Corrosion protection of carbon steel by an epoxy resin containing organically modified clay

This study focusses on the use of montmorillonite clay (MMT) treated with an organic compound (aminotrimethylphosphonic acid (ATMP)) and dispersed in an epoxy resin to improve corrosion protection of carbon steel. X-ray diffraction was performed to verify that the individual silicate layers were separated and dispersed in the epoxy resin. Corrosion resistance of the coated steel was evaluated by electrochemical impedance spectroscopy (EIS) and local electrochemical impedance spectroscopy (LEIS). Three systems were tested: the epoxy clear-coat, the epoxy resin containing 2 wt.% clay and the epoxy resin containing 2 wt.% clay modified byATMP (ATMP-modified clay). From conventional EIS, it was shown that the incorporation of clay or ATMP-modified clay in the epoxy matrix significantly improved the barrier properties of the coating. The corrosion resistance of the carbon steel coated by the epoxy resin containing ATMP-modified clay was higher than that obtained for the system containing non-treated clay. Local electrochemical measurements performed on scratched samples revealed the inhibitive role of ATMP at the carbon steel/coating interface

HIGH PROTECTION PERFORMANCE OF COATING SYSTEMS BASED ON ZINC RICH PRIMER AND FLUOROPOLYMER COATING

Coating systems based on zinc rich primer and fluoropolymer top coat were exposed for 8 years at different atmospheric stations in Vietnam: Hanoi, Ha Long and Nha Trang. For comparison the coating system with zinc rich primer and polyurethane topcoat was also tested. The degradations of coating systems were evaluated by gloss measurement and electrochemical impedance spectroscopy. The obtained results show that coating systems with zinc rich primer and top coatings based on fluoropolymer  and polyurethane topcoats show very high weather resistance and corrosion protection performance, but the systems with fluoropolymer are better than coating system with polyurethane topcoat

Incorporation of an indole-3 butyric acid modified clay in epoxy resin for corrosion protection of carbon steel

In the present work, indole-3 butyric acid (IBA) was inserted between montmorillonite clay platelets by cation exchange. The clay treated with the organic compound (IBA-modified clay) was then dispersed in an epoxy resin at a low concentration (2 wt.%). IBA was chosen to act both as an inhibitor and an adherence promoter. The effect of the IBA-modified clay on the microstructure and on the protective properties of the epoxy coating deposited on carbon steel was evaluated by a thermostimulated-current (TSC) method and by electrochemical impedance spectroscopy (EIS). The TSC measurements showed the specific action of IBA-modified clay which decreased the molecular mobility of the polymer chain by comparison with the pure epoxy. Impedance measurements corroborated the role of the modified clay on the barrier properties of the coating which remained high as a function of exposure time in a 0.5 M NaCl solution. The corrosion resistance of the carbon steel coated with the epoxy resin containing IBA-modified clay was significantly higher than that obtained with the clear coat. Polarization curves plotted in the presence of an artificial defect demonstrated the inhibitive role of IBA at the carbon steel/coating interface. The good adherence of the coating was seen during salt spray test

Torsion of Ileum Due To Giant Meckel's Diverticulum – A Case Report

Background: Meckel’s diverticulum (MD) is detected in approximately 2% of all individuals and only 2-4% MD patients may develop symptoms. Small intestinal obstruction is a frequent complication in adults. Case report: A 48-year-old male was admitted to emergency department for high intestinal obstruction symptoms. The imaging examinations were failed to detect the underlying causes. A median laparotomy revealed small bowel obstruction (SBO) due to a segment of ileum twisted around a giant MD axis. Conclusion: Thus, a giant MD generating torsion of ileum is an unusual complication. Preoperative diagnosis is challenging. Emergency surgery is preferred to make an accurate diagnosis and for treatment.    &nbsp

