Recent progress in cellulose nanocrystals: sources and production

Cellulose nanocrystals, a class of fascinating bio-based nanoscale materials, have received a tremendous amount of interest both in industry and academia owing to its unique structural features and impressive physicochemical properties such as biocompatibility, biodegradability, renewability, low density, adaptable surface chemistry, optical transparency, and improved mechanical properties. This nanomaterial is a promising candidate for applications in fields such as biomedical, pharmaceuticals, electronics, barrier films, nanocomposites, membranes, supercapacitors, etc. New resources, new extraction procedures, and new treatments are currently under development to satisfy the increasing demand of manufacturing new types of cellulose nanocrystals-based materials on an industrial scale. Therefore, this review addresses the recent progress in the production methodologies of cellulose nanocrystals, covering principal cellulose resources and the main processes used for its isolation. A critical and analytical examination of the shortcomings of various approaches employed so far is made. Additionally, structural organization of cellulose and nomenclature of cellulose nanomaterials have also been discussed for beginners in this field

Lambda hyperonic effect on the normal driplines

A generalized mass formula is used to calculate the neutron and proton drip lines of normal and lambda hypernuclei treating non-strange and strange nuclei on the same footing. Calculations suggest existence of several bound hypernuclei whose normal cores are unbound. Addition of Lambda or, Lambda-Lambda hyperon(s) to a normal nucleus is found to cause shifts of the neutron and proton driplines from their conventional limits.Comment: 6 pages, 4 tables, 0 figur

Microwave-Assisted Rapid Synthesis of Reduced Graphene Oxide-Based Gum Tragacanth Hydrogel Nanocomposite for Heavy Metal Ions Adsorption

This work aims to address the effectiveness and challenges of non-destructive testing (NDT) by active infrared thermography (IRT) for the inspection of aerospace-grade composite samples and seeks to compare uncooled and cooled thermal cameras using the signal-to-noise ratio (SNR) as a performance parameter. It focuses on locating impact damages and optimising the results using several signal processing techniques. The work successfully compares both types of cameras using seven different SNR definitions, to understand if a lower-resolution uncooled IR camera can achieve an acceptable NDT standard. Due to most uncooled cameras being small, lightweight, and cheap, they are more accessible to use on an unmanned aerial vehicle (UAV). The concept of using a UAV for NDT on a composite wing is explored, and the UAV is also tracked using a localisation system to observe the exact movement in millimetres and how it affects the thermal data. It was observed that an NDT UAV can access difficult areas and, therefore, can be suggested for significant reduction of time and cost

Enhanced Production of Neutron-Rich Rare Isotopes in Peripheral Collisions at Fermi Energies

A large enhancement in the production of neutron-rich projectile residues is observed in the reactions of a 25 MeV/nucleon 86Kr beam with the neutron rich 124Sn and 64Ni targets relative to the predictions of the EPAX parametrization of high-energy fragmentation, as well as relative to the reaction with the less neutron-rich 112Sn target. The data demonstrate the significant effect of the target neutron-to-proton ratio (N/Z) in peripheral collisions at Fermi energies. A hybrid model based on a deep-inelastic transfer code (DIT) followed by a statistical de-excitation code appears to account for part of the observed large cross sections. The DIT simulation indicates that the production of the neutron-rich nuclides in these reactions is associated with peripheral nucleon exchange. In such peripheral encounters, the neutron skins of the neutron-rich 124Sn and 64Ni target nuclei may play an important role. From a practical viewpoint, such reactions between massive neutron-rich nuclei offer a novel and attractive synthetic avenue to access extremely neutron-rich rare isotopes towards the neutron-drip line.Comment: 4 pages, 3 figures, submitted to Phys. Rev. Let

Quantification and confocal imaging of protein specific molecularly imprinted polymers

We have employed FITC-albumin as the protein template molecule in an aqueous phase molecular imprinted polymer (HydroMIP) strategy. For the first time, the use of a fluorescently labelled template is reported, with subsequent characterisation of the smart material to show that the HydroMIP possess a significant molecular memory in comparison to that of the nonimprinted control polymer (HydroNIP). The imaging of the FITC-albumin imprinted HydroMIP using confocal microscopy is described, with the in situ removal of imprinted protein displayed in terms of observed changes in the fluorescence of the imprinted polymer, both before and after template elution (using a 10% SDS/10% AcOH (w/v) solution). We also report the imaging of a bovine haemoglobin (BHb) imprinted HydroMIP using two-photon confocal microscopy, and describe the effects of template elution upon protein autofluorescence. The findings further contribute to the understanding of aqueous phase molecular imprinting protocols, and document the use of fluorescence as a useful tool in template labelling/detection and novel imaging strategies

