21,656 research outputs found
Imagining an ideal school for wellbeing: Locating student voice
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A New Equation of State for CCS Pipeline Transport: Calibration of Mixing Rules for Binary Mixtures of CO2 with N2, O2 and H2
One of the aspects currently holding back commercial scale deployment of
carbon capture and storage (CCS) is an accurate understanding of the
thermodynamic behaviour of carbon dioxide and relevant impurities during the
pipeline transport stage. In this article we develop a general framework for
deriving pressure-explicit EoS for impure CO2. This flexible framework
facilitates ongoing development of custom EoS in response to new data and
computational applications. We use our method to generalise a recent EoS for
pure CO2 [Demetriades et al. Proc IMechE Part E, 227 (2013) pp. 117] to binary
mixtures with N2, O2 and H2, obtaining model parameters by fitting to
experiments made under conditions relevant to CCS-pipeline transport. Our model
pertains to pressures up to 16MPa and temperatures between 273K and the
critical temperature of pure CO2. In this region, we achieve close agreement
with experimental data. When compared to the GERG EoS, our EoS has a comparable
level of agreement with CO2 -N2 VLE experiments and demonstrably superior
agreement with the O2 and H2 VLE data. Finally, we discuss future options to
improve the calibration of EoS and to deal with the sparsity of data for some
impurities
Periodic points for good reduction maps on curves
The periodic points of a morphism of good reduction for a smooth projective
curve with good reduction over the p-adics form a discrete set. This is used to
give an interpretation of the morphic height in terms of asymptotic properties
of periodic points, and a morphic analogue of Jensen's formula
<sup>87</sup>Sr/<sup>86</sup>Sr chemostratigraphy of Neoproterozoic Dalradian limestones of Scotland and Ireland: constraints on depositional ages and time scales
New calcite <sup>87</sup>Sr/<sup>86</sup>Sr data for 47 limestones from the metamorphosed and deformed Neoproterozoic-Cambrian Dalradian Supergroup of Scotland and Ireland are used to identify secular trends in seawater <sup>87</sup>Sr/<sup>86</sup>Sr through the Dalradian succession and to constrain its depositional age. Dalradian limestones commonly have Sr greater than 1000 ppm, indicating primary aragonite and marine diagenesis. Low Mn, Mn/Sr less than 0.6, ë<sup>18</sup>O and trace element data indicate that many <sup>87</sup>Sr/<sup>86</sup>Sr ratios are unaltered since diagenesis despite greenschist- to amphibolite-facies metamorphism, consistent with the documented behaviour of Sr and O during metamorphic fluid-rock interaction. Thus, the <sup>87</sup>Sr/<sup>86</sup>Sr data are interpreted largely to reflect <sup>87</sup>Sr/<sup>86</sup>Sr of coeval seawater. Currently available data show that Neoproterozoic seawater <sup>87</sup>Sr/<sup>86</sup>Sr rose from c. 0.7052 at 850-900 Ma to c. 0.7085 or higher in the latest Neoproterozoic. Temporal changes at c. 800 Ma and c . 600 Ma bracket the range in <sup>87</sup>Sr/<sup>86</sup>Sr values of calcite in Grampian. Appin and lowest Argyll Group (c.0.7064-0.7072) and middle and uppermost Argyll Group (c. 0.7082-0.7095) limestones, consistent with a rise in seawater <sup>87</sup>Sr/<sup>86</sup>Sr around 600 Ma. <sup>87</sup>Sr/<sup>86</sup>Sr data are consistent with the sedimentary affinity of the Islay Subgroup with the underlying Appin Group, and with a possible time interval between deposition of Islay and Easdale Subgroup rocks. They indicate that the Dalradian, as a whole, is younger than c. 800 Ma
A composite C-isotope profile for the Neoproterozoic Dalradian Supergroup of Scotland and Ireland
The Neoproterozoic Dalradian Supergroup is a dominantly siliciclastic metasedimentary succession in the Caledonian orogenic belt of Scotland and Ireland. Despite polyphase deformation and greenschist- to upper amphibolite-facies metamorphism, carbonate units distributed throughout the Dalradian record marked δ13Ccarbonate excursions that can be linked to those associated with key environmental events of Neoproterozoic time. These include: (1) tentative correlation of the Ballachulish Limestone with the c. 800 Ma Bitter Springs anomaly; (2) the presence of the pre-Marinoan Trezona anomaly and 635 Ma marinoan-equivalent cap carbonat sequence in rocks of the middle Easdale Subgroup; (3) the terminal proterozoic (c. 600-551 Ma)Wonoka-Shuram anomaly in the Girlsta Limestone on Shetland. These linkages strengthen previously inferred correlations of the Stralinchy-Reelan formations and the Inishowen-Loch na Cille-MacDuff ice-rafted debris beds to the respectively 635 Ma Marinoan and 582 Ma Gaskiers glaciations, and suggest that the oldest Dalradian glacial unit, the Port Askaig Formation, represents one of the c. 750-690 Ma Sturtian glacial episodes. These δ13C data and resulting correlations provide more robust constraints on the geological evolution of the Dalradian Supergroup than anything hitherto available and enhance its utility in helping refine understanding of Neoprotrozoic Earth history
