Bacterial methane formation and distribution in marine environments : case studies from Arkona Basin (Western Baltic Sea) and hotspots in the Central South Pacific

Im Rahmen dieser Arbeit wurde die Methangenese und sekundäre Abbauprozesse des Methans in zwei sehr unterschiedlichen marinen Milieus untersucht. Zum einen wurden die gasreichen flachmarinen Sedimente der westlichen Ostsee im Arkona Becken untersucht. Zum anderen waren submarine hydrothermale Fluid/Gas-Ausströmungen an Hotspot Vulkanen des zentralen Südpazifiks Ziel der in dieser Dissertation zusammengefassten Arbeiten. Anhand der Ergebnisse aus geochemischen, sedimentologischen und seismischen Untersuchungen, sowie geochemischen Modellierungen konnten Vorkommen, Verteilung, Genese und Abbauprozesse von Methan in den zwei Beispielgebieten geklärt werden. Insbesondere aus der Analyse der molekularen Zusammensetzung der aus den Fluid- bzw. Porenwasserproben extrahierten Kohlenwasserstoffe, in Kombination mit der stabilen Kohlenstoff- und Wasserstoff-Isotopie des Methans, konnten Rückschlüsse auf die Methanbildungsprozesse in den jeweiligen Arbeitsgebieten gezogen werden

Methane formation and distribution of acoustic turbidity in organic-rich surface sediments in the Arkona Basin, Baltic Sea

This study was performed to investigate gas formation and gas saturation conditions related to acoustic turbidity in shallow (∼40 m deep) marine basins. The Arkona Basin, Baltic Sea, with its organic-rich fine-grained surface sediment provides an ideal “Natural Laboratory” to characterise free gas using seismic, geoacoustic, and geochemical methods. The area of acoustic turbidity covers about 1500 km2 of the central Arkona Basin, corresponding to areas where organic-rich post-glacial sediments exceed 4–6 m in thickness. The highest concentration of pore water methane (7660 μmol L−1), found in areas of high acoustic turbidity, was near the calculated lower limit of methane solubility for the measured in situ temperature, salinity, and pressure. Pore water methane concentration decreased to near 4 μmol L−1 in areas outside of the zone of high acoustic turbidity. Stable carbon (−70.7‰ to −92.3‰ PDB) and hydrogen (−124‰ to −185‰ SMOW) isotope values of methane indicate that methane is predominantly formed by microbial CO2 reduction in Arkona Basin surface sediments and rules out significant contributions of other sources

Depositional environments and source rock potential of some Upper Palaeozoic (Devonian) coals on Bjørnøya, Western Barents shelf

Upper Palaeozoic strata are potential sources for hydrocarbon plays on the Norwegian Barents Shelf. The island of Bjørnøya (Bear Island) is located on the western margin of the Barents Shelf and represents an exposed part of the Stappen High, which makes it an excellent location to investigate the source rock potential of this succession. Here, we investigate the organic geochemical composition and source rock potential of coals and organic-rich mudstones of Late Devonian to middle Permian ages. The thermal maturity of the analysed samples ranges from mature to overmature with some samples being in the late oil generation window, and thus exhibiting higher maturities than age and facies equivalent strata in central Spitsbergen in the NW corner of the Barents Shelf and on the Finnmark Platform to the south. The high maturities and thermal cracking may thus have negatively affected the applied isoprenoid and biomarker-based source facies parameters, which potentially inhibit correct source facies interpretation. However, our results and comparisons with previous studies indicate that the vitrinite- and inertinite-dominated humic coals occurring in the lower part of the succession formed by the accumulation of peat in fluvially-influenced, humid wetlands at paleo-equatorial latitudes during a pronounced episode of rifting in the Late Devonian (Famennian) to earliest Carboniferous (Mississippian). Our source rock evaluation indicates a good potential for liquid hydrocarbon generation for the coals of the Upper Devonian Røedvika Formation prior to maturation. The oil-prone organic matter of these coals is primarily considered as terrestrial and non-aqueous. Because of renewed rifting in the middle Carboniferous combined with a shift to arid climatic conditions, as well as an environmental change from dominantly terrestrial and marginal marine clastic to marine carbonate platform environments, the accumulation of wetland peats effectively came to an end. Thus, the overlying Carboniferous and Permian strata generally seems to yield poor to no hydrocarbon generation potentia

Linking facies variations, organic carbon richness and bulk bitumen content – A case study of the organic-rich Middle Triassic shales from eastern Svalbard

The organic-rich shales of the Middle Triassic Botneheia Formation in Svalbard and its correlative units offshore are considered important source rock intervals for oil and gas generation in the Norwegian Barents Shelf region. Detailed investigation of these intervals is essential to better understand the intra source rock variations and thus to improve exploration models. As source rocks are rarely cored during exploration campaigns, outcrop studies of analogue source rocks onshore Svalbard are of great importance for gaining a comprehensive understanding of the Triassic petroleum system offshore. This integrated sedimentological and geochemical study of the Botneheia Formation investigates the intricate relationship between mudstone facies, total sulfur, total organic/inorganic carbon, and the absolute and relative abundance of bulk bitumen content. Both the Muen Member (Anisian) and the overlying Blanknuten Member (mostly Ladinian) of the Botneheia Formation were densely sampled and analyzed from three outcrop localities on Edgeøya, eastern Svalbard. The results show that total sulfur, total organic carbon, bitumen richness, and relative and absolute aromatic hydrocarbon content increase from bioturbated, gray-colored shales in the lower to middle Muen Member upwards into non-bioturbated, phosphogenic black shales in the middle part of the Blanknuten Member. From here, organic carbon and bulk bitumen richness subsequently decrease upwards in concert with the occurrence of bioturbated, calcareous mudstones and impure limestones towards the top of the Blanknuten Member. Optical vitrinite reflectance variations do not suggest significant maturity variations with depth in the sample profiles, highlighting that the total organic carbon and bulk bitumen content are dominantly coupled with the developing source facies. These facies and chemostratigraphic trends mirror the implied marine vs. terrigenous organic matter sedimentation and benthic preservation potential, which were at a maximum in the middle Blanknuten Member. These processes appear to be closely related to the supply of nutritious upwelled waters that are further linked with an evolving pan-Arctic 2nd order Middle Triassic transgressive–regressive sequence. Facies and multivariate analyses of the geochemical data show that the lower to middle Muen Member are comparable to the pro-delta mudstones of the younger Tschermakfjellet Formation (Carnian), and that both units are clearly distinct from the increased source rock potential and richness in the upper part of the Muen Member and the entire Blanknuten Member. This provides evidence of genetically different paleo-depositional environments and source rock properties that are confined to the lower and upper parts of the Middle Triassic Botneheia Formation, and may have wide applications for Triassic source rock assessment in the offshore Norwegian Barents Se