Hydrochemical Evolution of Ground and Surface Water within the Amansie and Adansi Districts of the Ashanti Region, Ghana

Source–rock deductions of major ions and saturation states of minerals in groundwater were employed to determine the origin of dissolved ions and the thermodynamic controls on the groundwater composition respectivelyin groundwater within the Amansie and Adansi Districts. Results show that, silicate weathering and ion-exchange reactions are the major processes influencing groundwater chemistry within the Districts. The main objective of this study is to characterize groundwater and delineate soil-water-rock interactions responsible for the chemical evolution of groundwater within the districts. Fifty-nine boreholes, twelve wells and two stream samples were collected for quality assessment. Results also show that groundwater within the districts is strongly to moderately acidic as, 62 % of the groundwaters has pH that range 3.6 - 6.0. Acidity in ground and surface water within the districts is attributable predominantly to natural processes than mining activities; however, the groundwaters still have the potential to neutralize acids due to the presence of silicates/aluminosilicates. The waters are fresh (EC< 500 μS/cm) with conductivity values which ranged 22.8 – 473 μS/cm, and a mean value of 172.9 μS/cm. TDS of the groundwaters ranged 14.9 – 309.8 mg/L with a mean value of 112.6 mg/L. The relative abundance of cations and anions are in the order: Ca2+ > Na+ > Mg2+ > K+ and HCO3- > Cl- > SO42-respectively. The states of saturation of the groundwaters with respect to major minerals using hydrogeochemical transport model Phreeqc for Windows suggest that, anhydrite and gypsum are subsaturated and indicates that, groundwater within the districts originates from a formation with insufficient amount of these minerals in solution or short residence time of these minerals with groundwater within the districts.Two principal hydrochemical water types; Ca-Mg-HCO3 and Na–Cl have been delineated, with Ca-Mg-SO4, Na-Mg-Ca-HCO3 and Na- Cl-SO4 as minor water types. Groundwater within the districts principally evolves from fresh Ca–Mg–HCO3 type water into Na–HCO3 type water into Ca–Mg–Cl type water into Na–Cl type water along its flow path due to ion-exchange reactions and therefore, largely characterized by recharge processes through mixing with waters of geochemically different ionic signatures

Assessment of Nutrients Levels in Groundwater within the Lower Pra Basin of Ghana

The level of concentration of nitrates, phosphates, and sulphates was determined in groundwater within the Pra Basin to ascertain the degree of anthropogenic influence via the application of fertilizer and other agro-chemical to farmlands by farmers. Sixty-five (65) boreholes in forty-five (45) communities were analysed between January and April 2012 to cover the dry season and between June and October 2012 to cover the wet season. The results show that nitrate for both seasons range between 0.011 mg/l and 5.01 mg/l and therefore within the WHO (2006) guideline value of 10 mg/l, whilst that of phosphate range between 0.01 mg/l and 3.08 mg/l and therefore outside the USEPA guideline value of 2.5 mg/l. Sulphate recorded a range between 1.60 and 96.2 mg/l and therefore within the WHO (2006) guideline value of 250 mg/l. The concentration levels of the two nutrients of the parameters, nitrates and phosphate were correlated against borehole depth and the results show a weak positive and negative correlation for nitrate and phosphate respectively. There was thus, an indication that the levels of all parameters, nitrate, phosphate and sulphate are not yet a threat to groundwater in the basin

Large Area Roller Embossing of Multilayered Ceramic Green Composites

In this paper, we will report our achievements in developing large area patterning of multilayered ceramic green composites using roller embossing. The aim of our research is to pattern large area ceramic green composites using a modified roller laminating apparatus, which is compatible with screen printing machines, for integration of embossing and screen printing. The instrumentation of our roller embossing apparatus, as shown in Figure1, consists of roller 1 and rollers 2. Roller 1 is heated up to the desired embossing temperature ; roller 2 is, however, kept at room temperature. The mould is a nickel template manufactured by plating nickel-based micro patterns (height : 50 $\mu$m) on a nickel film (thickness : 70 $\mu$m) ; the substrate for the roller embossing is a multilayered Heraeus Heralock HL 2000 ceramic green composite. Comparing with the conventional simultaneous embossing, the advantages of roller embossing include : (1) low embossing force ; (2) easiness of demoulding ; (3) localized area in contact with heater ; and etc. We have demonstrated the capability of large area roller embossing with a panel size of 150mmx 150mm on the mentioned substrate. We have explored and confirmed the impact of parameters (feed speed, temperature of roller and applied pressure) to the pattern quality of roller embossing. Furthermore, under the optimized process parameters, we characterized the variations of pattern dimension over the panel area, and calculated a scaling factor in order to make the panel compatible with other processes. Figure 2 shows the embossed patterns on a 150mmx 150mm green ceramic panel.Comment: Submitted on behalf of EDA Publishing Association (http://irevues.inist.fr/handle/2042/16838