PSSA- INTERNATIONAL SOLUTION TO PROTECT THE BIODIVERSITY IN HA LONG BAY - CAT BA MARINE AREA

A Particularly Sensitive Sea Area (PSSA) is an important management tool for biodiversity protection of a marine area. At the time of designation of a Particularly Sensitive Sea Area, an associated protective measure, which meets the requirements of the appropriate legal instrument establishing such measure, must have been approved or adopted by IMO to prevent, reduce, or eliminate the threat or identified vulnerability. Information on each of the Particularly Sensitive Sea Areas (PSSAs) that has been designated by IMO is available on the nautical chart. The Vietnam’s coastal zones and islands are the isolated oceanic habitat of extremely rich marine life in very good condition which is important to the maintenance and dispersal of the marine life of the western tropical Pacific. Vietnam coastal areas are very high risk areas affected by maritime activities, particularly international shipping, therefore in the future identification of some Particularly Sensitive Sea Areas (PSSAs) is necessary. The first Particularly Sensitive Sea Area for Vietnam in Ha Long - Cat Ba was initially proposed in this paper

The influence of brand equity on consumer responses toward Cho Gao dragon fruits brand

This thesis study wants to implement a model test for better understandings of brand equity and consumer responses toward Cho Gao Dragon Fruit brand. With the rapid growth of agriculture, including domestic consumption and export of the dragon fruits, it is crucial to differentiate the Cho Gao Dragon Fruits to other competitors in both domestic and foreign markets. Using Structural equation modeling (SEM) to analyze the data of 274 questionnaires to investigate the effects of brand equity and its dimensions on consumer responses. The results show that brand equity dimensions such as brand awareness, brand association, perceived quality are interrelated and those dimensions have a direct and significant effect on brand equity, except brand awareness. The results support the assumption that brand equity has a positive relationship with consumer responses. The findings shed light on the current issues of the market for dragon fruits, which enables us to provide some suggestions for the Government to facilitate farmers and traders in building brand names, marketers for doing marketing activities, and students to know about brand equity of agricultural product such as dragon fruits

An investment plan for low-emission rice production in the Mekong River Delta region in support of Vietnam's Nationally Determined Contribution to the Paris Agreement

Rice production is integral to agriculture and food security in Vietnam, but it also contributes greenhouse gas emissions. In 2010, paddy rice production emitted 44.61 million tons carbon dioxide equivalents (MtCO2e), 18% of total national GHG emissions. A variety of options to mitigate GHG emissions from paddy rice show promise and will contribute to implementing Vietnam’s Nationally Determined Contribution (NDC) and green growth strategies. One of the most promising options is alternate wetting and drying (AWD), a technique in which fields are allowed to dry out to a certain point before irrigation instances. This paper focuses on the Mekong River Delta region, which produces more than 50% of total rice production and 95% of rice exported from Vietnam. This study employs a literature review, a study of promising GHG mitigation options, and an analysis of cost and benefits of AWD to develop an investment plan for AWD in the Mekong River Delta. In our field survey, we found AWD contributed to increasing farmers’ net incomes primarily by decreasing production costs. The study proposes an investment plan with four outputs and 15 investment activities with a goal of practicing AWD on 900,000 hectares in the Mekong River Delta and mitigating 10.97 M.tCO2e. A co-benefit is additional net income for farmers of 8,540 billion VND (USD 371.36 million) per year compared to conventional rice cultivation. The budget is USD 721.78 million (81.32% for hard infrastructure, 18.19% for MRV operation, research, performance and planning), of which 36.9% is provided by the state, 29.92% from local provinces, 21.77% from international support and 11.42% from the private sector. Mobilization of financial resources from public and private sectors and the integration into government plans and programs are recommended

8-hydroxyquinoline-modified clay incorporated in an epoxy coating for the corrosion protection of carbon steel

In the present work, a well-known corrosion inhibitor (8-hydroxyquinoline (8HQ)) was inserted within the montmorillonite platelets (8HQ-MMT) and the modified clay was incorporated (3 wt.%) into a solvent-free epoxy coating which was afterwards deposited on carbon steel substrates. First, the inhibitive action of 8HQ was investigated by electrochemical methods carried out on a bare carbon steel rotating disk electrode in a 0.1 M NaCl solution. Then, electrochemical impedance measurements were performed to assess the effect of the 8HQ-MMT in the epoxy coating for the corrosion protection. The results were compared with a reference sample constituted by the epoxy coating containing an ammonium quaternary salt-modified clay. It was shown that the two coatings presented good barrier properties. Dry and wet adherence measurements revealed an improvement of the adherence when the 8HQ-MMT was incorporated into the coating by comparison with the reference sample. It was concluded that the 8HQ mainly had an effect at the metal/coating interface but its concentration was too low to afford significant corrosion protection of the carbon steel

