Non-uniform carrier density in Cd3_3As2_2 evidenced by optical spectroscopy

We report the detailed optical properties of Cd$_3$As$_2$ crystals in a wide parameter space: temperature, magnetic field, carrier concentration and crystal orientation. We investigate high-quality crystals synthesized by three different techniques. In all the studied samples, independently of how they were prepared and how they were treated before the optical experiments, our data indicate conspicuous fluctuations in the carrier density (up to 30%). These charge puddles have a characteristic scale of 100 $\mu$m, they become more pronounced at low temperatures, and possibly, they become enhanced by the presence of crystal twinning. The Drude response is characterized by very small scattering rates ($\sim 1$ meV) for as-grown samples. Mechanical treatment, such as cutting or polishing, influences the optical properties of single crystals, by increasing the Drude scattering rate and also modifying the high frequency optical response. Magneto-reflectivity and Kerr rotation are consistent with electron-like charge carriers and a spatially non-uniform carrier density.Comment: Accepted in Physical Review

2 Aminoadipic Acid C O Glutamate Based Prostate Specific Membrane Antigen Ligands for Potential Use as Theranostics

The design and synthesis of prostate specific membrane antigen (PSMA) ligands derived from 2-aminoadipic acid, a building block that has not previously been used to construct PSMA ligands, are reported. The effects of both the linker length and of an N-substituent of our PSMA ligands were probed, and X-ray structures of five of these ligands bound to PSMA were obtained. Among the ligands disclosed herein, 13b showed the highest inhibitory activity for PSMA. As ligand 13b can readily be radiolabeled since its fluorine atom is adjacent to the nitrogen atom of its pyridine ring, the use of this and related compounds as theranostics can be pursued

Anatomy and paleofluid evolution of laterally restricted extensional fault zones in the Jabal Qusaybah anticline, Salakh arch, Oman

© 2016 Geological Society of America. The E-W-trending Jabal Qusaybah anticline, at the western termination of the Salakh arch, Oman Mountains, is characterized by a complex fault network that developed in layered Cretaceous carbonates. This network includes NE-SW left-lateral, N-S extensional, and subordinate E-W extensional fault zones. The N-S-striking extensional faults zones are roughly perpendicular to the fold axis and are best developed in the longitudinally bulged central sector of the anticlinal crest. They are likely due to along-strike outer-arc extension associated with positive fault inversion and salt migration. These extensional fault zones are confined within, and locally abut, major NE-SW left-lateral strike-slip fault zones. Extensional fault displacements range between a few decimeters and ~60 m, whereas the maximum exposed trace lengths range between a few meters and ~800 m. Narrow (~1-15-cm-thick) cataclastic fault cores are surrounded by vein-dominated damage zones as thick as tens of meters. Moreover, fault zones show widespread evidence for substantial dilation in the form of (1) dilation breccias, (2) infilling by large columnar calcite crystals and aggregates, and (3) centimeter- to meter-thick veins. Dilation breccias and calcite infillings are primarily localized at fault tips, fault overlaps, and interaction zones between strike-slip and extensional fault segments. Displacement profiles along the N-S-striking extensional fault zones indicate that they are one order of magnitude shorter than values predicted by most published displacement-length scaling laws. By analyzing fault abutting geometries, detailed vein relative chronology, d13C and d18O signatures, and fluid inclusion data from calcite veins and calcite fault infillings, we propose a model whereby a deep-seated, regionally sized, left-lateral strike-slip fault system that was active during anticline growth inhibited the lateral propagation of late-stage transversal extensional fault zones. Our findings show that, in this geological setting, the structural position, rather than fault displacement, is the parameter controlling the location of the more dilatants (and permeable) fault segments. Results of the present work suggest that fault intersections may be more useful than fault throw for predicting zones of enhanced vertical fluid flow in structurally complex carbonate reservoirs.status: publishe

Photogrammetric digital outcrop reconstruction, visualization with textured surfaces, and three-dimensional structural analysis and modeling: Innovative methodologies applied to fault-related dolomitization (Vajont Limestone, Southern Alps, Italy)

© 2016 Geological Society of America. Different remote sensing technologies, including photogrammetry and LIDAR (light detection and ranging), allow collecting three-dimensional (3D) data sets that can be used to create 3D digital representations of outcrop surfaces, called digital outcrop models (DOM). The main advantages of photogrammetry over LIDAR are represented by the very simple and lightweight field equipment (a digital camera), and by the arbitrary spatial resolution, that can be increased simply getting closer to the outcrop or by using a different lens. The quality of photogrammetric data sets obtained with structure from motion (SFM) techniques has shown a tremendous improvement over the past few years, and this is becoming one of the more effective ways to collect DOM data sets. The Vajont Gorge (Belluno Dolomites, Italy) provides spectacular outcrops of jurassic limestones (Vajont Limestone Formation) in which mesozoic faults and fracture corridors are continuously exposed. Some of these faults acted as conduits for fluids, resulting in structurally controlled dolomitization. A 3D DOM study, based on a photogrammetric SFM data set, was carried out, aimed at enabling interdisciplinary characterization and reconstruction of coupled brittle deformation and fluid flow processes. For this study we used a DOM (730 m × 360 m × 270 m) consisting of continuous triangulated surfaces representing the outcrop, textured with highresolution images. Interpretation and modeling performed on this data set include (1) georeferencing of structural measurements and sampling stations; (2) tracing of stratigraphic boundaries, structural surfaces, and dolomitization fronts (ground-truthed); (3) correlation and extrapolation of realistic 3D surfaces from these traces; and (4) development of a 3D geological model at the scale of the Vajont Gorge, including stratigraphy, faults, dolomitization fronts, and volumetric meshes suitable for the statistical analysis of structural, diagenetic, and geochemical parameters. The DOM study highlighted the close relationship between faults and dolostone geobodies, demonstrating that dolomitization was guided by fluid infiltration along Mesozoic normal faults. In order to explore the uncertainty associated with the 3D model of irregularly shaped dolostone bodies, three different 3D dolostone geobody realizations have been modeled, providing a minimum, intermediate, and maximum estimate of the dolostone/limestone volumetric facies ratio, while honoring the field constraints.status: publishe