896 research outputs found
Basic Consideration on EAF Dust Treatment Using Hydrometallurgical Processes
Electric Arc Furnace (EAF) dust, defined as special industrial waste in Japan, is treated through pyrometallurgical processes in which crude ZnO powder is recovered. An on-site type process, however, is desired to reduce treatment cost and cost of transportation of the dust. A hydrometallurgical process is considered to be suitable for such an on-site treatment. Although many EAF dust treatment processes by hydrometallurgical method have been proposed, most of them have not been commercialized in Japan. A short review of hydrometallurgical processes foe EAF dust was done and a new hydrometallurgical process for EAF dust was proposed in this study. Nitric acid solution is used for the extraction of ZnO from the dust. Some characteristics of the process are as follows: 1. Recovery of Zn from zinc ferrite in EAF dust is the target, while the dissolution of Fe is limited by controlling the pH of the solution. 2. Zn is recovered as metallic Zn by electrowinning from the solution and nitric acid is regenerated in the anode.報文Original Pape
Oxygen Reduction Activity of Silk-derived Carbons
Carbonized silk fibroin (CS), which is free of metallic elements, showed high catalytic activity for oxygen-reduction reaction (ORR). The catalytic activity of CS for ORR was greatly enhanced by steam activation forming silk-derived activated carbon (CS-AC). The surface morphology, surface area, pore structure and remaining nitrogen species of the CSs were compared with those of the CS-ACs. The open-circuit potential and the power density of a polymer electrolyte fuel cell using a CS900-AC, which was heat-treated at 900 degrees C prior to the steam activation, and a platinum/C (C: carbon black) anode under pure oxygen and hydrogen gases, respectively, both at 0.2 MPa, were 0.92 V and 142 mW cm(-2) at 80 degrees C. The ORR on the activated carbon, CS900-AC, proceeded with a 3.5-electron reaction at 0.6V (vs. RHE): however, this was improved to a 3.9-electron reaction with the addition of zirconium oxide at 20 wt% to CS900-AC.ArticleJournal of Power Sources. 195(18):5840-5847. (2010)journal articl
Structural Changes of Pulled Vesicles: a Brownian Dynamics Simulation
金沢大学理学部We studied the structural changes of bilayer vesicles induced by mechanical forces using a Brownian dynamics simulation. Two nanoparticles, which interact repulsively with amphiphilic molecules, are put inside a vesicle. The position of one nanoparticle is fixed, and the other is moved by a constant force as in opticaltrapping experiments. First, the pulled vesicle stretches into a pear or tube shape. Then the inner monolayer in the tube-shaped region is deformed, and a cylindrical structure is formed between two vesicles. After stretching the cylindrical region, fission occurs near the moved vesicle. Soon after this the cylindrical region shrinks. The trapping force ;100 pN is needed to induce the formation of the cylindrical structure and fission
Effect of DMF on liver I/R
AIM
To investigate the hypothesis that treatment with dimethyl fumarate (DMF) may ameliorate liver ischemia/reperfusion injury (I/RI).
METHODS
Rats were divided into 3 groups: sham, control (CTL), and DMF. DMF (25 mg/kg, twice/d) was orally administered for 2 d before the procedure. The CTL and DMF rats were subjected to ischemia for 1 h and reperfusion for 2 h. The serum alanine aminotransferase (ALT) and malondialdehyde (MDA) levels, adenosine triphosphate (ATP), NO × metabolites, anti-oxidant enzyme expression level, anti-inflammatory effect, and anti-apoptotic effect were determined.
RESULTS
Histological tissue damage was significantly reduced in the DMF group (Suzuki scores: sham: 0 ± 0; CTL: 9.3 ± 0.5; DMF: 2.5 ± 1.2; sham vs CTL, P < 0.0001; CTL vs DMF, P < 0.0001). This effect was associated with significantly lower serum ALT (DMF 5026 ± 2305 U/L vs CTL 10592 ± 1152 U/L, P = 0.04) and MDA (DMF 18.2 ± 1.4 μmol/L vs CTL 26.0 ± 1.0 μmol/L, P = 0.0009). DMF effectively improved the ATP content (DMF 20.3 ± 0.4 nmol/mg vs CTL 18.3 ± 0.6 nmol/mg, P = 0.02), myeloperoxidase activity (DMF 7.8 ± 0.4 mU/mL vs CTL 6.0 ± 0.5 mU/mL, P = 0.01) and level of endothelial nitric oxide synthase expression (DMF 0.38 ± 0.05-fold vs 0.17 ± 0.06-fold, P = 0.02). The higher expression levels of anti-oxidant enzymes (catalase and glutamate-cysteine ligase modifier subunit and lower levels of key inflammatory mediators (nuclear factor-kappa B and cyclooxygenase-2 were confirmed in the DMF group.
