Infrared imaging investigation of temperature fluctuation and spatial distribution for a large laminated lithium ion power battery

The file attached to this record is the author's final peer reviewed version. The Publisher's final version can be found by following the DOI link.The present study investigates the thermal behaviors of a naturally cooled NCM-type LIB (LiNi1−x−yCoxMnyO2 as cathode) from an experimental and systematic approach. The temperature distribution was acquired for different discharge rates and Depth of Discharge (DOD) by the infrared imaging (IR) technology. Two new factors, the temperature variance ( ) and local overheating index (LOH index), were proposed to assess the temperature fluctuation and distribution. Results showed that the heat generation rate was higher on the cathode side than that on the anode side due to the different resistivity of current collectors. For a low-power discharge, the eventual stable high-temperature zone occurred in the center of the battery, while with a high-power discharge, the upper part of the battery was the high temperature region from the very beginning of discharge. It was found that the temperature variance ( ) and local overheating index (LOH index) were capable of holistically exhibiting the temperature non-uniformity both on numerical fluctuation and spatial distribution with varying discharge rates and DOD. With increasing the discharge rate and DOD, temperature distribution showed an increasingly non-uniform trend, especially at the initial and final stage of high-power discharge, the heat accumulation and concentration area increased rapidly

Improved thermal performance of a large laminated lithium-ion power battery by reciprocating air flow

The file attached to this record is the author's final peer reviewed version. The Publisher's final version can be found by following the DOI link.Thermal safety issues are increasingly critical for large-size laminated Lithium-Ion Batteries (LIBs). Despite a number of investigations conducted on the Battery Thermal Management System (BTMS) with reciprocating air-flow cooling, large laminated power LIBs are still not sufficiently investigated, particularly in the view of battery thermal characteristics. The present study investigates the thermal behaviors of an air-cooled NCM-type LIB (LiNi1−x−yCoxMnyO2 as cathode) from an experimental and systematic approach. The temperature distribution was acquired from different Depth of Discharge (DOD) by the infrared imaging (IR) technology. A reciprocating air-flow cooling method was proposed to restrict the temperature fluctuation and homogenize temperature distribution. Results showed that there was a remarkable temperature distribution phenomenon during the discharge process, the temperature distribution was affected by direction of air-flow. Forward air-flow (from current collector side to lower part of battery) was always recommended at the beginning of the discharge due to the thermal characteristics of the battery. After comprehensive consideration on battery temperature limit and cooling effect, the desired initial reversing timing was about 50% DOD at 3 C discharge rate. Different reversing strategies were investigated including isochronous cycles and aperiodic cycles. It was found that the temperature non-uniformity caused by heat accumulation and concentration was mitigated by reciprocating air-flow with optimized reversing strategy

Radiance and Doppler shift distributions across the network of the quiet Sun

The radiance and Doppler-shift distributions across the solar network provide observational constraints of two-dimensional modeling of transition-region emission and flows in coronal funnels. Two different methods, dispersion plots and average-profile studies, were applied to investigate these distributions. In the dispersion plots, we divided the entire scanned region into a bright and a dark part according to an image of Fe xii; we plotted intensities and Doppler shifts in each bin as determined according to a filtered intensity of Si ii. We also studied the difference in height variations of the magnetic field as extrapolated from the MDI magnetogram, in and outside network. For the average-profile study, we selected 74 individual cases and derived the average profiles of intensities and Doppler shifts across the network. The dispersion plots reveal that the intensities of Si ii and C iv increase from network boundary to network center in both parts. However, the intensity of Ne viii shows different trends, namely increasing in the bright part and decreasing in the dark part. In both parts, the Doppler shift of C iv increases steadily from internetwork to network center. The average-profile study reveals that the intensities of the three lines all decline from the network center to internetwork region. The binned intensities of Si ii and Ne viii have a good correlation. We also find that the large blue shift of Ne viii does not coincide with large red shift of C iv. Our results suggest that the network structure is still prominent at the layer where Ne viii is formed in the quiet Sun, and that the magnetic structures expand more strongly in the dark part than in the bright part of this quiet Sun region.Comment: 10 pages,9 figure

Numerical Study on Indoor Wideband Channel Characteristics with Different Internal Wall

Effects of material and configuration of the internal wall on the performance of wideband channel are investigated by using the Finite Difference Time-Domain (FDTD) method. The indoor wideband channel characteristics, such as the path-loss, Root-Mean-Square (RMS) delay spread and number of the multipath components (MPCs), are presented. The simulated results demonstrate that the path-loss and MPCs are affected by the permittivity, dielectric loss tangent and thickness of the internal wall, while the RMS delay spread is almost not relevant with the dielectric permittivity. Furthermore, the comparison of simulated result with the measured one in a simple scenario has validated the simulation study

Topology of Entanglement in Multipartite States with Translational Invariance

The topology of entanglement in multipartite states with translational invariance is discussed in this article. Two global features are foundby which one can distinguish distinct states. These are the cyclic unit and the quantised geometric phase. Furthermore the topology is indicated by the fractional spin. Finally a scheme is presented for preparation of these types of states in spin chain systems, in which the degeneracy of the energy levels characterises the robustness of the states with translational invariance.Comment: major revision. accepted by EPJ

Thermal stress-induced charge and structure heterogeneity in emerging cathode materials

Nickel-rich layered oxide cathode materials are attractive near-term candidates for boosting the energy density of next generation lithium-ion batteries. The practical implementation of these materials is, however, hindered by unsatisfactory capacity retention, poor thermal stability, and oxygen release as a consequence of structural decomposition, which may have serious safety consequences. The undesired side reactions are often exothermic, causing complicated electro-chemo-mechanical interplay at elevated temperatures. In this work, we explore the effects of thermal exposure on chemically delithiated LiNi0.8Mn0.1Co0.1O2 (NMC-811) at a practical state-of-charge (50% Li content) and an over-charged state (25% Li content). A systematic study using a suite of advanced synchrotron radiation characterization tools reveals the dynamics of thermal behavior of the charged NMC-811, which involves sophisticated structural and chemical evolution; e.g. lattice phase transformation, transition metal (TM) cation migration and valence change, and lithium redistribution. These intertwined processes exhibit a complex 3D spatial heterogeneity and, collectively, form a valence state gradient throughout the particles. Our study sheds light on the response of NMC-811 to elevated temperature and highlights the importance of the cathode's thermal robustness for battery performance and safety

A study of the problems associated with Dalangdian reservoir, China

There are over 2,300 lakes over 1 km2 in China (total area 80 000 km2). In addition there are approximately 87 000 reservoirs with a storage capacity of 413 billion m3. These form the main supply of drinking water as well as water for industrial and agricultural production and aquaculture. Because of a lack of understanding of the frailty of lake ecosystems and poor environmental awareness, human activities have greatly affected freshwater systems. This article focuses on the problems of one water supply reservoir, Dalangdian Reservoir, and considers options for improving its management. Dalangdian Reservoir is described and occurrence of algal genera given. The authors conclude with remarks on the future of the Dalangdian Reservoir