25,710 research outputs found

    Reliability analysis of continuous fiber composite laminates

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    A composite lamina may be viewed as a homogeneous solid whose directional strengths are random variables. Calculation of the lamina reliability under a multi-axial stress state can be approached by either assuming that the strengths act separately (modal or independent action), or that they interact through a quadratic interaction criterion. The independent action reliability may be calculated in closed form, while interactive criteria require simulations; there is currently insufficient data to make a final determination of preference between them. Using independent action for illustration purposes, the lamina reliability may be plotted in either stress space or in a non-dimensional representation. For the typical laminated plate structure, the individual lamina reliabilities may be combined in order to produce formal upper and lower bounds of reliability for the laminate, similar in nature to the bounds on properties produced from variational elastic methods. These bounds are illustrated for a (0/plus or minus 15)sub s Graphite/Epoxy (GR/EP) laminate. And addition, simple physically plausible phenomenological rules are proposed for redistribution of load after a lamina has failed. These rules are illustrated by application to (0/plus or minus 15)sub s and (90/plus or minus 45/0)sub s GR/EP laminates and results are compared with respect to the proposed bounds

    Master of Science

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    thesisEfforts towards understanding the nickel catalyzed cycloaddition of diynes and nitriles to make pyridines are described. During the course of this mechanistic study, a previously uncharacterized class of nickel-nitrile-NHC (N-heterocyclic carbene) dimers, which display cooperative η1 and η2 binding modes of the nitrile to nickel, were discovered. Crystal structures were obtained for select dimers. These dimers proved catalytically competent in the cycloaddition reaction. Pseudo first order kinetics revealed that the reaction was first order in dimer while being zero order in NHC ligand, nitrile, and diyne. While stoichiometric reactions with dimer and diyne in the absence of nitrile did give product, largely improved yields were observed in the presence of free nitrile. Stoichiometric competition studies utilizing various identities of free nitriles and dimers indicated a preference for incorporation of free nitrile into the product versus the dimer-bound nitrile. The results of this study suggest a mechanism involving partial dimer opening as the rate-determining step. This is then followed by nitrile binding, which precedes oxidative coupling with diyne

    Relativistic initial conditions for N-body simulations

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    Initial conditions for (Newtonian) cosmological N-body simulations are usually set by re-scaling the present-day power spectrum obtained from linear (relativistic) Boltzmann codes to the desired initial redshift of the simulation. This back-scaling method can account for the effect of inhomogeneous residual thermal radiation at early times, which is absent in the Newtonian simulations. We analyse this procedure from a fully relativistic perspective, employing the recently-proposed Newtonian motion gauge framework. We find that N-body simulations for LambdaCDM cosmology starting from back-scaled initial conditions can be self-consistently embedded in a relativistic space-time with first-order metric potentials calculated using a linear Boltzmann code. This space-time coincides with a simple "N-body gauge" for z<50 for all observable modes. Care must be taken, however, when simulating non-standard cosmologies. As an example, we analyse the back-scaling method in a cosmology with decaying dark matter, and show that metric perturbations become large at early times in the back-scaling approach, indicating a breakdown of the perturbative description. We suggest a suitable "forwards approach" for such cases.Comment: 20 pages, 8 figure

    General relativistic corrections to NN-body simulations and the Zel'dovich approximation

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    The initial conditions for Newtonian NN-body simulations are usually generated by applying the Zel'dovich approximation to the initial displacements of the particles using an initial power spectrum of density fluctuations generated by an Einstein-Boltzmann solver. We show that in most gauges the initial displacements generated in this way receive a first-order relativistic correction. We define a new gauge, the NN-body gauge, in which this relativistic correction vanishes and show that a conventional Newtonian NN-body simulation includes all first-order relativistic contributions (in the absence of radiation) if we identify the coordinates in Newtonian simulations with those in the relativistic NN-body gauge.Comment: 5 pages, 3 figures, revised text and figures, matches published version in PR

    Scalable Bayesian modeling, monitoring and analysis of dynamic network flow data

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    Traffic flow count data in networks arise in many applications, such as automobile or aviation transportation, certain directed social network contexts, and Internet studies. Using an example of Internet browser traffic flow through site-segments of an international news website, we present Bayesian analyses of two linked classes of models which, in tandem, allow fast, scalable and interpretable Bayesian inference. We first develop flexible state-space models for streaming count data, able to adaptively characterize and quantify network dynamics efficiently in real-time. We then use these models as emulators of more structured, time-varying gravity models that allow formal dissection of network dynamics. This yields interpretable inferences on traffic flow characteristics, and on dynamics in interactions among network nodes. Bayesian monitoring theory defines a strategy for sequential model assessment and adaptation in cases when network flow data deviates from model-based predictions. Exploratory and sequential monitoring analyses of evolving traffic on a network of web site-segments in e-commerce demonstrate the utility of this coupled Bayesian emulation approach to analysis of streaming network count data.Comment: 29 pages, 16 figure

    The Intrinsic Matter Bispectrum in Λ\LambdaCDM

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    We present a fully relativistic calculation of the matter bispectrum at second order in cosmological perturbation theory assuming a Gaussian primordial curvature perturbation. For the first time we perform a full numerical integration of the bispectrum for both baryons and cold dark matter using the second-order Einstein-Boltzmann code, SONG. We review previous analytical results and provide an improved analytic approximation for the second-order kernel in Poisson gauge which incorporates Newtonian nonlinear evolution, relativistic initial conditions, the effect of radiation at early times and the cosmological constant at late times. Our improved kernel provides a percent level fit to the full numerical result at late times for most configurations, including both equilateral shapes and the squeezed limit. We show that baryon acoustic oscillations leave an imprint in the matter bispectrum, making a significant impact on squeezed shapes.Comment: Accepted for publication in JCAP. 17 pages + appendices, 6 figures. Code available at GitHub: http://github.com/coccoinomane/son
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