13,504 research outputs found
Archived 1976-1985 JPL Aircraft SAR Data
This report describes archived data from the Jet Propulsion Laboratory (JPL) aircraft radar expeditions in the mid-1970s through the mid-1980s collected by Ron Blom, JPL Radar Geologist. The dataset was collected during Ron's career at JPL from the 1970s through 2015. Synthetic Aperture Radar (SAR) data in the 1970s and 1980s were recorded optically on long strips of film. SAR imagery was produced via an optical, holographic technique that resulted in long strips of film imagery
Text Organiztion and Structure in Science Textbooks
This study examined the text organization and structure of fourth and sixth grade science textbooks. This included prereading questions, advance organizers, margin notes, and type of text structure. In addition, chapter activities were classified as to the degree of problem solving skills developed by ranking the activities according to Bloom\u27s (1956) taxonomy of cognitive skills
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A pendant proton shuttle on [Fe4N(CO)12]- alters product selectivity in formate vs. H2 production via the hydride [H-Fe4N(CO)12].
Proton relays are known to increase reaction rates for H2 evolution and lower overpotentials in electrocatalytic reactions. In this report we describe two electrocatalysts, [Fe4N(CO)11(PPh3)]- (1-) which has no proton relay, and hydroxyl-containing [Fe4N(CO)11(Ph2P(CH2)2OH)]- (2-). Solid state structures indicate that these phosphine-substituted clusters are direct analogs of [Fe4N(CO)12]- where one CO ligand has been replaced by a phosphine. We show that the proton relay changes the selectivity of reactions: CO2 is reduced selectively to formate by 1- in the absence of a relay, and protons are reduced to H2 under a CO2 atmosphere by 2-. These results implicate a hydride intermediate in the mechanism of the reactions and demonstrate the importance of controlling proton delivery to control product selectivity. Thermochemical measurements performed using infrared spectroelectrochemistry provided pKa and hydricity values for [HFe4N(CO)11(PPh3)]-, which are 23.7, and 45.5 kcal mol-1, respectively. The pKa of the hydroxyl group in 2- was determined to fall between 29 and 41, and this suggests that the proximity of the proton relay to the active catalytic site plays a significant role in the product selectivity observed, since the acidity alone does not account for the observed results. More generally, this work emphasizes the importance of substrate delivery kinetics in determining the selectivity of CO2 reduction reactions that proceed through metal-hydride intermediates
Absolute radiometric calibration of the EUNIS-06 170-205 A channel and calibration update for CDS/NIS
The Extreme-Ultraviolet Normal-Incidence Spectrograph sounding-rocket payload
was flown on 2006 April 12 (EUNIS-06), carrying two independent imaging
spectrographs covering wave bands of 300-370 A in first order and 170-205 A in
second order, respectively. The absolute radiometric response of the EUNIS-06
long-wavelength (LW) channel was directly measured in the same facility used to
calibrate CDS prior to the SOHO launch. Because the absolute calibration of the
short-wavelength (SW) channel could not be obtained from the same lab
configuration, we here present a technique to derive it using a combination of
solar LW spectra and density- and temperature-insensitive line intensity
ratios. The first step in this procedure is to use the coordinated, cospatial
EUNIS and SOHO/CDS spectra to carry out an intensity calibration update for the
CDS NIS-1 waveband, which shows that its efficiency has decreased by a factor
about 1.7 compared to that of the previously implemented calibration. Then,
theoretical insensitive line ratios obtained from CHIANTI allow us to determine
absolute intensities of emission lines within the EUNIS SW bandpass from those
of cospatial CDS/NIS-1 spectra after the EUNIS LW calibration correction. A
total of 12 ratios derived from intensities of 5 CDS and 12 SW emission lines
from Fe Fe X - Fe XIII yield an instrumental response curve for the EUNIS-06 SW
channel that matches well to a relative calibration which relied on combining
measurements of individual optical components. Taking into account all
potential sources of error, we estimate that the EUNIS-06 SW absolute
calibration is accurate to about 20%.Comment: 11 pages, 10 figures, 4 tables. 2010, ApJ Suppl. In pres
Underflight calibration of SOHO/CDS and Hinode/EIS with EUNIS-07
Flights of Goddard Space Flight Center's Extreme-Ultraviolet Normal-Incidence
Spectrograph (EUNIS) sounding rocket in 2006 and 2007 provided updated
radiometric calibrations for SOHO/CDS and Hinode/EIS. EUNIS carried two
independent imaging spectrographs covering wavebands of 300-370 A in first
order and 170-205 A in second order. After each flight, end-to-end radiometric
calibrations of the rocket payload were carried out in the same facility used
for pre-launch calibrations of CDS and EIS. During the 2007 flight, EUNIS, SOHO
CDS and Hinode EIS observed the same solar locations, allowing the EUNIS
calibrations to be directly applied to both CDS and EIS. The measured CDS NIS 1
line intensities calibrated with the standard (version 4) responsivities with
the standard long-term corrections are found to be too low by a factor of 1.5
due to the decrease in responsivity. The EIS calibration update is performed in
two ways. One is using the direct calibration transfer of the calibrated
EUNIS-07 short wavelength (SW) channel. The other is using the insensitive line
pairs, in which one member was observed by EUNIS-07 long wavelength (LW)
channel and the other by EIS in either LW or SW waveband. Measurements from
both methods are in good agreement, and confirm (within the measurement
uncertainties) the EIS responsivity measured directly before the instrument's
launch. The measurements also suggest that the EIS responsivity decreased by a
factor of about 1.2 after the first year of operation. The shape of the EIS SW
response curve obtained by EUNIS-07 is consistent with the one measured in
laboratory prior to launch. The absolute value of the quiet-Sun He II 304 A
intensity measured by EUNIS-07 is consistent with the radiance measured by CDS
NIS in quiet regions near the disk center and the solar minimum irradiance
obtained by CDS NIS and SDO/EVE recently.Comment: 16 pages, 14 figures, 5 tables, accepted by ApJ Supplement (Sep.
2011
Localized vibration: effects on flexibility
Background. Flexibility is an important component of physical conditioning used to improve performance and prevent injury. The application of vibration is one method that has been reported to increase flexibility. The preponderance of the literature reports the effects of whole-body vibration; fewer studies have investigated the effects of local vibration (LV) therapy.
Aims. To assess if LV affects spinal flexibility, the sit-and-reach test, or lower extremity range of motion measurements when compared to controls. To determine if the effects were specific to the site of LV application and if changes persisted between the follow-up visits.
Methods. Forty-three college students (age range 21-40 years) responded to an email advertisement sent to a college of health professions. All participants underwent the same procedures and positioning but the vibration device was activated for the experimental group participants only. Nine flexibility measurements were obtained at the beginning and end of each of three visits.
Results. Changes in flexibility were statistically significant after LV at each visit except for the sit-and-reach test. No between visit effects or carry-over were observed.
Conclusion. The addition of LV to a training regime can improve flexibility immediately after its application. Although the persistence of the effect is unknown, no long-term effects were observed
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