Adaptive and coupled continuum-molecular mechanics simulations of amorphous materials

A method to reduce the degrees freedom in molecular mechanics simulation is presented. Although the approach is formulated for amorphous materials in mind, it is equally applicable to crystalline materials. The method can be selectively applied to regions where molecular displacements are expected to be small while simultaneously using classical molecular mechanics (MM) for regions undergoing large deformation. The accuracy and computational efficiency of the approach is demonstrated through the simulation of a polymer-like substrate being indented by a rigid hemispherical indentor. The region directly below the indentor is modelled by classical molecular mechanics while the region further away has the degrees of freedom (DOFs) reduced by about 50 times. The results of automatically reverting regions of reduced DOFs back to classical MM also demonstrate the capability of performing adaptive simulations

Assessment of trace metal contamination by geochemical normalisation in sediments of two lagoons: A comparative study of the Kpeshie and Muni lagoons, Ghana

Heavy metal contamination status of bottom sediments of two lagoons was compared by the employment of Enrichment Factor (EF) analysis for Iron (Fe), Manganese (Mn), Cupper (Cu), Lead (Pb), Chromium (Cr), Nickel (Ni), Silver (Ag), Zinc (Zn) and Mercury (Hg). Kpeshie Lagoon recorded enrichment (EF ≥ 1) for Cd, Pb, Ag, Hg and Zn, whilst Muni Lagoon recorded enrichment for Cd, Mn, Ag, Hg and Zn as metals of anthropogenic influence. Kpeshie, situated in a highly urbanized area, has 75% spatial distribution of Pb enrichment. The assessment shows that Ag and Hg are the most enriched metals in the sediments of both Lagoons, reaching extremely severe levels. Only Mn showed statistically significant difference in mean concentration of metals for both Lagoons. Pearson correlation matrix indicated that Pb had a strong relation with Ag, Hg and Zn (r = 0.956; p < 0.05) which is significant in Kpeshie. It also had a strong association with Ag and Hg but not with Zn (r = 0.240) in the Muni. The study clearly delineates Pb as a pollutant that designates the urban status of Kpeshie. Its associated metals; Ag, Hg and Zn which may be coming from a common source are from industrialized zones

The expanding phenotype of MELAS caused by the m.3291T \u3e C mutation in the MT-TL1 gene

Crown Copyright © 2016 Published by Elsevier Inc. m.3291T \u3e C mutation in the MT-TL1 gene has been infrequently encountered in association with mitochondrial myopathy, encephalopathy, lactic acidosis and stroke-like episodes (MELAS), however remains poorly characterized from a clinical perspective. In the following report we describe in detail the phenotypic features, long term follow up (\u3e 7 years) and management in a Caucasian family with MELAS due to the m.3291T \u3e C mutation and review the literature on m.3291T \u3e C mutation. The clinical phenotype in the proposita included overlapping features of MELAS, MERRF (Myoclonic epilepsy and ragged-red fiber syndrome), MNGIE (Mitochondrial neurogastrointestinal encephalopathy), KSS (Kearns-Sayre Syndrome) and CPEO (Chronic progressive external ophthalmoplegia)

Preoperative Kidney Function linked to mortality and readmission outcomes at Day 90 and 30 in Older Emergency Surgical Patients

Grants were received from British Geriatric Society and The Renal Association to support Louis EvansPeer reviewedPublisher PD

Health risk assessment and source identification of Polycyclic Aromatic Hydrocarbons (PAHs) in commercially available singed cowhide within the Greater Accra Region, Ghana

This study ascertains the sources and potential carcinogenic threats of polycyclic aromatic hydrocarbons (PAHs) in singed cowhide. The objective was to assess the sources of PAHs and the health threats singed cowhide possess to the consuming public. A total of fifty-four (54) cowhide samples from selected markets within the Greater-Accra Region of Ghana were analyzed using Agilent GC 6890N, MS5975B Series gas chromatography in a splitless mode. The study shows that, singed cowhide within the Greater Accra Region is dominated by positive genotoxicity PAHs classified as carcinogens (1) and possible carcinogens (2B) as well as positive and questionable genotoxic PAHs that are not classifiable (3). The [B(a)P]eq and PEC results suggest that consumption of singed cowhide at the rate of 25.2 g/day poses potential adverse health effects such as cancer, mutations and birth defects in terms of B(a)P to humans. Results further show that, the HQ/HI < 1, thus, there is no concern for potential human health risks caused by exposure to non-carcinogenic PAHs in singed cowhide. However, the carcinogenic toxic equivalent (TEQs) values for both adults and children were greater than the screening values and therefore, there is concern for potential human health risks caused by exposure to carcinogenic PAHs in singed cowhide. Source assessment of PAHs in singed cowhide shows that, PAH sources in singed cowhide is predominantly from pyrolitic rather than petrogenic origins. Thus, the PAHs in singed cowhide within the Greater Accra Region originate primarily from incomplete combustion and of petroleum origin due to singeing.&nbsp