6,250 research outputs found

    Exact Camera Location Recovery by Least Unsquared Deviations

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    We establish exact recovery for the Least Unsquared Deviations (LUD) algorithm of Ozyesil and Singer. More precisely, we show that for sufficiently many cameras with given corrupted pairwise directions, where both camera locations and pairwise directions are generated by a special probabilistic model, the LUD algorithm exactly recovers the camera locations with high probability. A similar exact recovery guarantee was established for the ShapeFit algorithm by Hand, Lee and Voroninski, but with typically less corruption

    A Two-stage Polynomial Method for Spectrum Emissivity Modeling

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    Spectral emissivity is a key in the temperature measurement by radiation methods, but not easy to determine in a combustion environment, due to the interrelated influence of temperature and wave length of the radiation. In multi-wavelength radiation thermometry, knowing the spectral emissivity of the material is a prerequisite. However in many circumstances such a property is a complex function of temperature and wavelength and reliable models are yet to be sought. In this study, a two stages partition low order polynomial fitting is proposed for multi-wavelength radiation thermometry. In the first stage a spectral emissivity model is established as a function of temperature; in the second stage a mathematical model is established to describe the dependence of the coefficients corresponding to the wavelength of the radiation. The new model is tested against the spectral emissivity data of tungsten, and good agreement was found with a maximum error of 0.64

    Propagation of solitary waves through signicantly curved shallow water channels

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    Propagation of solitary waves in curved shallow water channels of constant depth and width is investigated by carrying out numerical simulations based on the generalized weakly nonlinear and weakly dispersive Boussinesq model. The objective is to investigate the effects of channel width and bending sharpness on the transmission and reflection of long waves propagating through significantly curved channels. Our numerical results show that, when travelling through narrow channel bends including both smooth and sharp-cornered 90°-bends, a solitary wave is transmitted almost completely with little reflection and scattering. For wide channel bends, we find that, if the bend is rounded and smooth, a solitary wave is still fully transmitted with little backward reflection, but the transmitted wave will no longer preserve the shape of the original solitary wave but will disintegrate into several smaller waves. For solitary waves travelling through wide sharp-cornered 90°-bends, wave reflection is seen to be very significant, and the wider the channel bend, the stronger the reflected wave amplitude. Our numerical results for waves in sharp-cornered 90°-bends revealed a similarity relationship which indicates that the ratios of the transmitted and reflected wave amplitude, excess mass and energy to the original wave amplitude, mass and energy all depend on one single dimensionless parameter, namely the ratio of the channel width b to the effective wavelength [lambda][sub]e. Quantitative results for predicting wave transmission and reflection based on b/[lambda][sub]e are presented

    Studies Towards a pH-Sensitive Anticancer Prodrug Model

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    Tumour-activated prodrug (TAP) is designed to aim at increasing the prodrug selectivity to kill cancer cells. One strategy to is to design a TAP containing an amine cytotoxin, present as an amide function, which could be released more rapidly in the low pH environment of tumour tissues when amide undergoes hydrolysis. The prodrug model (1) was the subject of the current study. At lower pH its un-ionised carboxylic acid group provides neighbouring catalysis of hydrolysis of the adjacent amide. It was synthesised via ring-opening of the imide (2) which itself was directly synthesised from endo-bicyclo[2.2.2]octa-5-ene-2,3-dicarboxylic anhydride and p-methoxyaniline. The pH-rate profile of (1) was established over the pH range of 3-10, covering rapid hydrolysis of un-ionised acid-amide at lower pH but slower imide formation above pH 8 from the ionised acid-amide. From the kinetic data were calculated the dissociation constant for (1) (pKa: 5.1 at 30 C) and limiting lower pH rate constant for hydrolysis of (1) in its fully neutral form (klim: 0.44 min-1 at 30 C). The data in the pH range of 8-10 provided klow (0.067 min-1) representing formation of (2) from fully ionised (1). The following equilibrium reaction was also investigated at high pH, at which (1) was in its fully ionised amide carboxylate form, by kinetic studies on (2) in hydroxide solutions. Imide + OH- Amide carboxylate The second order rate constant for the forward reaction, kf, was 74 L mol-1 min-1 which with klow for the reverse reaction gave K as 1100 L mol-1

    Lived Experiences of a Hong Kong Physical Education Teacher: Ethnographical and Phenomenological Approaches

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    This study employed ethnographical and phenomenological methods to explore the lived experiences and career of a Hong Kong secondary school physical education (PE) teacher (Wharton) in order to embody his versatile roles through phenomenological description of a lived body itself and the lived world. The central research question is “How does a male secondary school PE teacher manage his work life and the embodiment of his professional roles?” Data collection techniques were in-depth interviewing, participant observation and field notes, participant’s reflection documentation and visual elicitation. Concepts of “play to learn,” “professional development” and “political empowerment” were used to examine Wharton’s lived experiences and career. Themes such as Static Gestalt, Dynamic Gestalt, Style Gestalt and Reversibility Gestalt were identified. This study may inform literature on sociological perspectives and the life histories of PE teachers and applicable to other teachers as they adapt to environmental changes in other settings

