PSMA. As ligand 13b can readily be radiolabeled since its fluorine atom is adjacent to the nitrogen atom of its pyridine ring, the use of this and related compounds as theranostics can be pursued

Anatomy and paleofluid evolution of laterally restricted extensional fault zones in the Jabal Qusaybah anticline, Salakh arch, Oman

© 2016 Geological Society of America. The E-W-trending Jabal Qusaybah anticline, at the western termination of the Salakh arch, Oman Mountains, is characterized by a complex fault network that developed in layered Cretaceous carbonates. This network includes NE-SW left-lateral, N-S extensional, and subordinate E-W extensional fault zones. The N-S-striking extensional faults zones are roughly perpendicular to the fold axis and are best developed in the longitudinally bulged central sector of the anticlinal crest. They are likely due to along-strike outer-arc extension associated with positive fault inversion and salt migration. These extensional fault zones are confined within, and locally abut, major NE-SW left-lateral strike-slip fault zones. Extensional fault displacements range between a few decimeters and ~60 m, whereas the maximum exposed trace lengths range between a few meters and ~800 m. Narrow (~1-15-cm-thick) cataclastic fault cores are surrounded by vein-dominated damage zones as thick as tens of meters. Moreover, fault zones show widespread evidence for substantial dilation in the form of (1) dilation breccias, (2) infilling by large columnar calcite crystals and aggregates, and (3) centimeter- to meter-thick veins. Dilation breccias and calcite infillings are primarily localized at fault tips, fault overlaps, and interaction zones between strike-slip and extensional fault segments. Displacement profiles along the N-S-striking extensional fault zones indicate that they are one order of magnitude shorter than values predicted by most published displacement-length scaling laws. By analyzing fault abutting geometries, detailed vein relative chronology, d13C and d18O signatures, and fluid inclusion data from calcite veins and calcite fault infillings, we propose a model whereby a deep-seated, regionally sized, left-lateral strike-slip fault system that was active during anticline growth inhibited the lateral propagation of late-stage transversal extensional fault zones. Our findings show that, in this geological setting, the structural position, rather than fault displacement, is the parameter controlling the location of the more dilatants (and permeable) fault segments. Results of the present work suggest that fault intersections may be more useful than fault throw for predicting zones of enhanced vertical fluid flow in structurally complex carbonate reservoirs.status: publishe