CONCLUSION
DMF improved the liver function and the anti-oxidant and inflammation status following I/RI. Treatment with DMF could be a promising strategy in patients with liver I/RI
All-optical formation of a Bose-Einstein condensate for applications in scanning electron microscopy
We report on the production of a F=1 spinor condensate of 87Rb atoms in a
single beam optical dipole trap formed by a focused CO2 laser. The condensate
is produced 13mm below the tip of a scanning electron microscope employing
standard all-optical techniques. The condensate fraction contains up to 100,000
atoms and we achieve a duty cycle of less than 10s.Comment: 5 pages, 4 figure
Significance of Off-Center Rattling for Emerging Low-lying THz Modes in type-I Clathrates
We show that the distinct differences of low-lying THz-frequency dynamics
between type-I clathrates with on-center and off-center guest ions naturally
follow from a theoretical model taking into account essential features of the
dynamics of rattling guest ions. Our model analysis demonstrates the drastic
change from the conventional dynamics shown by on-center systems to the
peculiar dynamics of off-center systems in a unified manner. We claim that
glass-like plateau thermal conductivities observed for off-center systems stem
from the flattening of acoustic phonon dispersion in the regime |k|<|G|/4. The
mechanism is applicable to other systems such as glasses or relaxers
Possibility of an ultra-precise optical clock using the transition in Yb atoms held in an optical lattice
We report calculations designed to assess the ultimate precision of an atomic
clock based on the 578 nm transition in Yb atoms
confined in an optical lattice trap. We find that this transition has a natural
linewidth less than 10 mHz in the odd Yb isotopes, caused by hyperfine
coupling. The shift in this transition due to the trapping light acting through
the lowest order AC polarizability is found to become zero at the magic trap
wavelength of about 752 nm. The effects of Rayleigh scattering, higher-order
polarizabilities, vector polarizability, and hyperfine induced electronic
magnetic moments can all be held below a mHz (about a part in 10^{18}), except
in the case of the hyperpolarizability larger shifts due to nearly resonant
terms cannot be ruled out without an accurate measurement of the magic
wavelength.Comment: 4 pages, 1 figur
Anomalous infrared spectra of hybridized phonons in type-I clathrate BaGaGe
The optical conductivity spectra of the rattling phonons in the clathrate
BaGaGe are investigated in detail by use of the terahertz
time-domain spectroscopy. The experiment has revealed that the lowest-lying
vibrational mode of a Ba(2) ion consists of a sharp Lorentzian peak at
1.2 THz superimposed on a broad tail weighted in the lower frequency regime
around 1.0 THz. With decreasing temperature, an unexpected linewidth broadening
of the phonon peak is observed, together with monotonic softening of the phonon
peak and the enhancement of the tail structure. These observed anomalies are
discussed in terms of impurity scattering effects on the hybridized phonon
system of rattling and acoustic phonons.Comment: Submitted to JPS
Accessing the dynamics of large many-particle systems using Stochastic Series Expansion
The Stochastic Series Expansion method (SSE) is a Quantum Monte Carlo (QMC)
technique working directly in the imaginary time continuum and thus avoiding
"Trotter discretization" errors. Using a non-local "operator-loop update" it
allows treating large quantum mechanical systems of many thousand sites. In
this paper we first give a comprehensive review on SSE and present benchmark
calculations of SSE's scaling behavior with system size and inverse
temperature, and compare it to the loop algorithm, whose scaling is known to be
one of the best of all QMC methods. Finally we introduce a new and efficient
algorithm to measure Green's functions and thus dynamical properties within
SSE.Comment: 11 RevTeX pages including 7 figures and 5 table
Optimized production of a cesium Bose-Einstein condensate
We report on the optimized production of a Bose-Einstein condensate of cesium
atoms using an optical trapping approach. Based on an improved trap loading and
evaporation scheme we obtain more than atoms in the condensed phase. To
test the tunability of the interaction in the condensate we study the expansion
of the condensate as a function of scattering length. We further excite strong
oscillations of the trapped condensate by rapidly varying the interaction
strength.Comment: 9 pages, 7 figures, submitted to Appl. Phys.
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