Evaluation of the Mineral Element Profile of Wastes of Some Wine Grape (Vitis Vinifera L.) Varieties

In this study, the level of macro and micro elements of six wine grape cultivars were determined in seeds, bagasse (skin and pulp) and pomace (seed, skin and pulp) by inductively coupled plasma mass spectrometry and atomic absorption spectroscopy after microwave digestion (ICP-AES). The levels of macro and micro elements exhibited a genotype dependent alteration and affected by the part of the berry sampled. Potassium was the predominant macro element in bagasse and pomace, varying from 6.78 g/kg dry weight in pomace (Carignane) to 21.05 g/kg dry weight in bagasse (Cabernet Sauvignon). However, the level of calcium was higher than potassium in seeds and varied between 4.95 g/kg (Kalecik karası) and 6.73 g/kg (Carignane). Seeds were also richer than the bagasse and pomace related with phosphorus, magnesium, and sulfur. Among the micro elements, Fe had the highest amount in all parts of the berries. Its content ranged from 13.9 mg/kg dry weights in bagasse of Semillon to 24.8 mg/kg dry weight in seeds of Syrah. Iron, manganese, zinc and molybdenum in seeds; copper and boron in bagasse were higher amount than the other groups analyzed. The results of this study show that all parts of the grape berries are potentially rich sources of mineral elements. So, they could be used as a food supplement to improve the nutritive value of the human diet and for some engineering processes in food industry

Dynamic Behavior of Droplet Impact on Inclined Surfaces with Acoustic Waves

Droplet impact on arbitrary inclined surfaces is of great interest for applications such as antifreezing, self-cleaning, and anti-infection. Research has been focused on texturing the surfaces to alter the contact time and rebouncing angle upon droplet impact. In this paper, using propagating surface acoustic waves (SAWs) along the inclined surfaces, we present a novel technique to modify and control key droplet impact parameters, such as impact regime, contact time, and rebouncing direction. A high-fidelity finite volume method was developed to explore the mechanisms of droplet impact on the inclined surfaces assisted by SAWs. Numerical results revealed that applying SAWs modifies the energy budget inside the liquid medium, leading to different impact behaviors. We then systematically investigated the effects of inclination angle, droplet impact velocity, SAW propagation direction, and applied SAW power on the impact dynamics and showed that by using SAWs, droplet impact on the nontextured hydrophobic and inclined surface is effectively changed from deposition to complete rebound. Moreover, the maximum contact time reduction up to ∼50% can be achieved, along with an alteration of droplet spreading and movement along the inclined surfaces. Finally, we showed that the rebouncing angle along the inclined surface could be adjusted within a wide range

Tuning the magnetic anisotropy in single-layer crystal structures

The effect of an applied electric field and the effect of charging are investigated on the magnetic anisotropy (MA) of various stable two-dimensional (2D) crystals such as graphene, FeCl2, graphone, fluorographene, and MoTe2 using first-principles calculations. We found that the magnetocrystalline anisotropy energy of Co-on-graphene and Os-doped-MoTe2 systems change linearly with electric field, opening the possibility of electric field tuning MA of these compounds. In addition, charging can rotate the easy-axis direction of Co-on-graphene and Os-doped-MoTe2 systems from the out-of-plane (in-plane) to in-plane (out-of-plane) direction. The tunable MA of the studied materials is crucial for nanoscale electronic technologies such as data storage and spintronics devices. Our results show that controlling the MA of the mentioned 2D crystal structures can be realized in various ways, and this can lead to the emergence of a wide range of potential applications where the tuning and switching of magnetic functionalities are important.Flemish Science Foundation (FWO-Vl); Methusalem Foundation of the Flemish government; Hercules Foundation; FWO Pegasus Marie Curie Fellowship; TUBITAK (111T318

Polysulfone/Clay Nanocomposites by in situ Photoinduced Crosslinking Polymerization

Cataloged from PDF version of article.PSU/MMT nanocomposites are prepared by dispersing MMT nanolayers in a PSU matrix via in situ photoinduced crosslinking polymerization. Intercalated methacrylate-functionalized MMT and polysulfone dimethacrylate macromonomer are synthesized independently by esterification. In situ photoinduced crosslinking of the intercalated monomer and the PSU macromonomer in the silicate layers leads to nanocomposites that are formed by individually dispersing inorganic silica nanolayers in the polymer matrix. The morphology of the nanocomposites is investigated by XRD and TEM, which suggests the random dispersion of silicate layers in the PSU matrix. TGA results confirm that the thermal stability and char yield of PSU/MMT nanocomposites increases with the increase of clay loading

Endoscopic Removal of an Unusual Foreign Body Causing Gastrointestinal Bleeding

Foreign body ingestion is a condition more common in the pediatric population than in adults. In adults, although foreign body ingestion can be well tolerated, approximately 10-20% of patients require endoscopic intervention. Delayed diagnosis and unremoved foreign bodies can cause serious and fatal complications including perforation, fistula and gastrointestinal bleeding. Here we report a patient with bleeding duodenal ulcer thought to be initiated by a large foreign body

Computer models of saliency alone fail to predict subjective visual attention to landmarks during observed navigation

This study aimed to understand whether or not computer models of saliency could explain landmark saliency. An online survey was conducted and participants were asked to watch videos from a spatial navigation video game (Sea Hero Quest). Participants were asked to pay attention to the environments within which the boat was moving and to rate the perceived saliency of each landmark. In addition, state-of-the-art computer saliency models were used to objectively quantify landmark saliency. No significant relationship was found between objective and subjective saliency measures. This indicates that during passive observation of an environment while being navigated, current automated models of saliency fail to predict subjective reports of visual attention to landmarks