    Characteristics of typical pollutants in tannery site soil

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    Content: This paper briefly introduced the process of leather manufacture and the potential pollution sources of soil in tannery sites. Pollutants are mainly derived from the use of a large number of various chemicals and organic matter decomposed by raw skin. The characteristics of typical pollutants in tannery sites soil were summarized, including tannery site soil pH, organic and inorganic compounds, and heavy metals, etc., especially the status of chromium contamination were reviewed. The pH of soil in the tanning workshop (6.65-7.8) is generally lower than tannery sludge dumping site (7.94-8.40). The main organic pollutants contained in the tannery site soil include nitrogen compound, grease, petroleum hydrocarbon. In tannery sludge dumping site soil, the content of nitrogen compound (10cm depth) is 28400 mg/kg, which is similar to tannery sludge. The content of petroleum hydrocarbon is 5-700 mg/kg, which partially exceed the limits of China agricultural land quality standard(450mg/L), total dissolved solids (>1000mg/L), sulfate ions (>250mg/L), nitrite nitrogen (>0.02mg/L) partially exceed the limits of China groundwater quality standard, which are found in groundwater below the tannery site. Heavy metal pollutants in the tannery sites soil have many characteristics and large differences in content, due to the different tanning processes. Among them, chromium (Cr) is the most used heavy metal and the highest content of pollutants. Cr content in tanning process wastewater, dyeing process wastewater and chromiumcontaining sludge are about 2000-3000 mg/L, 30-40 mg/L and 8500-25800 mg/kg, respectively. Total Cr content in the partial tannery sites soil are higher than 800 mg/kg, which exceed the limits of China agricultural land quality standard(<150mg/kg). Surprisingly, Cr(VI) appears in tannery sites soil and the contents are partly higher than 40 mg/kg, which exceed the limits of China development land quality standard(<3.0mg/kg). Furthermore, the more effort needs to be directed toward the chemistry of chromium-organic complex pollutants, and an understanding of the speciation of Cr in highly organics contaminated tannery site soil is essential for the development of suitable remediation strategies for contaminated soil. Take-Away: 1. The pH of soil in the tanning workshop (6.65-7.8) is generally lower than tannery sludge dumping site(7.94-8.40). 2. Total Cr content in the partial tannery sites soil are higher than 800 mg/kg, which exceed the limits of China agricultural land quality standard(<150mg/kg). 3. Cr(VI) appears in tannery sites soil and the contents are partly higher than 40 mg/kg, which exceed the limits of China development land quality standard(<3.0mg/kg)

    A COMPUTATIONAL STUDY ON THE HYDROGEN-BONDED COMPLEXES FORMED BY THE ANTHYRIDONE AND DIALDEHYDE DERIVATIVES

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    A theoretical study on hydrogen-bonded complex 1 formed by anthyridone (monomer A) and 2,6-diaminopyridine-3,5-dialdehyde (monomer B) was performed using the AM1 method to obtain its binding energy. A series of complexes 2 to 9 were designed by changing the R-groups on monomer A in complex 1 into C6H5, p-toluene, p-phenol, OH, OCH3, and turning the X-groups on monomer B into F, Cl, I, respectively. Based on the optimized geometries, the electronic spectra for the complexes were calculated with the INDO/CIS method and the IR spectra were computed utilizing the AM1 method. It was indicated that the dimer could be formed by the two monomers via triple hydrogen bonds because of its negative binding energy. The binding energies of the complexes were changed with the change of the electronic properties and steric effects of the substituents on the monomers. The first absorptions in the electronic spectra of the complexes were red-shifted compared with those of the monomers. The stretching vibrations of the N-H bonds on the monomers were weakened and their frequencies were reduced with the formation of the hydrogen bonds. KEY WORDS: Anthyridone, 2,6-Diaminopyridine-3,5-dialdehyde, Hydrogen bonding, IR spectra, AM1 Bull. Chem. Soc. Ethiop. 2007, 21(2), 263-270

    Duty ratio modulation direct torque control of brushless doubly-fed machines

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    For the brushless doubly-fed machine (BDFM), traditional direct torque control (DTC) has many problems such as big output torque ripple and uncertain inverter switch frequency. Based on the analysis of traditional DTC, this paper proposed a new torque control which applied duty ratio modulation into direct torque control. This new control method can decrease the torque ripple effectively by adding zero voltage in each control cycle. According to the brushless BDFM state equation and the prediction of torque, flux linkage in the next moment and the theory of electromagnetic torque equals to referenced value at the instant moment in one control cycle, torque ripple can be decreased. Through theoretical analysis and experiments, the proposed control method has all advantages of traditional direct torque control and can decrease torque ripple and flux linkage ripple, which can optimize the performance of direct torque control
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