Local formation of nitrogen-vacancy centers in diamond by swift heavy ions

We exposed nitrogen-implanted diamonds to beams of swift uranium and gold ions (~1 GeV) and find that these irradiations lead directly to the formation of nitrogen vacancy (NV) centers, without thermal annealing. We compare the photoluminescence intensities of swift heavy ion activated NV- centers to those formed by irradiation with low-energy electrons and by thermal annealing. NV- yields from irradiations with swift heavy ions are 0.1 of yields from low energy electrons and 0.02 of yields from thermal annealing. We discuss possible mechanisms of NV-center formation by swift heavy ions such as electronic excitations and thermal spikes. While forming NV centers with low efficiency, swift heavy ions enable the formation of three dimensional NV- assemblies over relatively large distances of tens of micrometers. Further, our results show that NV-center formation is a local probe of (partial) lattice damage relaxation induced by electronic excitations from swift heavy ions in diamond.Comment: to be published in Journal of Applied Physic

Extreme rejuvenation of a bulk metallic glass at the nanoscale by swift heavy ion irradiation

Swift heavy ions can be used as a tool to tune material properties by generating high aspect ratio, nanometric trails of defects, or new disordered phases. This work explores different aspects of using this tool for rejuvenating and enhancing plasticity in bulk metallic glasses. An amorphous alloy with a nominal composition of Pd40Ni40P20 was irradiated with GeV-accelerated Au ions. Irradiation-induced out-of-plane swelling steps up to approxi- mately 100 nm in height are measured at the boundary between irradiated and non-irradiated areas. Changes of the relaxation enthalpy have been investigated using differential scanning calorimetry. Low-temperature heat capacity measurements substantiate an irradiation-induced increase of the boson peak height with increasing fluences. Accompanying transport measurements using radioactive Ag atoms as tracer also revealed increased diffusion rates in the irradiated samples dependent on the total fluence. Nano-indentation measurements show enhanced plasticity in the ion-irradiated glass which can be correlated with an increased heterogeneity as indicated by variable resolution fluctuation electron microscopy. The whole volume of the derived data sub- stantiates a prominent enhancement of the excess volume in the solidified ion tracks and the irradiation-induced modifications are discussed and analyzed in the framework of strong glass rejuvenation within the nanometric ion tracks

Heavy ion induced radiation effects in novel molybdenum-carbide graphite composite materials

Innovative molybdenum-carbide graphite (Mo-Gr) composites were specifically developed for high energy physics applications. These materials are showing a very promising combination of thermal, electrical, and mechanical properties for application in beam protection elements for high-power accelerators. To date very little is known about their structural and dimensional stability and about degradation of functional properties under irra- diation. Within the EU, FP7, EuCARD-2 project [1], an intense campaign for testing radiation hardness using different particle beams and energies is taking place at GSI Helmholtzzentrum as well as at Brookhaven National Laboratory (USA) and Kurchatov Institute ( Russia)

Multicomponent and High Entropy Alloys

YesThis paper describes some underlying principles of multicomponent and high entropy alloys, and gives some examples of these materials. Different types of multicomponent alloy and different methods of accessing multicomponent phase space are discussed. The alloys were manufactured by conventional and high speed solidification techniques, and their macroscopic, microscopic and nanoscale structures were studied by optical, X-ray and electron microscope methods. They exhibit a variety of amorphous, quasicrystalline, dendritic and eutectic structures