Anatomical Characteristics and Variants of Prostatic Artery in Patients of Benign Hyperplasia Prostate by Digital Subtraction Angiography

AIM: This work is aimed to describe anatomical features and variants of the prostatic artery (PA) using digital subtraction angiography (DSA). METHODS: This is a descriptive statistic study. We reviewed the DSA of 348 patients, who had a PA embolisation to reduce the benign prostatic hyperplasia (BPH) symptoms at Radiology Department of Bach Mai Hospital from Oct – 2014 to Oct – 2018. RESULTS: PA was found at 660 pelvic halves, of which 30 pelvic halves (4.5%) had two PAs, 630 pelvic halves had one PA. In terms of the origin of PA, in total 690 PAs, the percentage of type 1, 2, 3, 4 and 5 was successively 33.9%, 13.9%, 18.3%, 23.9% and 10.4%, respectively. Atherosclerosis of PA observed in 20.9%. The ‘corkscrew’ pattern was found in 30.4%. The average diameter of PA was 1.5 ± 0.34mm. The anastomosis of PA with surrounding arteries was common. PA may supply rectum (6.1%), seminal vesical (9.6%), bladder (5.2%), contralateral prostatic parenchyma (13.0%), surrounding soft-tissues (3.5%). CONCLUSION: The common trunk with SVA superior vesical artery was the most common origin of PA. Anastomoses of PA with surrounding tissues were complex

Assessment of Antioxidant and Antibacterial Activities of Lactobacillus farciminis HN11 as a Probiotic Candidate

Background and Objective: Lactobacillus farciminis is an obligate homofermentative bacterial species in fermented foods. Although other species such as Lactobacillus plantarum, Lactobacillus acidophilus, Lactobacillus casei and Lactobacillus rhamnosus in Lactobacillus genus have been well characterized, probiotic characteristics of Lactobacillus farciminis still need to investigate. Thus, the objective of this study was to investigate probiotic characteristics and antibacterial activity of Lactobacillus farciminis HN11 isolated from Solanum macrocarpon sauces in Hue city, Vietnam. Material and Methods: Lactobacillus farciminis HN11 was cultured in Rogosa and Sharpe media and antibacterial activity of the free-cell suspension was assessed against Escherichia coli, Vibrio parahaemolyticus K5, Vibrio parahaemolyticus KS-02, Vibrio owensii KS-05, Vibrio alginolyticus KS-08, Vibrio alginolyticus A1-1 and Staphylococcus aureus using agar well diffusion method. Various probiotic characteristics of the isolate including antibacterial and antioxidant activities, autoaggregation and coaggregation were assessed. Furthermore, hemolytic and amino-acid dercarboxylase activities were assessed for biosafety assessment. The strain abilities to resist sodium chloride and bile salts were assessed as well. Results and Conclusion: Lactobacillus farciminis HN11 exhibited significant resistance to NaCl and bile salts. The strain expressed high coaggregation abilities for Escherichia coli, significant autoaggregation abilities and antibacterial activities against Vibrio spp. and Escherichia coli. Antioxidant assessment showed that Lactobacillus farciminis HN11 contained high antioxidant activities. This strain was negative for hemolytic and amino-acid dercarboxylase activities. Moreover, ampicillin and chloramphenicol inhibited growth of Lactobacillus farciminis HN11. This study assessed characteristics of Lactobacillus farciminis HN11 and showed its great potentials as a probiotic in fermented foods, enhancing antioxidant and decreasing harmful foodborne bacteria. Although, encapsulation of the strain within acid resistance materials is suggested to better protect it against high-acid contents of the stomach. Conflict of interest: The authors declare no conflict of interest