The touch and zap method for in vivo whole-cell patch recording of intrinsic and visual responses of cortical neurons and Glial cells
Whole-cell patch recording is an essential tool for quantitatively establishing the biophysics of brain function, particularly in vivo. This method is of particular interest for studying the functional roles of cortical glial cells in the intact brain, which cannot be assessed with extracellular recordings. Nevertheless, a reasonable success rate remains a challenge because of stability, recording duration and electrical quality constraints, particularly for voltage clamp, dynamic clamp or conductance measurements. To address this, we describe "Touch and Zap", an alternative method for whole-cell patch clamp recordings, with the goal of being simpler, quicker and more gentle to brain tissue than previous approaches. Under current clamp mode with a continuous train of hyperpolarizing current pulses, seal formation is initiated immediately upon cell contact, thus the "Touch". By maintaining the current injection, whole-cell access is spontaneously achieved within seconds from the cell-attached configuration by a self-limited membrane electroporation, or "Zap", as seal resistance increases. We present examples of intrinsic and visual responses of neurons and putative glial cells obtained with the revised method from cat and rat cortices in vivo. Recording parameters and biophysical properties obtained with the Touch and Zap method compare favourably with those obtained with the traditional blind patch approach, demonstrating that the revised approach does not compromise the recorded cell. We find that the method is particularly well-suited for whole-cell patch recordings of cortical glial cells in vivo, targeting a wider population of this cell type than the standard method, with better access resistance. Overall, the gentler Touch and Zap method is promising for studying quantitative functional properties in the intact brain with minimal perturbation of the cell's intrinsic properties and local network. Because the Touch and Zap method is performed semi-automatically, this approach is more reproducible and less dependent on experimenter technique
Improved Precision and Efficiency of a Modified ORG0020 Dynamic Respiration Test Setup for Compost Stability Assessment
The ORG0020 dynamic respiration test is effective at distinguishing source segregated organic waste derived composts across a wide range of stabilities when compared to other standard tests; however, using the original diaphragm pump and manifold setup, the test is affected by variability in flow rate with time and across sample replicate vessels. Here, we demonstrate the use of a multichannel peristaltic pump to deliver a more consistent air flow to individual vessels. Using finished and unfinished industry compost samples from different sites with varying stabilities, we provide evidence of greater precision of the modified setup compared to the original. Furthermore, the reduced need for air flow adjustment resulted in improved running cost efficiency with less labour demand. Analysis of compost sample oxygen demand supports the current test air flow rate of 25–75 mL min−1, although the improved air flow control will enable future narrowing of the acceptable range for better inter-laboratory performance
Understanding Concerns about Community Relations in Calderdale
•This study examined attitudes and dispositions towards greater ethnic and religious diversity, as well as community relations more generally, among residents of predominantly white British neighbourhoods. It also examined people’s attitudes and responses to anti-minority protest by groups like the English Defence League (EDL)and towards cohesion policy and practices.
A mixed methods design was used combining a (non-representative) household survey (n=212) in three selected research sites (Illingworth, Sowerby Bridge and Todmorden) with eight key informant interviews (across key institutions) and nine focus group discussions (across age-ranges and localities) with local people
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