Functionalized platinum nanoparticles with surface charge trigged by pH: synthesis, characterization and stability studies

In this work, the synthesis and characterization of functionalized platinum nanoparticles (PtNPs) have been investigated. PtNPs were obtained by a wet redox procedure using 2-diethylaminoethanethiol hydrochloride (DEA) as capping agent. By varying the Pt/thiol molar ratio, monodispersed and stable particles with diameters in the range of 3-40 nm were isolated. The amino functionality allows neutral particles to be obtained in basic water solution and positive charged nanoparticles in neutral or acidic water solution (pH 7-2), as confirmed by DLS and ζ-potential measurements. FTIR spectroscopy, FE-SEM, DLS and ζ-potential measurements confirmed the size and showed long term water stability (up to three months) of the colloidal system

Formation and evolution of clumpy tidal tails around globular clusters

We present some results of numerical simulations of a globular cluster orbiting in the central region of a triaxial galaxy on a set of 'loop' orbits. Tails start forming after about a quarter of the globular cluster orbital period and develop, in most cases, along the cluster orbit, showing clumpy substructures as observed, for example, in Palomar 5. If completely detectable, clumps can contain about 7,000 solar masses each, i.e. about 10% of the cluster mass at that epoch. The morphology of tails and clumps and the kinematical properties of stars in the tails are studied and compared with available observational data. Our finding is that the stellar velocity dispersion tends to level off at large radii, in agreement to that found for M15 and Omega Centauri.Comment: LaTeX 2e, uses AASTeX v5.x, 40 pages with 18 figures. Submitted to The Astronomical Journa

The Supersymmetric Ward-Takahashi Identity in 1-Loop Lattice Perturbation Theory. I. General Procedure

The one-loop corrections to the lattice supersymmetric Ward-Takahashi identity (WTi) are investigated in the off-shell regime. In the Wilson formulation of the N=1 supersymmetric Yang-Mills (SYM) theory, supersymmetry (SUSY) is broken by the lattice, by the Wilson term and is softly broken by the presence of the gluino mass. However, the renormalization of the supercurrent can be realized in a scheme that restores the continuum supersymmetric WTi (once the on-shell condition is imposed). The general procedure used to calculate the renormalization constants and mixing coefficients for the local supercurrent is presented. The supercurrent not only mixes with the gauge invariant operator $T_\mu$. An extra mixing with other operators coming from the WTi appears. This extra mixing survives in the continuum limit in the off-shell regime and cancels out when the on-shell condition is imposed and the renormalized gluino mass is set to zero. Comparison with numerical results are also presented.Comment: 16 pages, 2 figures. Typos error correcte

Spitsbergen volume : Frontiers of Rationality

This volume contains 20 papers related to the workshop Frontiers of Rationality that was held in Longyearbyen, Spitsbergen, in July 2014

Geometry Diagnostics of a Stellar Flare from Fluorescent X-rays

We present evidence of Fe fluorescent emission in the Chandra HETGS spectrum of the single G-type giant HR 9024 during a large flare. In analogy to solar X-ray observations, we interpret the observed Fe K$\alpha$ line as being produced by illumination of the photosphere by ionizing coronal X-rays, in which case, for a given Fe photospheric abundance, its intensity depends on the height of the X-ray source. The HETGS observations, together with 3D Monte Carlo calculations to model the fluorescence emission, are used to obtain a direct geometric constraint on the scale height of the flaring coronal plasma. We compute the Fe fluorescent emission induced by the emission of a single flaring coronal loop which well reproduces the observed X-ray temporal and spectral properties according to a detailed hydrodynamic modeling. The predicted Fe fluorescent emission is in good agreement with the observed value within observational uncertainties, pointing to a scale height $\lesssim 0.3$\rstar. Comparison of the HR 9024 flare with that recently observed on II Peg by Swift indicates the latter is consistent with excitation by X-ray photoionization.Comment: accepted for publication on the Astrophysical Journal Letter

Magnetic dipoles and electric currents

We discuss several similarities and differences between the concepts of electric and magnetic dipoles. We then consider the relation between the magnetic dipole and a current loop and show that in the limit of a pointlike circuit, their magnetic fields coincide. The presentation is accessible to undergraduate students with a knowledge of the basic ideas of classical electromagnetism.Comment: 7 pages, 1 figur

A detailed study of the rise phase of a long duration X-ray flare in the young star TWA 11B

