Cold N+NH Collisions in a Magnetic Trap

We present an experimental and theoretical study of atom-molecule collisions in a mixture of cold, trapped atomic nitrogen and NH molecules at a temperature of $\sim 600$~mK. We measure a small N+NH trap loss rate coefficient of $k^{(\mathrm{N+NH})}_\mathrm{loss} = 8(4) \times 10^{-13}$~cm$^{3}$s$^{-1}$. Accurate quantum scattering calculations based on {\it ab initio} interaction potentials are in agreement with experiment and indicate the magnetic dipole interaction to be the dominant loss mechanism. Our theory further indicates the ratio of N+NH elastic to inelastic collisions remains large ($>100$) into the mK regime

Kz selective scattering within quasiparticle interference measurements of FeSe

Quasiparticle interference (QPI) provides a wealth of information relating to the electronic structure of a material. However, it is often assumed that this information is constrained to two-dimensional electronic states. We show that this is not necessarily the case. For FeSe, a system dominated by surface defects, we show that it is actually all electronic states with negligible group velocity in the z axis that are contained within the experimental data. By using a three-dimensional tight-binding model of FeSe, fit to photoemission measurements, we directly reproduce the experimental QPI scattering dispersion, within a T-matrix formalism, by including both kz=0 and kz=π electronic states. This result unifies both tunnelling based and photoemission based experiments on FeSe and highlights the importance of kz within surface sensitive measurements of QPI.Publisher PDFPeer reviewe

FeSe and the missing electron pocket problem

LR acknowledges funding from the Royal Commission for the Exhibition 1851.The nature and origin of electronic nematicity remains a significant challenge in our understanding of the iron-based superconductors. This is particularly evident in the iron chalcogenide, FeSe, where it is currently unclear how the experimentally determined Fermi surface near the M point evolves from having two electron pockets in the tetragonal state, to exhibiting just a single electron pocket in the nematic state. This has posed a major theoretical challenge, which has become known as the missing electron pocket problem of FeSe, and is of central importance if we wish to uncover the secrets behind nematicity and superconductivity in the wider iron-based superconductors. Here, we review the recent experimental work uncovering this nematic Fermi surface of FeSe from both ARPES and STM measurements, as well as current theoretical attempts to explain this missing electron pocket of FeSe, with a particular focus on the emerging importance of incorporating the dxy orbital into theoretical descriptions of the nematic state. Furthermore, we will discuss the consequence this missing electron pocket has on the theoretical understanding of superconductivity in this system and present several remaining open questions and avenues for future research.Publisher PDFPeer reviewe

Cold heteromolecular dipolar collisions

We present the first experimental observation of cold collisions between two different species of neutral polar molecules, each prepared in a single internal quantum state. Combining for the first time the techniques of Stark deceleration, magnetic trapping, and cryogenic buffer gas cooling allows the enhancement of molecular interaction time by 10$^5$. This has enabled an absolute measurement of the total trap loss cross sections between OH and ND$_3$ at a mean collision energy of 3.6 cm$^{-1}$ (5 K). Due to the dipolar interaction, the total cross section increases upon application of an external polarizing electric field. Cross sections computed from \emph{ab initio} potential energy surfaces are in excellent agreement with the measured value at zero external electric field. The theory presented here represents the first such analysis of collisions between a $^2\Pi$ radical and a closed-shell polyatomic molecule.Comment: 7 pages, 5 figure

A general few-projection method for tomographic reconstruction of samples consisting of several distinct materials

We present a method for tomographic reconstruction of objects containing several distinct materials, which is capable of accurately reconstructing a sample from vastly fewer angular projections than required by conventional algorithms. The algorithm is more general than many previous discrete tomography methods, as: (i) a priori knowledge of the exact number of materials is not required; (ii) the linear attenuation coefficient of each constituent material may assume a small range of a priori unknown values. We present reconstructions from an experimental x-ray computed tomography scan of cortical bone acquired at the SPring-8 synchrotron

Revealing the single electron pocket of FeSe in a single orthorhombic domain

Authors acknowledge Diamond Light Source for time on beamline I05-ARPES under Proposal SI23890. L.C.R. acknowledges funding from the Royal Commission for the Exhibition of 1851.We measure the electronic structure of FeSe from within individual orthorhombic domains. Enabled by an angle-resolved photoemission spectroscopy beamline with a highly focused beam spot (nano-ARPES), we identify clear stripelike orthorhombic domains in FeSe with a length scale of approximately 1-5 μm. Our photoemission measurements of the Fermi surface and band structure within individual domains reveal a single electron pocket at the Brillouin zone corner. This result provides clear evidence for a one-electron-pocket electronic structure of FeSe, observed without the application of uniaxial strain, and calls for further theoretical insight into this unusual Fermi surface topology. Our results also showcase the potential of nano-ARPES for the study of correlated materials with local domain structures.Publisher PDFPeer reviewe

Mechanism of Collisional Spin Relaxation in Triplet-Sigma Molecules

We measure and theoretically determine the effect of molecular rotational splitting on Zeeman relaxation rates in collisions of cold Triplet-Sigma molecules with helium atoms in a magnetic field. All four stable isotopomers of the imidogen (NH) molecule are magnetically trapped and studied in collisions with 3He and 4He. The 4He data support the predicted inverse square dependence of the collision induced Zeeman relaxation rate coefficient on the molecular rotational constant B. The measured 3He rate coefficients are much larger than 4He and depend less strongly on B, and the theoretical analysis indicates they are strongly affected by a shape resonance. The results demonstrate the influence of molecular structure on collisional energy transfer at low temperatures.Comment: 10 pages, 3 figures, revised introduction and focu