Creating transient gradients in supramolecular hydrogels

The self‐assembly of low molecular weight gelators in water usually produces homogeneous hydrogels. However, homogeneous gels are not always desired. Using a photoacid generator, it is shown how to form gels with a transient gradient in stiffness, proved using cavitation and bulk rheology. Small‐angle neutron scattering is used to show that the gels formed by photoacid are the result of the same structures as when using a conventional pH trigger. Patterned gels can also be formed, again with transient differences in stiffness

A review and evaluation of secondary school accountability in England: Statistical strengths, weaknesses, and challenges for 'Progress 8' raised by Covid-19

School performance measures are published annually in England to hold schools to account and to support parental school choice. This article reviews and evaluates the ‘Progress 8’ secondary school accountability system for state-funded schools. We assess the statistical strengths and weaknesses of Progress 8 relating to: choice of pupil outcome attainment measure; potential adjustments for pupil input attainment and background characteristics; decisions around which schools and pupils are excluded from the measure; presentation of Progress 8 to users, choice of statistical model, and calculation of statistical uncertainty; and issues related to the volatility of school performance over time, including scope for reporting multi-year averages. We then discuss challenges for Progress 8 raised by the COVID-19 pandemic. Six simple recommendations follow to improve Progress 8 and school accountability in England. Context and implication Rationale for this study This study fulfils a need for a comprehensive statistical evaluation of the Progress 8 school accountability system in England, which has been in place since 2016. Why the new findings matter A review of Progress 8 is an important contribution as decisions on its calculation and presentation have important consequences for schools and pupils. Implications for educational researchers and policy makers Our findings on the statistical strengths and weaknesses of Progress 8 and the resulting recommendations made for improvements to the measure and school accountability have clear implications for informing policy makers in the educational system. This includes wider lessons extending beyond Progress 8 to other performance metrics and to other school systems internationally where similar issues apply. Additionally, the review highlights key concerns that the public and school practitioners may like to consider when drawing upon Progress 8 to make decisions around school choice and in assessing how well a school is performing

Controlling the properties of the micellar and gel phase by varying the counterion in functionalised-dipeptide systems

The micellar aggregates formed at high pH for dipeptide-based gelators can be varied by using different alkali metal salts to prepare the solutions. The nature of the micellar aggregates directly affects the properties of the resulting gels

Isotopic control over self-assembly in supramolecular gels

It is common to switch between H2O and D2O when examining peptide-based systems with the assumption being that there are no effects from this change. Here, we describe the effect of changing from H2O to D2O in a number of low molecular weight dipeptide-based gels. Gels are formed by decreasing the pH. In most cases, there is little dif-ference in the structures formed at high pH, but this is not universally true. On lowering the pH, the ki-netics of gelation are affected and, in some cases, the structures underpinning the gel network are dif-ferent. Where there are differences in the self-assembled structures, the resulting gel properties are different. We therefore show isotopic control over gel properties is possible

Timeline analysis and wavelet multiscale analysis of the AKARI All-Sky Survey at 90 micron

We present a careful analysis of the point source detection limit of the AKARI All-Sky Survey in the WIDE-S 90 $\mu$m band near the North Ecliptic Pole (NEP). Timeline Analysis is used to detect IRAS sources and then a conversion factor is derived to transform the peak timeline signal to the interpolated 90 $\mu$m flux of a source. Combined with a robust noise measurement, the point source flux detection limit at S/N $>5$ for a single detector row is $1.1\pm0.1$ Jy which corresponds to a point source detection limit of the survey of $\sim$0.4 Jy. Wavelet transform offers a multiscale representation of the Time Series Data (TSD). We calculate the continuous wavelet transform of the TSD and then search for significant wavelet coefficients considered as potential source detections. To discriminate real sources from spurious or moving objects, only sources with confirmation are selected. In our multiscale analysis, IRAS sources selected above $4\sigma$ can be identified as the only real sources at the Point Source Scales. We also investigate the correlation between the non-IRAS sources detected in Timeline Analysis and cirrus emission using wavelet transform and contour plots of wavelet power spectrum. It is shown that the non-IRAS sources are most likely to be caused by excessive noise over a large range of spatial scales rather than real extended structures such as cirrus clouds.Comment: 16 pages, 19 figures, 5 tables, accepted for publication in MNRA

Analytical model for calculating the nonlinear distortion in silicon-based electro-optic Mach-Zehnder modulators

[EN] In this study, an analytical model for calculating the nonlinear harmonic/intermodulation distortion for RF signals in silicon-based electro-optic modulators is investigated by considering the nonlinearity on the effective index change curve with the operation point and the device structure simultaneously. Distortion expressions are obtained and theoretical results are presented showing that optimal modulator parameters can be found to linearize it. Moreover, the harmonic distortion of a 1 mm silicon-based asymmetric MZI is RF characterized and used to corroborate the theoretical results. Based on the present model, the nonlinear distortion in terms of bias voltage or operating wavelength is calculated and validated by comparing with the experimental data, showing a good agreement between measurements and theory. Analog photonic link quality parameter like carrier-todistortion is one of the parameters that can be found with that model. Finally, the modulation depth is measured to assure that no over-modulation is produced.This work was supported by the funding from the European Commission under project HELIOS (pHotonics Electronics functional Integration on CMOS), FP7-224312. The work of P. Sanchis and J.-M. Fedeli was supported by the funding funding from TEC2012-38540 LEOMIS, TEC2008-06333 SINADEC, and PROMETEO-2010-087. The work of F. Y. Gardes, D. J. Thomson and G. T. Reed was supported by funding received from the UK EPSRC funding body under the grant "UK Silicon Photonics."Gutiérrez Campo, AM.; Brimont, ACJ.; Herrera Llorente, J.; Aamer, M.; Thomson, DJ.; Gardes, FY.; Reed, GT.... (2013). Analytical model for calculating the nonlinear distortion in silicon-based electro-optic Mach-Zehnder modulators. Journal of Lightwave Technology. 31(23):3603-3612. https://doi.org/10.1109/JLT.2013.2286838S36033612312