We analyzed a long duration flare observed in a serendipitous XMM-Newton detection of the M star CD-39 7717B (TWA 11B), member of the young stellar association TW Hya (~ 8 Myr). Only the rise phase (with a duration of ~ 35 ks) and possibly the flare peak were observed. We took advantage of the high count-rate of the X-ray source to carry out a detailed analysis of its spectrum during the whole exposure. After a careful analysis, we interpreted the rise phase as resulting from the ignition of a first group of loops (event A) which triggered a subsequent two-ribbon flare (event B). Event A was analyzed using a single-loop model, while a two-ribbon model was applied for event B. Loop semi-lengths of ~ 4 R* were obtained. Such large structures had been previously observed in very young stellar objects (~ 1 - 4 Myr). This is the first time that they have been inferred in a slightly more evolved star. The fluorescent iron emission line at 6.4 keV was detected during event B. Since TWA 11B seems to have no disk, the most plausible explanation found for its presence in the X-ray spectrum of this star is collisional - or photo- ionization. As far as we are concerned, this is only the third clear detection of Fe photospheric fluorescence in stars other than the Sun.Comment: Accepted for publication in ApJ. 15 pages, 9 figure

An enigmatic long-lasting gamma-ray burst not accompanied by a bright supernova

Gamma-ray bursts (GRBs) are short, intense flashes of soft gamma-rays coming from the distant Universe. Long-duration GRBs (those lasting more than ~2 s) are believed to originate from the deaths of massive stars, mainly on the basis of a handful of solid associations between GRBs and supernovae. GRB 060614, one of the closest GRBs discovered, consisted of a 5-s hard spike followed by softer, brighter emission that lasted for ~100 s. Here we report deep optical observations of GRB 060614 showing no emerging supernova with absolute visual magnitude brighter than M_V = -13.7. Any supernova associated with GRB 060614 was therefore at least 100 times fainter, at optical wavelengths, than the other supernovae associated with GRBs. This demonstrates that some long-lasting GRBs can either be associated with a very faint supernova or produced by different phenomena.Comment: 14 pages, 4 color figures. Final version accepted to Nature. Title and author list updated. Includes supplementary material and one extra color figure for presentation

A bag of tricks: Using proper motions of Galactic stars to identify the Hercules ultra-faint dwarf galaxy members

Hercules is the prototype of the ultra-faint dwarf (UFD) galaxies. To date, there are still no firm constraints on its total luminosity, due to the difficulty of disentangling Hercules bona-fide stars from the severe Galactic field contamination. In order to better constrain Hercules properties we aim at removing foreground and background contaminants in the galaxy field using the proper motions of the Milky Way stars and the colour-colour diagram. We have obtained images of Hercules in the rSloan, BBessel and Uspec bands with the Large Binocular Telescope (LBT) and LBC-BIN mode capabilities. The rSloan new data-set combined with data from the LBT archive span a time baseline of about 5 yr, allowing us to measure for the first time proper motions of stars in the Hercules direction. The Uspec data along with existing LBT photometry allowed us to use colour-colour diagram to further remove the field contamination. Thanks to a highly-accurate procedure to derive the rSloan-filter geometric distortion solution for the LBC-red, we were able to measure stellar relative proper motions to a precision of better than 5 mas yr^-1 down to rSloan=22 mag and disentangle a significant fraction (\>90\%) of Milky Way contaminants. We ended up with a sample of 528 sources distributed over a large portion of the galaxy body (0.12 deg^2). Of these sources, 171 turned out to be background galaxies and additional foreground stars, from the analysis of the Uspec - BBessel vs. BBessel - rSloan colour-colour diagram. This leaves us with a sample of 357 likely members of the Hercules UFD. We compared the cleaned colour-magnitude diagram (CMD) with evolutionary models and synthetic CMDs, confirming the presence in Hercules of an old population (t=12\pm 2 Gyr), with a wide spread in metallicity (-3.3\<[Fe/H]\<-1.8).Comment: 16 pages, 15 figures, 3 tables, accepted for publication in A&

Modelling and simulation of dynamic recrystallization (DRX) in OFHC copper at very high strain rates

At high strain rates, deformation processes are essentially adiabatic and if the plastic work is large enough dynamic recrystallization can occur. In this work, an examination on microstructure evolution of OFHC copper in Dynamic Tensile Extrusion (DTE) test, performed at 400 m/s, was carried out. EBSD investigations, along the center line of the fragment remaining in the extrusion die, showed a progressive elongation of the grains, and an accompanying development of a strong < 001 > + < 111 > dual fiber texture. Discontinuous dynamic recrystallization (DRX) occurred at larger strains, and it was showed that nucleation occurred during straining. A criterion for DRX to occur, based on the evolution of Zener-Hollomon parameter during the dynamic deformation process, is proposed. Finally, DTE test was simulated using the modified Rusinek-Klepaczko constitutive model incorporating a model for the prediction of DRX initiation