148 research outputs found
Hybridisation at the organic-metal interface: a surface-scientific analogue of H\"uckel's rule?
We demonstrate that cyclooctatetraene (COT) can be stabilised in different
conformations when adsorbed on different noble-metal surfaces due to varying
molecule-substrate interaction. While at first glance the behaviour seems to be
in accordance with H\"uckel's rule, a theoretical analysis reveals no
significant charge transfer. The driving mechanism for the conformational
change is hybridisation at the organic-metal interface and does not necessitate
any charge transfer.Comment: Accepted for publication in Chemical Communications. Main article: 6
pages, 2 figures; Supplementary Information: 4 pages, 3 figures, 1 table. All
in one fil
Coherent terabit communications with microresonator Kerr frequency combs
Optical frequency combs enable coherent data transmission on hundreds of
wavelength channels and have the potential to revolutionize terabit
communications. Generation of Kerr combs in nonlinear integrated microcavities
represents a particularly promising option enabling line spacings of tens of
GHz, compliant with wavelength-division multiplexing (WDM) grids. However, Kerr
combs may exhibit strong phase noise and multiplet spectral lines, and this has
made high-speed data transmission impossible up to now. Recent work has shown
that systematic adjustment of pump conditions enables low phase-noise Kerr
combs with singlet spectral lines. Here we demonstrate that Kerr combs are
suited for coherent data transmission with advanced modulation formats that
pose stringent requirements on the spectral purity of the optical source. In a
first experiment, we encode a data stream of 392 Gbit/s on subsequent lines of
a Kerr comb using quadrature phase shift keying (QPSK) and 16-state quadrature
amplitude modulation (16QAM). A second experiment shows feedback-stabilization
of a Kerr comb and transmission of a 1.44 Tbit/s data stream over a distance of
up to 300 km. The results demonstrate that Kerr combs can meet the highly
demanding requirements of multi-terabit/s coherent communications and thus
offer a solution towards chip-scale terabit/s transceivers
Universal asymptotic behavior in flow equations of dissipative systems
Based on two dissipative models, universal asymptotic behavior of flow
equations for Hamiltonians is found and discussed. Universal asymptotic
behavior only depends on fundamental bath properties but not on initial system
parameters, and the integro-differential equations possess an universal
attractor. The asymptotic flow of the Hamiltonian can be characterized by a
non-local differential equation which only depends on one parameter -
independent of the dissipative system or truncation scheme. Since the fixed
point Hamiltonian is trivial, the physical information is completely
transferred to the transformation of the observables. This yields a more stable
flow which is crucial for the numerical evaluation of correlation functions.
Furthermore, the low energy behavior of correlation functions is determined
analytically. The presented procedure can also be applied if relevant
perturbations are present as is demonstrated by evaluating dynamical
correlation functions for sub-Ohmic environments. It can further be generalized
to other dissipative systems.Comment: 15 pages, 9 figures; to appear in Phys. Rev.
Spontaneous symmetry breaking in the colored Hubbard model
The Hubbard model is reformulated in terms of different ``colored'' fermion
species for the electrons or holes at different lattice sites.
Antiferromagnetic ordering or d-wave superconductivity can then be described in
terms of translationally invariant expectation values for colored composite
scalar fields. A suitable mean field approximation for the two dimensional
colored Hubbard model shows indeed phases with antiferromagnetic ordering or
d-wave superconductivity at low temperature. At low enough temperature the
transition to the antiferromagnetic phase is of first order. The present
formulation also allows an easy extension to more complicated microscopic
interactions.Comment: 19 pages, 5 figure
Fingerprints of the urban particle number size distribution in Helsinki, Finland : Local versus regional characteristics
Peer reviewe
Tomonaga-Luttinger model with an impurity for a weak two-body interaction
The Tomonaga-Luttinger model with impurity is studied by means of flow
equations for Hamiltonians. The system is formulated within collective density
fluctuations but no use of the bosonization formula is made. The truncation
scheme includes operators consisting of up to four fermion operators and is
valid for small electron-electron interactions. In this regime, the exact
expression for the anomalous dimension is recovered. Furthermore, we verify the
phase diagram of Kane and Fisher also for intermediate impurity strength. The
approach can be extended to more general one-body potentials.Comment: 10 pages, 1 figur
The role of seasonality of mineral dust concentration and size on glacial/interglacial dust changes in the EPICA Dronning Maud Land ice core
We present a record of particulate dust concentration and size distribution in subannual resolution measured on the European Project for Ice Coring in Antarctica (EPICA) Dronning Maud Land (EDML) ice core drilled in the Atlantic sector of the East Antarctic plateau. The record reaches from present day back to the penultimate glacial until 145,000 years B.P. with subannual resolution from 60,000 years B.P. to the present. Mean dust concentrations are a factor of 46 higher during the glacial (~850–4600 ng/mL) compared to the Holocene (~16–112 ng/mL) with slightly smaller dust particles during the glacial comparedto the Holocene and with an absolute minimum in the dust size at 16,000 years B.P. The changes in dust concentration are mainly attributed to changes in source conditions in southern South America. An increase in the modal value of the dust size suggests that at 16,000 years B.P. a major change in atmospheric circulation apparently allowed more direct transport of dust particles to the EDML drill site. We find a clear in-phase relation of the seasonal variation in dust mass concentration and dust size during the glacial
(r(conc,size) = 0.8) but no clear phase relationship during the Holocene (0
<r(conc,size)<0.4). With a simple conceptual 1-D model describing the transport of the dust to the ice sheet using the size as an indicator
for transport intensity, we find that the effect of the changes in the seasonality of the source emission strength and the transport intensity on the dust decrease over Transition 1 can significantly contribute to the
large decrease of dust concentration from the glacial to the Holocene
Genomics of Divergence along a Continuum of Parapatric Population Differentiation
MM received funding from the Max Planck innovation funds for this project. PGDF was supported by a Marie Curie European Reintegration Grant (proposal nr 270891). CE was supported by German Science Foundation grants (DFG, EI 841/4-1 and EI 841/6-1)
- …