217 research outputs found
Workshop on Next Generation Real-Time Embedded Systems
Front Matter, Table of Contents, Preface, Conference Organizatio
Halogen bonding stabilizes a cis-azobenzene derivative in the solid state: A crystallographic study
Crystals of trans- and cis-isomers of a fluorinated azobenzene derivative have been prepared and characterized by single-crystal X-ray diffraction. The presence of F atoms on the aromatic core of the azobenzene increases the lifetime of the metastable cis-isomer, allowing single crystals of the cis-azobenzene to be grown. Structural analysis on the cis-azobenzene, complemented with density functional theory calculations, highlights the active role of the halogen-bond contact (N...I synthon) in promoting the stabilization of the cis-isomer. The presence of a long aliphatic chain on the azobenzene unit induces a phase segregation that stabilizes the molecular arrangement for both the trans- and cis-isomers. Due to the rarity of cis-azobenzene crystal structures in the literature, our paper makes a step towards understanding the role of non-covalent interactions in driving the packing of metastable azobenzene isomers. This is expected to be important in the future rational design of solid-state, photoresponsive materials based on halogen bonding. We show by single-crystal X-ray diffraction studies and computational analysis that halogen bonding can stabilize a metastable cis-azobenzene derivative in the solid state
Coordination networks incorporating halogen-bond donor sites and azobenzene groups
Two Zn coordination networks, [Zn(1)(Py)2]2(2-propanol)n (3) and [Zn(1)2(Bipy)2](DMF)2n (4), incorporating halogen-bond (XB) donor sites and azobenzene groups have been synthesized and fully characterized. Obtaining 3 and 4 confirms that it is possible to use a ligand wherein its coordination bond acceptor sites and XB donor sites are on the same molecular scaffold (i.e., an aromatic ring) without interfering with each other. We demonstrate that XBs play a fundamental role in the architectures and properties of the obtained coordination networks. In 3, XBs promote the formation of 2D supramolecular layers, which, by overlapping each other, allow the incorporation of 2-propanol as a guest molecule. In 4, XBs support the connection of the layers and are essential to firmly pin DMF solvent molecules through Iâ‹ŻO contacts, thus increasing the stability of the solvated systems
Efficient light-induced phase transitions in halogen-bonded liquid crystals
Here, we present a new family of light-responsive, fluorinated supramolecular liquid crystals (LCs) showing efficient and reversible light-induced LC-to-isotropic phase transitions. Our materials design is based on fluorinated azobenzenes, where the fluorination serves to strengthen the noncovalent interaction with bond-accepting stilbazole molecules, and increase the lifetime of the cis-form of the azobenzene units. The halogen-bonded LCs were characterized by means of X-ray diffraction, hot-stage polarized optical microscopy, and differential scanning calorimetry. Simultaneous analysis of light-induced changes in birefringence, absorption, and optical scattering allowed us to estimate that <4% of the mesogenic units in the cis-form suffices to trigger the full LC-to-isotropic phase transition. We also report a light-induced and reversible crystal-to-isotropic phase transition, which has not been previously observed in supramolecular complexes. In addition to fundamental understanding of light-responsive supramolecular complexes, we foresee this study to be important in the development of bistable photonic devices and supramolecular actuators
Quantum Fractal Fluctuations
We numerically analyse quantum survival probability fluctuations in an open,
classically chaotic system. In a quasi-classical regime, and in the presence of
classical mixed phase space, such fluctuations are believed to exhibit a
fractal pattern, on the grounds of semiclassical arguments. In contrast, we
work in a classical regime of complete chaoticity, and in a deep quantum regime
of strong localization. We provide evidence that fluctuations are still
fractal, due to the slow, purely quantum algebraic decay in time produced by
dynamical localization. Such findings considerably enlarge the scope of the
existing theory.Comment: revtex, 4 pages, 5 figure
S-matrix theory for transmission through billiards in tight-binding approach
In the tight-binding approximation we consider multi-channel transmission
through a billiard coupled to leads. Following Dittes we derive the coupling
matrix, the scattering matrix and the effective Hamiltonian, but take into
account the energy restriction of the conductance band. The complex eigenvalues
of the effective Hamiltonian define the poles of the scattering matrix. For
some simple cases, we present exact values for the poles. We derive also the
condition for the appearance of double poles.Comment: 29 pages, 9 figures, submitted to J. Phys. A: Math. and Ge
LNCaP Prostate Cancer Growth In Vivo: Oncostatic Effects of Melatonin as Compared to Hypoxia and Reoxygenation
Heat conduction in one dimensional systems: Fourier law, chaos, and heat control
In this paper we give a brief review of the relation between microscopic
dynamical properties and the Fourier law of heat conduction as well as the
connection between anomalous conduction and anomalous diffusion. We then
discuss the possibility to control the heat flow.Comment: 15 pages, 11 figures. To be published in the Proceedings of the NATO
Advanced Research Workshop on Nonlinear Dynamics and Fundamental
Interactions, Tashkent, Uzbekistan, Octo. 11-16, 200
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