Development of potassium ion conducting hollow glass fibers

Potassium ion conducting glasses, chemically resistant to potassium, potassium sulfide and sulfur, were made and their possible utility as the membrane material for a potassium/sulfur battery was evaluated. At least one satisfactory candidate was found. It possesses an electrical resistance which makes it usable as a membrane in the form of a fine hollow fiber. It's chemical and electrochemical resistances are excellent. The other aspects of the possible potassium sulfur battery utilizing such fine hollow fibers, including the header (or tube sheet) and a cathode current collector were studied. Several cathode materials were found to be satisfactory. None of the tube sheet materials studied possessed all the desired properties. Multi-fiber cells had very limited life-time due to physical failure of fibers at the fiber/tube sheet junctions

The development of a potassium-sulfide glass fiber cell and studies on impurities in alkali metal-sulfur cells

Potassium sulfur rechargeable cells, having as the electrolyte the thin walls of hollow glass fibers made from permeable glass, were developed. The cells had short lives, probably due to the construction materials and impurities in the potassium. The effect of the impurities in the analogous NA-S system was studied. Calcium, potassium, and NaOH/oxide impurities caused increased resistance or corrosion of the glass fibers. For long lived cell operation, the Na must contain less than 1 ppm Ca and less than a few ppm of hydroxide/oxide. Up to 150 ppm K can be tolerated. After purification of the Na anolyte, cell lifetimes in excess of 1000 deep charge-discharge cycles or over 8 months on continuous cycling at 10-30 percent depth of discharge were obtained

Illustrating Electric Conductivity Using the Particle-in-a-Box Model: Quantum Superposition is the Key

Most of the textbooks explaining electric conductivity in the context of quantum mechanics provide either incomplete or semi-classical explanations that are not connected with the elementary concepts of quantum mechanics. We illustrate the conduction phenomena using the simplest model system in quantum dynamics, a particle in a box (PIB). To induce the particle dynamics, a linear potential tilting the bottom of the box is introduced, which is equivalent to imposing a constant electric field for a charged particle. Although the PIB model represents a closed system that cannot have a flow of electrons through the system, we consider the oscillatory dynamics of the particle probability density as the analogue of the electric current. Relating the amplitude and other parameters of the particle oscillatory dynamics with the gap between the ground and excited states of the PIB model allows us to demonstrate one of the most basic dependencies of electric conductivity on the valence-conduction band gap of the material

Coupling and higher-order effects in the 12C(d,p)13C and 13C(p,d)12C reactions

Coupled channels calculations are performed for the 12C(d,p)13C and 13C(p,d)12C reactions between 7 and 60 MeV to study the effect of inelastic couplings in transfer reactions. The effect of treating transfer beyond Born approximation is also addressed. The coupling to the 12C 2+ state is found to change the peak cross-section by up to 15 %. Effects beyond Born approximation lead to a significant renormalization of the cross-sections, between 5 and 10 % for deuteron energies above 10 MeV, and larger than 10 % for lower energies. We also performed calculations including the remnant term in the transfer operator, which has a small impact on the 12C(d,p)13C(g.s.) and 13C(p,d)12C(g.s.) reactions. Above 30 MeV deuteron energy, the effect of the remnant term is larger than 10 % for the 12C(d,p)13C(3.09 MeV) reaction and is found to increase with decreasing neutron separation energy for the 3.09 MeV state of 13C. This is of importance for transfer reactions with weakly bound nuclei.Comment: 7 pages, 7 figures, submitted to Phys. Rev.

A new approach to upscaling fracture network models while preserving geostatistical and geomechanical characteristics

A new approach to upscaling two-dimensional fracture network models is proposed for preserving geostatistical and geomechanical characteristics of a smaller-scale “source” fracture pattern. First, the scaling properties of an outcrop system are examined in terms of spatial organization, lengths, connectivity, and normal/shear displacements using fractal geometry and power law relations. The fracture pattern is observed to be nonfractal with the fractal dimension D ≈ 2, while its length distribution tends to follow a power law with the exponent 2 < a < 3. To introduce a realistic distribution of fracture aperture and shear displacement, a geomechanical model using the combined finite-discrete element method captures the response of a fractured rock sample with a domain size L = 2 m under in situ stresses. Next, a novel scheme accommodating discrete-time random walks in recursive self-referencing lattices is developed to nucleate and propagate fractures together with their stress- and scale-dependent attributes into larger domains of up to 54 m × 54 m. The advantages of this approach include preserving the nonplanarity of natural cracks, capturing the existence of long fractures, retaining the realism of variable apertures, and respecting the stress dependency of displacement-length correlations. Hydraulic behavior of multiscale growth realizations is modeled by single-phase flow simulation, where distinct permeability scaling trends are observed for different geomechanical scenarios. A transition zone is identified where flow structure shifts from extremely channeled to distributed as the network scale increases. The results of this paper have implications for upscaling network characteristics for reservoir simulation

Towards weak sustainability in the formal curricula: a case study of research-driven pedagogical reform in Hong Kong

Presentation 3International organizations such as UNESCO have long recognized the important role of education in helping to achieve the goals of sustainability/sustainable development. The launch of the Decade of Education of Sustainable Development (2005-2014) is a strong indication of UNESCO’s commitment to promoting the Education for Sustainable Development. Curiously “Education for Sustainability” has been used interchangeably with “Education for Sustainable Development” by many organizations, even though there are subtle but significant differences between the two phrases. The teaching and learning of both concepts involve capacity-building and life-style changes and, as such, they are different from the conventional type of environmental education that concentrates on problem-solving …published_or_final_versio

Translating Literary Ideology from Ancient Chinese into Modern French: François Cheng’s Francophone Poetry in \u3cem\u3eDouble chant\u3c/em\u3e (2000)

François Cheng (1929- ), elected to the Académie Française in 2002, structurally introduced the lexicological, syntactic, and semiotic form of Tang poetry to the French academia via his academic works. In the late 1980s, François Cheng shifted his focus from academic writing to creative writing, both in French, winning the 1998 Prix Femina for his novel Le Dit de Tianyi (1998) and Prix Roger Caillois for his collection of poems Double chant (2000). Focusing on his less-discussed poetry, which reveals higher congruity of his understanding of Chinese literary classics with creative representation, this paper argues that, as an analyst of Tang poetry, Cheng also acts as a contemporary translator of the classical Chinese aesthetic ideology into French modern verses. His subjective creation of poetry is both transcultural and trans-temporal, ambiguously corresponding to his lingual, racial, cultural, and national belonging, and appropriating a new valid form of French literary style. This ambiguity both transcends national identification and universalizes the international flow of knowledge. Beyond Feng Lan\u27s (2017) recognition of François Cheng as a special representative of Chinese diasporic intellectuals who mediate between institutionalized French discourses and Chinese classical philosophy, a close reading of Cheng’s poems in the paper will support an investigation of his successive and transformative production of text