Experimental Validation of the Largest Calculated Isospin-Symmetry-Breaking Effect in a Superallowed Fermi Decay

A precision measurement of the gamma yields following the beta decay of 32Cl has determined its isobaric analogue branch to be (22.47^{+0.21}_{-0.19})%. Since it is an almost pure Fermi decay, we can also determine the amount of isospin-symmetry breaking in this superallowed transition. We find a very large value, delta_C=5.3(9)%, in agreement with a shell-model calculation. This result sets a benchmark for isospin-symmetry-breaking calculations and lends support for similarly-calculated, yet smaller, corrections that are currently applied to 0+ -> 0+ transitions for tests of the Standard Model

Asymptotic normalization coefficients for 8B->7Be+p from a study of 8Li->7Li+n

Asymptotic normalization coefficients (ANCs) for 8Li->7Li+n have been extracted from the neutron transfer reaction 13C(7Li,8Li)12C at 63 MeV. These are related to the ANCs in 8B->7Be+p using charge symmetry. We extract ANCs for 8B that are in very good agreement with those inferred from proton transfer and breakup experiments. We have also separated the contributions from the p_1/2 and p_3/2 components in the transfer. We find the astrophysical factor for the 7Be(p,gamma)8B reaction to be S_17(0)=17.6+/-1.7 eVb. This is the first time that the rate of a direct capture reaction of astrophysical interest has been determined through a measurement of the ANCs in the mirror system.Comment: 5 pages, 3 figures, 2 table

Three-body decay of 6^{6}Be

Three-body correlations for the ground-state decay of the lightest two-proton emitter $^{6}$Be are studied both theoretically and experimentally. Theoretical studies are performed in a three-body hyperspherical-harmonics cluster model. In the experimental studies, the ground state of $^{6}$Be was formed following the $\alpha$ decay of a $^{10}$C beam inelastically excited through interactions with Be and C targets. Excellent agreement between theory and experiment is obtained demonstrating the existence of complicated correlation patterns which can elucidate the structure of $^{6}$Be and, possibly, of the A=6 isobar.Comment: 17 pages, 21 figures, 5 table

Asymptotic Normalization Coefficients for 13C+p->14N

The $^{13}C(^{14}N,^{13}C)^{14}N$ proton exchange reaction has been measured at an incident energy of 162 MeV. Angular distributions were obtained for proton transfer to the ground and low lying excited states in $^{14}N$. Elastic scattering of $^{14}N$ on $^{13}C$ also was measured out to the rainbow angle region in order to find reliable optical model potentials. Asymptotic normalization coefficients for the system $^{13}C+p\to {}^{14}N$ have been found for the ground state and the excited states at 2.313, 3.948, 5.106 and 5.834 MeV in $^{14}N$. These asymptotic normalization coefficients will be used in a determination of the S-factor for $^{7}Be(p,\gamma)^{8}B$ at solar energies from a measurement of the proton transfer reaction $^{14}N(^{7}Be,^{8}B)^{13}C$.Comment: 5 pages, 6 figure

Tests of Transfer Reaction Determinations of Astrophysical S-Factors

The ${}^{16}O ({}^{3}He,d) {}^{17}F$ reaction has been used to determine asymptotic normalization coefficients for transitions to the ground and first excited states of ${}^{17}F$. The coefficients provide the normalization for the tails of the overlap functions for ${}^{17}F \to{}^{16}O + p$ and allow us to calculate the S-factors for ${}^{16}O (p,\gamma){}^{17}F$ at astrophysical energies. The calculated S-factors are compared to measurements and found to be in very good agreement. This provides the first test of this indirect method to determine astrophysical direct capture rates using transfer reactions. In addition, our results yield S(0) for capture to the ground and first excited states in $^{17}F$, without the uncertainty associated with extrapolation from higher energies.Comment: 6 pages, 2 figure